Search found 35 matches
- Tue Mar 13, 2018 11:47 pm
- Forum: Entropy Changes Due to Changes in Volume and Temperature
- Topic: Midterm Question 6B
- Replies: 1
- Views: 433
Midterm Question 6B
Can anyone explain/provide their work for this question? For further reference, it is the one where 2/3 of the question was taken out and the one that remained was "under constant volume." How would you figure out moles for this question, too?
- Tue Mar 13, 2018 11:45 pm
- Forum: Phase Changes & Related Calculations
- Topic: Midterm, Question 4B
- Replies: 2
- Views: 456
Midterm, Question 4B
Hi, can anyone provide the correct answer for this question? Thank you!
- Tue Mar 13, 2018 11:32 pm
- Forum: Balancing Redox Reactions
- Topic: Test 2 Question 8
- Replies: 2
- Views: 414
Test 2 Question 8
Hi!
For the electrochemistry test (which I took Wednesday in Dane's section), how do you tell what the value of n, the number of electrons exchanged is? And also what is the balanced equation for this question?
Thank you!
For the electrochemistry test (which I took Wednesday in Dane's section), how do you tell what the value of n, the number of electrons exchanged is? And also what is the balanced equation for this question?
Thank you!
- Tue Mar 06, 2018 3:44 pm
- Forum: Zero Order Reactions
- Topic: 15.16
- Replies: 1
- Views: 917
15.16
This isn't a homework problem, but could someone help me understand this question please? Thank you! In the reaction 4 Fe2+(aq) + O2(g) + 4 H3O+(aq) --> 4 Fe3+(aq) + 6 H2O(l), when the Fe2+ concentration alone was doubled, the rate increased by a factor of 8; when both the Fe2+ and the O2 concentrat...
- Mon Mar 05, 2018 11:28 pm
- Forum: Method of Initial Rates (To Determine n and k)
- Topic: Unique rates
- Replies: 4
- Views: 685
Re: Unique rates
Dr. Lavelle also summarizes information regarding unique rates in this thread below and, in general, it is a very informative thread:
viewtopic.php?f=145&t=28677
viewtopic.php?f=145&t=28677
- Mon Mar 05, 2018 11:22 pm
- Forum: General Rate Laws
- Topic: 15.17
- Replies: 4
- Views: 585
15.17
I'm a little confused as to how [C] is independent of the rate, as stated in the solutions manual.
- Mon Mar 05, 2018 11:11 pm
- Forum: Kinetics vs. Thermodynamics Controlling a Reaction
- Topic: Kinetics Test
- Replies: 2
- Views: 548
Kinetics Test
I know that our test only covers 15.1-15.6 but can someone please clarify which class lectures/material that covers and which homework problems would fit that frame?
- Wed Feb 28, 2018 10:29 am
- Forum: General Rate Laws
- Topic: 15.9
- Replies: 5
- Views: 664
Re: 15.9
Matthew Lee 3L wrote:On the syllabus, it says to omit this question from the homework.
I think Dr. Lavelle meant to omit Section 15.9 of the reading, not the actual homework question.
- Wed Feb 28, 2018 10:27 am
- Forum: General Rate Laws
- Topic: Finding reaction rate [ENDORSED]
- Replies: 5
- Views: 788
Re: Finding reaction rate [ENDORSED]
keep in mind that the rate of reaction is equal to the change in concentration over the change in time. and as said above, concentration is always found in mols
- Wed Feb 28, 2018 10:17 am
- Forum: Kinetics vs. Thermodynamics Controlling a Reaction
- Topic: Textbook Problems 15.3 and 15.5
- Replies: 7
- Views: 1085
Re: Textbook Problems 15.3 and 15.5
also regarding this question, is there a difference in how we should calculate rate of reaction and rate of formation?
- Tue Feb 20, 2018 6:21 pm
- Forum: Balancing Redox Reactions
- Topic: Homework Question 14.5
- Replies: 2
- Views: 388
Homework Question 14.5
For part a and part d of 14.5, what is the oxidation state of O3 and P4? Thank you!
- Tue Feb 20, 2018 6:07 pm
- Forum: Balancing Redox Reactions
- Topic: calculating oxidation states
- Replies: 2
- Views: 446
Re: calculating oxidation states
These are also some general rules that are really helpful: The oxidation state of an individual atom is 0. The total oxidation state of all atoms in: a neutral species is 0 and in an ion is equal to the ion charge. Group 1 metals have an oxidation state of +1 and Group 2 an oxidation state of +2 The...
- Tue Feb 20, 2018 6:03 pm
- Forum: Balancing Redox Reactions
- Topic: oxidation
- Replies: 4
- Views: 774
Re: oxidation
what about for O3 like in 14.5 part a?
- Mon Feb 12, 2018 3:49 pm
- Forum: Third Law of Thermodynamics (For a Unique Ground State (W=1): S -> 0 as T -> 0) and Calculations Using Boltzmann Equation for Entropy
- Topic: Degeneracy
- Replies: 2
- Views: 375
Re: Degeneracy
In lecture, we learned that degeneracy, W, is the number of ways of achieving a given energy state. W would be equal to the (number of microstates) ^ (number of particles in the system). To relate it to entropy, you would use the Boltzmann formula: S = kb(lnW).
- Mon Feb 12, 2018 3:38 pm
- Forum: Third Law of Thermodynamics (For a Unique Ground State (W=1): S -> 0 as T -> 0) and Calculations Using Boltzmann Equation for Entropy
- Topic: 9.25
- Replies: 2
- Views: 430
Re: 9.25
I would recommend drawing out the Lewis structures as well. Sometimes, the electron geometry will align with the number of orientation (in example 9.8 in the book), but it does not in this problem. The best way to be sure is to draw them out.
- Mon Feb 12, 2018 3:21 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Units for enthalpy
- Replies: 2
- Views: 425
Units for enthalpy
Can someone refresh my memory as to what Dr. Lavelle said in class today regarding units for enthalpy? My impression is that he said kJ and kJ/mol could be accepted interchangeably (when we were doing the Hess's Law question).
- Mon Feb 05, 2018 6:55 pm
- Forum: Concepts & Calculations Using Second Law of Thermodynamics
- Topic: 9.25
- Replies: 5
- Views: 586
Re: 9.25
to follow up, how do you know that W is 6?
- Mon Feb 05, 2018 10:25 am
- Forum: Gibbs Free Energy Concepts and Calculations
- Topic: DG = 0 [ENDORSED]
- Replies: 3
- Views: 1107
Re: DG = 0 [ENDORSED]
Adding on to what Ryan said, DeltaG at equilibrium means there's no net flow, or no tendency for the reaction to favor either direction.
- Mon Feb 05, 2018 10:23 am
- Forum: Concepts & Calculations Using Second Law of Thermodynamics
- Topic: Types of Disorders [ENDORSED]
- Replies: 5
- Views: 769
Re: Types of Disorders [ENDORSED]
Thermal disorder is the disorder arising from the thermal motion of the molecules (heating); an increase in heating supplied/temperature leads to an increase in the disorder of a system because the supply of energy increases the thermal motion of the molecules. Positional disorder refers to the diso...
- Mon Feb 05, 2018 10:16 am
- Forum: Entropy Changes Due to Changes in Volume and Temperature
- Topic: Clausius Inequality
- Replies: 1
- Views: 245
Clausius Inequality
Can someone explain the Clausius Inequality and its relevance to what we have been learning about thermodynamics? I found the book's explanation to be a bit confusing.
- Mon Jan 29, 2018 9:35 am
- Forum: Thermodynamic Definitions (isochoric/isometric, isothermal, isobaric)
- Topic: Useful Summary of Thermodynamic Definitions
- Replies: 55
- Views: 18645
Re: Useful Summary of Thermodynamic Definitions
will we be discussing these different types of systems each in detail or should we just know the general conceptual idea behind them such as is provided here? thank you!
- Mon Jan 29, 2018 9:32 am
- Forum: Environment, Fossil Fuels, Alternative Fuels
- Topic: biodiesel fuel [ENDORSED]
- Replies: 4
- Views: 1638
Re: biodiesel fuel [ENDORSED]
I think the most important difference about biodiesel fuel compared to regular fuel is that it is renewable (it can also be domestically produced and is cleaner); instead of being produced from fossil fuels, it can be manufactured from vegetable oils, animal fats, or recycled restaurant grease.
- Mon Jan 29, 2018 9:27 am
- Forum: Entropy Changes Due to Changes in Volume and Temperature
- Topic: Entropy Definition [ENDORSED]
- Replies: 2
- Views: 455
Entropy Definition [ENDORSED]
In class, Dr. Lavelle avoided using the word "disorder" to describe entropy but the book consistently uses it. How would we define/what was Dr. Lavelle's definition of entropy without using "disorder"?
- Mon Jan 22, 2018 2:54 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Cv vs. Cp [ENDORSED]
- Replies: 13
- Views: 11895
Re: Cv vs. Cp [ENDORSED]
Will we have to know the Cvm and Cpm values for the test?
- Mon Jan 22, 2018 2:44 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Concepts for Chapter 8 [ENDORSED]
- Replies: 5
- Views: 581
Concepts for Chapter 8 [ENDORSED]
I was wondering if anyone who had Dr. Lavelle last quarter has any suggestions as to how study for conceptual problems for this chapter. Thank you!
- Mon Jan 22, 2018 2:42 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Determining Enthalpy of Vaporization
- Replies: 4
- Views: 635
Re: Determining Enthalpy of Vaporization
Intermolecular forces are the forces of attraction between molecules. Ranked from weakest to strongest, the IMFs we learned last quarter in Chem 14A are London dispersion forces, dipole-induced dipole, ion-induced dipole, dipole-dipole, hydrogen bonding, and ion-dipole. What you are referring to wit...
- Sun Jan 21, 2018 2:43 am
- Forum: Calculating Work of Expansion
- Topic: Reversible vs Isothermal
- Replies: 3
- Views: 424
Re: Reversible vs Isothermal
Just to be clear, Dr. Lavelle said this wouldn't be on this week's test right?
- Sun Jan 21, 2018 2:42 am
- Forum: Concepts & Calculations Using First Law of Thermodynamics
- Topic: Exercise 8.7
- Replies: 2
- Views: 282
Re: Exercise 8.7
My TA said that sig figs aren't as big a deal this quarter because students end up focusing more on worrying about sig figs than they do about getting the actual concepts down/the problems right. But yes, answer is written in scientific notation just for the purpose of sig figs.
- Tue Jan 16, 2018 11:46 am
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Bond Enthalpies
- Replies: 2
- Views: 395
Bond Enthalpies
For bond enthalpies, I was wondering how we know which bonds to exclude from our calculations. Is it just the ones that repeat in the reactants and the products?
- Tue Jan 16, 2018 11:44 am
- Forum: Phase Changes & Related Calculations
- Topic: Good hw questions to practice?
- Replies: 2
- Views: 300
Re: Good hw questions to practice?
I found the sections under "Reaction Enthalpies," "Hess's Law," "Standard Enthalpies of Formation," and "Bond Formation" to align with what we have learned in class up to this point.
- Tue Jan 16, 2018 11:39 am
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: living plant
- Replies: 4
- Views: 404
Re: living plant
A living plant is an open system. Just think about it in terms of photosynthesis where it takes carbon dioxide from its surroundings to produce oxygen; thus there's a constant exchange/flow of mass and energy between the plant and its surroundings.
- Sun Jan 14, 2018 10:46 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Standard States
- Replies: 3
- Views: 7291
Re: Standard States
A standard state of a substance is its phase (the most stable one) at 1 atm and 25°C. Liquid is the standard state for mercury and bromine. Gas is the standard state for noble gases, halogens, fluorine, chlorine, hydrogen, nitrogen, and oxygen, while all other elements are solid in their standard st...
- Wed Jan 10, 2018 11:33 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Closed System
- Replies: 7
- Views: 777
Closed System
In discussion, one of the examples for a closed system my TA used was a coolant in a refrigerator coil. Can someone explain how it functions in a manner that makes it a closed system?
- Wed Jan 10, 2018 11:25 pm
- Forum: Student Social/Study Group
- Topic: Post All Chemistry Jokes Here
- Replies: 9651
- Views: 3667087
Re: Post All Chemistry Jokes Here
Anne 2L wrote:what did the ice cube say to his mom as he was melting
MOM ITS JUST A PHASE
- Wed Jan 10, 2018 11:13 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Bond Enthalpies
- Replies: 6
- Views: 2347
Bond Enthalpies
Can someone please explain to me why bond enthalpies (method 2) are always positive? Thank you!