## Search found 53 matches

Sun Mar 18, 2018 4:24 pm
Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
Topic: Is enthalpy a state function?
Replies: 12
Views: 954

### Re: Is enthalpy a state function?

we use the hess's law approach to add up enthalpies, which is only possible because it is a state function
Sun Mar 18, 2018 4:21 pm
Forum: Reaction Mechanisms, Reaction Profiles
Topic: steady state vs pre equilibrium
Replies: 3
Views: 312

### Re: steady state vs pre equilibrium

what makes steady state more flexible in contrast to pre equilibrium?
Sun Mar 18, 2018 4:18 pm
Forum: Second Order Reactions
Topic: Derivations
Replies: 4
Views: 557

### Re: Derivations

the graph of 1/[reactant] over time has a positive slope which is equal to k for 2nd order reactions
Sun Mar 18, 2018 4:12 pm
Forum: Reaction Mechanisms, Reaction Profiles
Topic: Pseudo Rate Laws
Replies: 5
Views: 597

### Re: Pseudo Rate Laws

One reactant is in large excess so we can ignore its concentration and find the psuedo rate law of the other reactant.
Fri Mar 16, 2018 7:28 pm
Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
Topic: Winter Final 2012 #3
Replies: 1
Views: 123

### Winter Final 2012 #3

For this problem it tells us that there is CrCl3 (aq), CuSO4 (aq), copper wire, and chrome plated metal. How do we know that the copper wire is the cathode and that the chrome plated metal is the anode?
Fri Mar 16, 2018 12:00 am
Forum: Third Law of Thermodynamics (For a Unique Ground State (W=1): S -> 0 as T -> 0) and Calculations Using Boltzmann Equation for Entropy
Topic: Winter 2011 Final #1C
Replies: 1
Views: 221

### Winter 2011 Final #1C

Why does NO have more residual entropy than BF3?
Thu Mar 15, 2018 5:43 pm
Forum: Gibbs Free Energy Concepts and Calculations
Topic: Relationship between K and G
Replies: 1
Views: 392

### Relationship between K and G

Why is it that when K<1, G is + and when K>1, G is -? I know that this is because of the equation G = -RTlnK, but what does it mean conceptually?
Tue Mar 13, 2018 10:03 pm
Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
Topic: Breaking ATP bonds and engergy
Replies: 1
Views: 146

### Breaking ATP bonds and engergy

If breaking bonds is an endothermic process and requires energy, then why does breaking down ATP into ADP also release energy?
Sun Mar 11, 2018 11:44 pm
Forum: *Free Energy of Activation vs Activation Energy
Topic: Relation between k and activation energy
Replies: 6
Views: 1700

### Re: Relation between k and activation energy

Reactions generally speed up when temperature increases and slow down when temperature decreases. This means that k increases with increasing temperature, which in turn increases the overall rate of the reaction.
Sun Mar 11, 2018 11:42 pm
Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
Topic: Cell Diagram Order for Same Phases
Replies: 4
Views: 285

### Re: Cell Diagram Order for Same Phases

I asked my TA and he says it doesn't matter what order they are in if they are the same phase.
Sun Mar 11, 2018 11:38 pm
Forum: Reaction Mechanisms, Reaction Profiles
Topic: Intermediates in Rate law
Replies: 3
Views: 841

### Re: Intermediates in Rate law

Yes, the reaction for the final rate law should not contain intermediates. Solve for the intermediates in terms of the reactants that should be in the final reaction and substitute it instead of the concentration of the intermediate if you have to.
Sun Mar 11, 2018 6:19 pm
Forum: Reaction Mechanisms, Reaction Profiles
Topic: SN2
Replies: 3
Views: 184

### Re: SN2

It is important in organic chemistry and relates to gibbs free energy
Sun Mar 11, 2018 6:06 pm
Forum: Arrhenius Equation, Activation Energies, Catalysts
Topic: 15.69
Replies: 2
Views: 162

### Re: 15.69

rate = k[reactant concentrations] so if k increases by a factor of 1000, the rate would also increase by a factor of 1000
Sat Mar 10, 2018 9:22 pm
Forum: Second Order Reactions
Topic: the slope
Replies: 12
Views: 667

### Re: the slope

0 and first order: -k
second order: k
Thu Feb 22, 2018 9:54 pm
Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
Topic: 14.29 States of redox couples
Replies: 3
Views: 169

### 14.29 States of redox couples

For 29, how do we know which elements are aqueous, solid, etc. when we write the cell diagram?
Thu Feb 22, 2018 2:19 pm
Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
Topic: Cell Diagram Order for Same Phases
Replies: 4
Views: 285

### Cell Diagram Order for Same Phases

When there are 2 elements in the same phase in a cell diagram separated by a comma like in 14.17 with
Pt(s)|Fe3+(aq), Fe2+(aq)||H+(aq), MnO4-(aq), Mn2+(aq)|Pt(s), how do you know which element comes first within the series of commas?
Wed Feb 14, 2018 1:54 pm
Forum: Calculating Work of Expansion
Topic: Calculating work for winter 2013 midterm 4.B.
Replies: 4
Views: 262

### Re: Calculating work for winter 2013 midterm 4.B.

But it uses w = -nRTln(P1/P2), not -nRTln(V1/V2). Shouldn't we use both equations since there is both a change in pressure and volume?
Wed Feb 14, 2018 1:38 pm
Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
Topic: What does E stand for?
Replies: 3
Views: 272

### What does E stand for?

In the Winter 2014 midterm 5C, it asks which are state functions for w, G, q, H, E, and S.
G,H,S are state functions and w,q, E are not. I'm not sure what E is in this problem.
Wed Feb 14, 2018 1:35 pm
Forum: Third Law of Thermodynamics (For a Unique Ground State (W=1): S -> 0 as T -> 0) and Calculations Using Boltzmann Equation for Entropy
Topic: Standard molar entropy vs. residual entropy
Replies: 2
Views: 283

### Standard molar entropy vs. residual entropy

I'm a bit confused about the distinction between these two. In the winter 2013 midterm 5B, it tells us that CH3F<CH2F2<CHF3<CF4 in terms of increasing standard molar entropy. I think this is because F is more massive, so that it has more elementary particles. But then, doesn't CH3F have more possibl...
Wed Feb 14, 2018 1:28 pm
Forum: Calculating Work of Expansion
Topic: Calculating work for winter 2013 midterm 4.B.
Replies: 4
Views: 262

### Calculating work for winter 2013 midterm 4.B.

Going for point B to point C has a change in both pressure and volume, but the answer seems to only account for the work done based on the change in pressure. Yet it states both equations. Why do we not calculate the work done by change in volume?
Wed Feb 14, 2018 1:23 pm
Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
Topic: Winter 2011 Midterm #1
Replies: 2
Views: 356

### Re: Winter 2011 Midterm #1

But why is it C = nq/T and not just C= q/tusing the q = CT formula?
Tue Feb 13, 2018 8:06 pm
Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
Topic: Winter 2011 Midterm #1
Replies: 2
Views: 356

### Winter 2011 Midterm #1

For this problem why do we not use the equation q=mC(deltaT) to find C?
Thu Feb 08, 2018 9:27 am
Forum: Gibbs Free Energy Concepts and Calculations
Topic: 9.83 moles
Replies: 1
Views: 124

### 9.83 moles

In this problem, why are the moles of HBr formed 2(5.35x10^-3) and not just 5.35x10^-3?
Thu Feb 08, 2018 12:21 am
Forum: Concepts & Calculations Using Second Law of Thermodynamics
Topic: 9.61 sig figs
Replies: 2
Views: 186

### 9.61 sig figs

Can someone explain why the answers for each part of this problem has the number of sig figs it has? I don't see where it is coming from.
Sun Feb 04, 2018 11:54 pm
Forum: Phase Changes & Related Calculations
Topic: The universe
Replies: 9
Views: 436

### Re: The universe

nothing can be exchanged outside the universe because nothing outside the universe exists
Sun Feb 04, 2018 11:44 pm
Forum: Calculating Standard Reaction Entropies (e.g. , Using Standard Molar Entropies)
Topic: Higher Molar Entropy
Replies: 4
Views: 260

### Re: Higher Molar Entropy

Also, a more massive element would have a higher molar entropy because there are fundamental particles (electrons, protons, neutrons), and so would a molecule made up of multiple atoms vs. one atom.
Sun Feb 04, 2018 11:37 pm
Forum: Thermodynamic Systems (Open, Closed, Isolated)
Topic: test question 5
Replies: 5
Views: 326

### Re: test question 5

So in this question, is the system considered the contents of the cooler as well as the cooler itself, rather than just the contents being the system?
Sun Feb 04, 2018 11:24 pm
Forum: Concepts & Calculations Using Second Law of Thermodynamics
Topic: 9.37 d
Replies: 1
Views: 90

### 9.37 d

For 37 part d) 4KClO3(s) => 3KClO4(s) + KCl(s) why are the products more ordered than the reactants, resulting in a negative entropy?
Sun Feb 04, 2018 12:36 am
Forum: Thermodynamic Systems (Open, Closed, Isolated)
Topic: Isolated
Replies: 9
Views: 451

### Re: Isolated

There isn't any exchange in heat or matter with the surroundings of an isolated system, but heat can still be generated inside the system itself. This change is isolated because it is contained within the system, and the heat is not released into the surroundings.
Thu Jan 25, 2018 12:40 pm
Forum: Phase Changes & Related Calculations
Topic: Change in internal energy as a state function
Replies: 2
Views: 539

### Change in internal energy as a state function

Can someone please explain to me how delta U is a state function and = w + q, but w and q are not state functions?
Sun Jan 21, 2018 10:08 pm
Forum: Phase Changes & Related Calculations
Topic: Carbon as graphite [ENDORSED]
Replies: 7
Views: 416

### Carbon as graphite[ENDORSED]

Can someone explain to me again why carbon is more stable as graphite and why in 67 b, it isn't a gas like hydrogen and oxygen?
Thu Dec 07, 2017 7:00 pm
Forum: Conjugate Acids & Bases
Topic: HW 12.45
Replies: 4
Views: 399

### Re: HW 12.45

pkb = 14 - pka
The lower the pkb is, the stronger the base, so the higher the pka = smaller pkb = stronger base
Thu Dec 07, 2017 6:42 pm
Forum: Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions
Topic: Change in concentration
Replies: 2
Views: 160

### Re: Change in concentration

From the homework problems that we've done, it seems that they usually tell us if the change in pressure is caused by adding gas (which would not shift the reaction) or by changing volume, so I would assume the test would do the same.
Thu Dec 07, 2017 6:40 pm
Forum: *Shrodinger Equation
Topic: Midterm Question
Replies: 1
Views: 333

### Re: Midterm Question

Use the formula Ephoton = work function + Kinetic energy of electron. The KE of an electron is (1/2)mv^2 so Ephoton = work function + (1/2)mv^2. Convert the 2 given energies to joules and plug them in for Ephoton and work function. The mass of an electron is a constant so you have all the needed qua...
Thu Dec 07, 2017 4:28 pm
Forum: Bronsted Acids & Bases
Topic: Single arrow vs. double arrows
Replies: 2
Views: 406

### Single arrow vs. double arrows

Does it matter if we use double arrows or a single arrow when writing the reactions for strong acids and bases? For example, the dissociation of H2SO4 on 12.3a on the homework is a strong acid reaction, so I was under the impression that it would be a single arrow but the solutions manual shows a do...
Tue Dec 05, 2017 5:06 pm
Forum: Shape, Structure, Coordination Number, Ligands
Topic: Shape of [Co(en)2(Br)2]
Replies: 1
Views: 238

### Shape of [Co(en)2(Br)2]

On Q4B on the 2010 final, why is the shape of [Co(en)2(Br)2] octahedral if the coordination number is 4?
Mon Dec 04, 2017 1:50 am
Forum: Bronsted Acids & Bases
Topic: Fundamentals J 5 Neutralization
Replies: 2
Views: 212

### Fundamentals J 5 Neutralization

For the reaction in 5b with (CH3)3N and HNO3, why does it not produce water and a salt? Is it not a neutralization reaction?
Sat Dec 02, 2017 4:03 pm
Forum: Equilibrium Constants & Calculating Concentrations
Topic: Kc [ENDORSED]
Replies: 3
Views: 209

### Re: Kc[ENDORSED]

You compare heat in endothermic reactions to a reactant (since it is required to start the reaction) and heat in exothermic reactions to a product (it is produced by the reaction). If you increase a reactant, more product will form, as in adding heat to an endothermic reaction. If you increase produ...
Sat Dec 02, 2017 3:55 pm
Forum: Naming
Topic: naming compounds [ENDORSED]
Replies: 3
Views: 258

### Re: naming compounds[ENDORSED]

The transition metal, which is the central metal atom, is the Lewis acid and it accepts electron pairs. This element comes last in the naming process. The surrounding ligands are Lewis bases and they are the electron donors.
Sat Dec 02, 2017 3:51 pm
Forum: Properties & Structures of Inorganic & Organic Acids
Topic: Strong acid vs weak acid [ENDORSED]
Replies: 7
Views: 434

### Re: Strong acid vs weak acid[ENDORSED]

Does the strength of acids and bases relate in anyway to electronegativity differences or ionization energy?
Tue Nov 28, 2017 9:04 pm
Forum: Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions
Topic: 11.89 part a
Replies: 1
Views: 158

### 11.89 part a

Could someone explain to me how to find the balanced chemical equation for this problem? I understand how to do part b based on the graph and the answer for part a, but I am unsure of how to find the coefficients for the equation.
Wed Nov 22, 2017 3:46 pm
Forum: Lewis Structures
Topic: Extended Octets
Replies: 1
Views: 133

### Extended Octets

For elements with extended octets, how do we determine to what extent they can be expanded to?
Tue Nov 14, 2017 11:51 pm
Forum: Determining Molecular Shape (VSEPR)
Topic: How to Find Bond Angle
Replies: 2
Views: 167

### Re: How to Find Bond Angle

The bond angles are determined theoretically by the different geometric shapes of the compounds with consideration of any lone pairs that may change the arrangement.
Tue Nov 14, 2017 11:29 pm
Forum: Determining Molecular Shape (VSEPR)
Topic: Ch 4 #11 Part b and more
Replies: 2
Views: 310

### Re: Ch 4 #11 Part b and more

ICl3 has 5 regions of electron density with the 3 Cl atoms and 2 lone pairs, where as NH3 has 4 regions with 3 H atoms and 1 lone pair. The 5 regions of ICl3 makes the electron arrangement trigonal bipyramidal, and the 2 lone pairs make it T shaped unlike NH3 which has a tetrahedral arrangement and ...
Tue Nov 14, 2017 10:59 pm
Forum: Determining Molecular Shape (VSEPR)
Topic: Memorizing Shapes
Replies: 2
Views: 163

### Re: Memorizing Shapes

I think it would be best to memorize all the shapes and angles in the diagrams of the textbook, including t shaped.
Tue Nov 14, 2017 10:54 pm
Forum: Hybridization
Topic: Diapole
Replies: 4
Views: 335

### Re: Diapole

A dipole moment is where one atom is more electronegative than the other, which results in separation of positive and negative charges.
Tue Nov 14, 2017 10:51 pm
Forum: Hybridization
Topic: Purpose of hybridization [ENDORSED]
Replies: 5
Views: 1499

### Re: Purpose of hybridization[ENDORSED]

Hybridization results in orbitals with lower energy compared to separate s and p orbitals.
Sun Nov 12, 2017 12:11 am
Forum: DeBroglie Equation
Topic: When to use DeBroglie Equation
Replies: 4
Views: 249

### Re: When to use DeBroglie Equation

the equation is wavelength = planck's constant / mass x velocity. If there is 0 mass and/or velocity, the denominator would be zero and we cannot use the equation.
Tue Nov 07, 2017 5:00 pm
Forum: Ionic & Covalent Bonds
Topic: Order of Electrons Lost by Ions
Replies: 2
Views: 297

### Order of Electrons Lost by Ions

Why is it that 4s is filled before 3d but when cations are formed, electrons are taken from 4s before 3d and not 3d first?
Mon Oct 30, 2017 9:10 pm
Forum: Electron Configurations for Multi-Electron Atoms
Topic: Valence-shell Configuration for Transition Metals
Replies: 1
Views: 164

### Re: Valence-shell Configuration for Transition Metals

I believe by "group 5 transition metals" it means the fifth column of the transition metals starting with Mn, and not group 5 of the periodic table. If you use the fifth column then it gives you (n-1)d^5ns^2 like in the solutions manual.
Fri Oct 27, 2017 10:29 pm
Forum: Resonance Structures
Topic: Formal charge question
Replies: 3
Views: 296

### Re: Formal charge question

The lower the formal charge is, the more stable the molecule is and the less likely it will form reactions. Since the model with double bonds has a lower formal charge, it has a higher stability and is a better representation.
Fri Oct 27, 2017 10:24 pm
Forum: Resonance Structures
Topic: Resonance in SO4
Replies: 5
Views: 405

### Re: Resonance in SO4

I think the goal is the have the formal charge of all atoms to be as low as possible but having 4 double bonds for S is not possible.
Mon Oct 16, 2017 5:59 pm
Forum: Properties of Light
Topic: Rydberg's Constant
Replies: 4
Views: 453

### Re: Rydberg's Constant

The two numbers seem to be different because 3.29 x 10^15 has the units of s^-1 and the number you found online is in m^-1. For 13, we would use 3.29 x 10^15 s^-1 to cancel with the s^-1 unit in the speed of light constant.