Search found 56 matches
- Thu Mar 15, 2018 11:07 am
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: 15.101b
- Replies: 3
- Views: 446
Re: 15.101b
Also, why is H20 not included in the K of the first step reaction? Is it because it's a catalyst?
- Thu Mar 15, 2018 11:06 am
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: 15.101b
- Replies: 3
- Views: 446
Re: 15.101b
^I agree. Shouldn't you use the K of the 3rd step reaction and substitute that in for OH-?
- Thu Mar 15, 2018 10:45 am
- Forum: *Enzyme Kinetics
- Topic: Question 15.85
- Replies: 4
- Views: 972
Re: Question 15.85
Can someone please explain how we draw the activated complex?
- Tue Mar 13, 2018 10:39 am
- Forum: Arrhenius Equation, Activation Energies, Catalysts
- Topic: Hw 15.67
- Replies: 5
- Views: 1618
Re: Hw 15.67
Where did this catalyzed/uncatalyzed set up come from?
- Mon Mar 12, 2018 10:27 pm
- Forum: Arrhenius Equation, Activation Energies, Catalysts
- Topic: 15.63
- Replies: 1
- Views: 291
Re: 15.63
Why isn't it ln(k2, k1)=Ea/R((1/T1)-(1/T2)? Thats what I used and got the same answer as the solutions manual.
- Mon Mar 12, 2018 12:18 pm
- Forum: Administrative Questions and Class Announcements
- Topic: FINAL
- Replies: 9
- Views: 1436
Re: FINAL
Good morning! Are the functional groups that Dr. Lavelle went over in class going to be on the final as well? Just wondering because this was not part of the Kinetics syllabus :)
- Sun Mar 11, 2018 11:13 pm
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: Intermediates
- Replies: 6
- Views: 772
Re: Intermediates
Yes, it would still be an intermediate because it helped to promote the reaction to the next step and is not a final product in the overall reaction.
- Sun Mar 11, 2018 11:10 pm
- Forum: Administrative Questions and Class Announcements
- Topic: FINAL
- Replies: 9
- Views: 1436
FINAL
How much of Chapter 15 will be on the final? Will we have time to cover everything?
- Thu Mar 08, 2018 9:53 am
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: Slow step
- Replies: 3
- Views: 430
Re: Slow step
Isn't it determined by the likelihood that the molecules of the reactants will collide simultaneously?
- Thu Mar 08, 2018 9:52 am
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: Slow step
- Replies: 3
- Views: 430
Re: Slow step
How do you know it has a smaller k value?
- Thu Mar 08, 2018 9:51 am
- Forum: Administrative Questions and Class Announcements
- Topic: practice final?
- Replies: 4
- Views: 670
Re: practice final?
Hi, I noticed that Lyndon was only reviewing Electrochemistry and Kinetics. DOES THIS MEAN NO PRACTICE FINAL????
- Mon Mar 05, 2018 7:05 pm
- Forum: Kinetics vs. Thermodynamics Controlling a Reaction
- Topic: How to tell difference btwn thermo and kinetics [ENDORSED]
- Replies: 7
- Views: 1008
Re: How to tell difference btwn thermo and kinetics [ENDORSED]
Can you please provide an example problem where we would have to apply this concept?
- Thu Mar 01, 2018 5:45 pm
- Forum: First Order Reactions
- Topic: 15.27
- Replies: 7
- Views: 1390
Re: 15.27
Never mind I see that there’s different ways to add/subtract things to both sides. I’m a brick
- Thu Mar 01, 2018 5:40 pm
- Forum: First Order Reactions
- Topic: 15.27
- Replies: 7
- Views: 1390
Re: 15.27
For part c, shouldn’t you get on (0.15) when subtracting the natural log of the concentrations instead of ln (1/0.15)?
- Tue Feb 20, 2018 11:52 am
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: 14.11d
- Replies: 1
- Views: 255
14.11d
How do you come up with the oxidizing half reduction? Why is H+ on the same side as the O2?
- Tue Feb 20, 2018 11:51 am
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: 14.13b
- Replies: 2
- Views: 312
Re: 14.13b
What indicates that the reaction occurs in the same solution?
- Wed Feb 14, 2018 1:00 am
- Forum: Third Law of Thermodynamics (For a Unique Ground State (W=1): S -> 0 as T -> 0) and Calculations Using Boltzmann Equation for Entropy
- Topic: cis vs trans [ENDORSED]
- Replies: 4
- Views: 2653
Re: cis vs trans [ENDORSED]
is there a trick to finding the number of available positions?
- Tue Feb 13, 2018 10:46 am
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: 8.53
- Replies: 2
- Views: 293
Re: 8.53
how can we assume that there is no work being done?
- Sat Feb 10, 2018 6:48 pm
- Forum: Entropy Changes Due to Changes in Volume and Temperature
- Topic: 9.71b
- Replies: 1
- Views: 398
9.71b
Can someone please give me a better answer than the one in the solutions manual? How would you be able to tell whether the phase change would change the answer without looking at the values?
- Sat Feb 10, 2018 5:36 pm
- Forum: Gibbs Free Energy Concepts and Calculations
- Topic: 9.65d
- Replies: 1
- Views: 240
Re: 9.65d
or because it does not have a significant impact on the whether the delta S value is positive the S(s) is irrelevant regarding which solid state it is in?
- Sat Feb 10, 2018 5:35 pm
- Forum: Gibbs Free Energy Concepts and Calculations
- Topic: 9.65d
- Replies: 1
- Views: 240
9.65d
How do you know which solid state of S(s) to use for the standard entropy?
- Sun Feb 04, 2018 8:36 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: combustion
- Replies: 4
- Views: 513
Re: combustion
Yes, the equation was provided in the book and by Dr. Lavelle.
- Sun Feb 04, 2018 8:33 pm
- Forum: Entropy Changes Due to Changes in Volume and Temperature
- Topic: Problem 9.19 about Standard Entropy
- Replies: 6
- Views: 837
Re: Problem 9.19 about Standard Entropy
You have to cool it down to find the standard entropy of vaporization for 85 degrees not 100.
- Sun Feb 04, 2018 8:31 pm
- Forum: Entropy Changes Due to Changes in Volume and Temperature
- Topic: 9.13
- Replies: 7
- Views: 1013
Re: 9.13
We use Cv because N2 is an ideal gas, so we used 5/2R because N2 is diatomic. My TA said that the answer in the solutions manual was wrong. Hope this helps!
- Sun Jan 28, 2018 8:34 pm
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: Question from test?
- Replies: 4
- Views: 625
Re: Question from test?
Closed system. The ice pack can still exchange heat with its surroundings (keeping a sandwich in your lunch bag cold), but it cannot exchange matter.
- Sun Jan 28, 2018 8:24 pm
- Forum: Calculating Work of Expansion
- Topic: work done on and by the system
- Replies: 12
- Views: 1430
Re: work done on and by the system
When work is positive, work is done on the system. When work is negative, work is done by the system.
- Sun Jan 21, 2018 1:11 pm
- Forum: Phase Changes & Related Calculations
- Topic: Test 1 translation and rotational energy?
- Replies: 1
- Views: 227
Test 1 translation and rotational energy?
Will translational and rotational energy be on the test? I don't remember it being covered in lecture, but would just like to double check. Thanks.
- Sun Jan 21, 2018 12:50 pm
- Forum: Phase Changes & Related Calculations
- Topic: question 8.41
- Replies: 5
- Views: 506
Re: question 8.41
why do you not use q=nCdT because dH is the molar enthalpy of change?
- Tue Jan 16, 2018 2:13 pm
- Forum: Calculating Work of Expansion
- Topic: Homework Question 8.3
- Replies: 4
- Views: 656
Re: Homework Question 8.3
Thank you that makes so much sense!
- Tue Jan 16, 2018 2:12 pm
- Forum: Phase Changes & Related Calculations
- Topic: 8.37
- Replies: 3
- Views: 248
Re: 8.37
Shoot just saw this. Thank you Kelly!
- Tue Jan 16, 2018 2:11 pm
- Forum: Phase Changes & Related Calculations
- Topic: 8.37
- Replies: 3
- Views: 248
Re: 8.37
nevermind I understand now
- Tue Jan 16, 2018 10:24 am
- Forum: Phase Changes & Related Calculations
- Topic: 8.37
- Replies: 3
- Views: 248
8.37
How do you know how to find the enthalpy? I don't understand how they derived the answer in the solutions manual.
- Sun Jan 14, 2018 3:00 pm
- Forum: Calculating Work of Expansion
- Topic: Homework Question 8.3
- Replies: 4
- Views: 656
Re: Homework Question 8.3
How do you know that q is 0 when finding the internal energy?
- Sat Dec 09, 2017 8:52 pm
- Forum: Administrative Questions and Class Announcements
- Topic: Practice Test Fall 2017 [ENDORSED]
- Replies: 19
- Views: 3442
Re: Practice Test Fall 2017 [ENDORSED]
Is MO theory going to be on the final? It's in the course reader and I've seen a few questions asked about it on Chem Community.
- Sat Dec 09, 2017 8:24 pm
- Forum: Administrative Questions and Class Announcements
- Topic: Final [ENDORSED]
- Replies: 6
- Views: 1055
Re: Final [ENDORSED]
THIS IS NOT ON THE FINAL104917030 wrote:correct me if I am wrong but Dr. Lavelle did say that salts would not be on the final because we did not go over that lesson in class, due to classes being cancelled because of the fire.
- Sat Dec 09, 2017 1:07 pm
- Forum: Naming
- Topic: Differences between systems of naming [ENDORSED]
- Replies: 1
- Views: 290
Differences between systems of naming [ENDORSED]
If you name a compound using the UPAC method (bromido rather than bromo) and then name CN- with a bond on the nitrogen "isocyano" (as seen in the book) would that be considered breaking the rules? Should you call it "isocyanido" to be consistent with the UPAC naming system?
- Sat Dec 09, 2017 12:52 pm
- Forum: Administrative Questions and Class Announcements
- Topic: Practice Test Fall 2017 [ENDORSED]
- Replies: 19
- Views: 3442
Re: Practice Test Fall 2017 [ENDORSED]
On worksheet 7:
1. Would we be marked down for putting the concentrations in brackets? Never heard of this...
4. Why was en put before Iodide? I thought anionic ligands were supposed to be put before neutral when writing the formula?
1. Would we be marked down for putting the concentrations in brackets? Never heard of this...
4. Why was en put before Iodide? I thought anionic ligands were supposed to be put before neutral when writing the formula?
- Thu Dec 07, 2017 11:22 am
- Forum: Administrative Questions and Class Announcements
- Topic: REVIEW WORKSHEET (CH 3 & 4) FALL 2017 [ENDORSED]
- Replies: 5
- Views: 1028
Re: REVIEW WORKSHEET (CH 3 & 4) FALL 2017 [ENDORSED]
Hi, given the circumstances at hand, can you please post the solutions?
- Sun Dec 03, 2017 11:10 pm
- Forum: Calculating pH or pOH for Strong & Weak Acids & Bases
- Topic: 12.29
- Replies: 1
- Views: 182
12.29
When trying to find the pOH, should we write out the chemical equation? Also, why do bases not react with water?
- Sun Dec 03, 2017 11:08 pm
- Forum: Acidity & Basicity Constants and The Conjugate Seesaw
- Topic: 12.45 [ENDORSED]
- Replies: 2
- Views: 373
12.45 [ENDORSED]
So the back of the book has two different ways of arriving at the fact that 2,4,6 trichlorophenol. Is it enough to just look at which compound has a greater Ka value or do we need to know that the chlorine atoms have a greater withdrawing power?
- Sun Nov 26, 2017 8:45 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: 45 part c
- Replies: 1
- Views: 286
45 part c
How do you figure out which one is more stable?
- Sun Nov 26, 2017 8:44 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: #7
- Replies: 1
- Views: 151
#7
Can someone please explain to me what the diagrams represent and how you can tell which state of the equation it's in?
- Sun Nov 19, 2017 5:10 pm
- Forum: Naming
- Topic: Ch. 17 Problem 29a [ENDORSED]
- Replies: 4
- Views: 489
Re: Ch. 17 Problem 29a [ENDORSED]
Why do you change iron to ferrate?
- Thu Nov 16, 2017 2:12 am
- Forum: Determining Molecular Shape (VSEPR)
- Topic: Chapter 4 19b
- Replies: 1
- Views: 184
Chapter 4 19b
How do you know that the shape of (CH3)2Be is tetrahedral? I got that the central atom was Be and it had 4 regions of e- density but 2/4 regions were electron pairs.
- Sun Nov 12, 2017 7:39 pm
- Forum: Lewis Structures
- Topic: Midterm Question CH3SH
- Replies: 5
- Views: 1063
Re: Midterm Question CH3SH
I got that 3 Hydrogens are bonded to Carbon and Carbon also shares a single bond with Sulfur. Sulfur has 2 sets of lone pairs. Hydrogen is bonded to Sulfur. Carbon is the least electronegative, so it is the central atom. With this configuration the formal charge for each element is 0.
- Sun Nov 12, 2017 7:30 pm
- Forum: Ionic & Covalent Bonds
- Topic: Midterm
- Replies: 6
- Views: 1048
Re: Midterm
I got:
KCl is ionic
N2 is non polar because the structure equally shares the electrons because the same element has the same electronegativity value
SiO2 is polar
KCl is ionic
N2 is non polar because the structure equally shares the electrons because the same element has the same electronegativity value
SiO2 is polar
- Mon Oct 30, 2017 5:22 pm
- Forum: Electron Configurations for Multi-Electron Atoms
- Topic: 2.53 [ENDORSED]
- Replies: 4
- Views: 676
2.53 [ENDORSED]
Why does Ge only have one unpaired electron? Shouldn't it be 3 unpaired electrons because it's 4p2?
- Mon Oct 30, 2017 5:13 pm
- Forum: Quantum Numbers and The H-Atom
- Topic: Question 2.19 b.
- Replies: 5
- Views: 411
Re: Question 2.19 b.
For 3p, you know that n=3 and the fact that it's in the p-orbital indicates that l=1. Therefore, there are 3 values for ml. 1,0,-1.
- Mon Oct 30, 2017 5:09 pm
- Forum: Electron Configurations for Multi-Electron Atoms
- Topic: Ground state vs. Excited State
- Replies: 2
- Views: 349
Ground state vs. Excited State
How do you differentiate whether the electron is in the excited state or the ground state?
- Wed Oct 25, 2017 10:00 pm
- Forum: Wave Functions and s-, p-, d-, f- Orbitals
- Topic: 2.1 part d
- Replies: 4
- Views: 450
2.1 part d
How do we know that the radius of the atom increases as an electron goes from n=1 to n=2? Is it because the electron is moving further away from the nucleus?
- Sun Oct 22, 2017 7:42 pm
- Forum: Heisenberg Indeterminacy (Uncertainty) Equation
- Topic: Test 3 [ENDORSED]
- Replies: 5
- Views: 814
Re: Test 3 [ENDORSED]
What sections of what chapter does test 3 cover?
- Sun Oct 22, 2017 5:56 pm
- Forum: Heisenberg Indeterminacy (Uncertainty) Equation
- Topic: Test 2
- Replies: 5
- Views: 735
Re: Test 2
When do we get test 2 back?
- Sun Oct 15, 2017 1:02 pm
- Forum: Properties of Light
- Topic: Speed of Light Constant
- Replies: 18
- Views: 1782
I don't know how to post my own topic
Can someone please explain how to start a new topic on this please? I also don't understand 30 C on the post module for Photoelectric effect
- Sun Oct 15, 2017 12:55 pm
- Forum: Properties of Light
- Topic: Photons
- Replies: 7
- Views: 795
Photoelectric effect Module
How do you do 29 B?
- Thu Oct 05, 2017 12:47 am
- Forum: Molarity, Solutions, Dilutions
- Topic: G11
- Replies: 2
- Views: 546
Re: G11
convert mmol to moles. Rearrange the equation M= n/v to V=n/m.
- Thu Oct 05, 2017 12:45 am
- Forum: Limiting Reactant Calculations
- Topic: L #39
- Replies: 4
- Views: 577
L #39
why do you use O instead of O2 for this problem?