Search found 30 matches
- Sun Jun 10, 2018 4:46 pm
- Forum: Shape, Structure, Coordination Number, Ligands
- Topic: coordination number=polydentate number?
- Replies: 5
- Views: 608
Re: coordination number=polydentate number?
I think double bonds are considered as one total ligand attachment.
- Sun Jun 10, 2018 4:44 pm
- Forum: Shape, Structure, Coordination Number, Ligands
- Topic: 17.29
- Replies: 2
- Views: 401
Re: 17.29
When determining the charge of the central atom, I think you have to consider the ligands as separate molecules. For the CN ligand, you would have to draw its Lewis structure under the assumption that it was not bonded with Fe, and that it had a full octet. So you would get CN-.
- Sun Jun 10, 2018 4:39 pm
- Forum: Shape, Structure, Coordination Number, Ligands
- Topic: Charge of ligands
- Replies: 5
- Views: 732
Re: Charge of ligands
There are some ligands that are common polyatomic ions, like oxalate (C2O4)2-. Some of the textbook problems use these repeatedly, so memorizing some ions could save time.
- Sun Jun 03, 2018 1:06 am
- Forum: Hybridization
- Topic: Amplitude and Hybridization
- Replies: 2
- Views: 447
Re: Amplitude and Hybridization
What part of the chapter was this topic in?
- Sun Jun 03, 2018 1:03 am
- Forum: Determining Molecular Shape (VSEPR)
- Topic: Lone Pair Placement [ENDORSED]
- Replies: 2
- Views: 423
Re: Lone Pair Placement [ENDORSED]
As mentioned in the previous post, some molecules like the trigonal bipyramidal shape have multiple intersecting planes of bonded atoms. In the horizontal plane of the trigonal bipyramidal shape, the bond angles are larger, and so I think the lone pair would probably cause less repulsion if placed b...
- Sun Jun 03, 2018 12:54 am
- Forum: Hybridization
- Topic: Hybridization Notation
- Replies: 3
- Views: 392
Re: Hybridization Notation
For atoms, I know we can just say sp hybridized, sp2 hybridized, etc. I guess for molecules the textbook notation should be followed, but I don't remember that in the lecture (not that it might not have been covered in lecture).
- Sun May 27, 2018 8:24 am
- Forum: Determining Molecular Shape (VSEPR)
- Topic: Types of Bonds
- Replies: 6
- Views: 853
Re: Types of Bonds
Sigma bonds allow more flexibility for molecules to change shape. Pi bonds make molecules more rigid.
- Sun May 27, 2018 8:22 am
- Forum: Determining Molecular Shape (VSEPR)
- Topic: AXE Notation and Shape
- Replies: 4
- Views: 954
Re: AXE Notation and Shape
For me, it also helped to know the amount of lone pairs/bonding atoms that each shape had. For example, the seesaw shape has 4 bonded atoms and 1 lone pair on the central atom, for a total of 5 atoms total in the molecule.
- Sun May 27, 2018 8:19 am
- Forum: Determining Molecular Shape (VSEPR)
- Topic: VSEPR
- Replies: 3
- Views: 459
Re: VSEPR
Molecules can be in the same VSEPR category. That would mean that their bonding domains/lone pairs would shape the angles between bonds the same way. For example, CH4 and and SO4 (2-) both have tetrahedral molecular geometry.
- Sun May 20, 2018 9:13 am
- Forum: Dipole Moments
- Topic: Polarization
- Replies: 2
- Views: 443
Re: Polarization
Polar molecules can be covalent as well. All that is needed to get polarity is/are more electronegative atom(s) pulling electrons to one region of a molecule. This is also shown by the dipole arrows on a diagram pointing in the same direction.
- Sun May 20, 2018 9:10 am
- Forum: Bond Lengths & Energies
- Topic: Pentane vs. 2,2 Dimethylpropane
- Replies: 3
- Views: 1396
Re: Pentane vs. 2,2 Dimethylpropane
Molecular structures with greater surface area tend to have higher melting points.
- Sun May 20, 2018 9:07 am
- Forum: Polarisability of Anions, The Polarizing Power of Cations
- Topic: Bonds
- Replies: 4
- Views: 710
Re: Bonds
I don't think electron shielding and bond length are closely related.
- Sun May 13, 2018 9:30 pm
- Forum: Ionic & Covalent Bonds
- Topic: 3.25 part c
- Replies: 3
- Views: 448
Re: 3.25 part c
I think most, if not all the time, aluminum ions have a 3+ charge.
- Sun May 13, 2018 8:19 am
- Forum: Resonance Structures
- Topic: Resonance Structures and Formal charges
- Replies: 7
- Views: 966
Re: Resonance Structures and Formal charges
I thought this site explains the relationship between resonance structures and formal charges well. It also goes really in-depth with well-explained examples.
https://chem.libretexts.org/Core/Physic ... /Resonance
https://chem.libretexts.org/Core/Physic ... /Resonance
- Sun May 13, 2018 8:14 am
- Forum: Formal Charge and Oxidation Numbers
- Topic: Oxidation Number & Bonds
- Replies: 6
- Views: 2594
Re: Oxidation Number & Bonds
Also, I think that the group where an element is located plays a role in its bonding. So to reinforce the previous post, Cl usually tries to gain one more electron to get a full octet because it is a halogen (Group 7).
- Sun May 06, 2018 10:48 pm
- Forum: Wave Functions and s-, p-, d-, f- Orbitals
- Topic: 2.37
- Replies: 3
- Views: 553
Re: 2.37
I think it just means that the s-orbitals are closer to the nucleus. There is a greater density of s-orbital electrons near the nucleus than that of other subshells.
- Sat May 05, 2018 10:28 pm
- Forum: Heisenberg Indeterminacy (Uncertainty) Equation
- Topic: Everyday Objects and heisenberg's equation [ENDORSED]
- Replies: 2
- Views: 464
Re: Everyday Objects and heisenberg's equation [ENDORSED]
The uncertainty of larger objects is harder to determine because they are easier to observe. Knowing how fast a car is going doesn't affect our knowledge of where it is located, because cars are much bigger than atoms, and are therefore easier to observe.
- Sat May 05, 2018 10:18 pm
- Forum: Electron Configurations for Multi-Electron Atoms
- Topic: Homework 2.55
- Replies: 2
- Views: 443
Re: Homework 2.55
For atoms with an atomic number greater than 20, the 4s state is higher in energy than that of 3d, which is why the d subshells are written before the s subshells for those e- configurations. Just looking at the configurations, the 4s and 4p subshells are the two "written last" of the Grou...
- Sun Apr 29, 2018 5:28 pm
- Forum: Wave Functions and s-, p-, d-, f- Orbitals
- Topic: understanding orbitals [ENDORSED]
- Replies: 8
- Views: 870
Re: understanding orbitals [ENDORSED]
I think that each plane shows the path with the highest probability of (specifically) the two electrons in that particular orbital.
- Sun Apr 29, 2018 5:22 pm
- Forum: Quantum Numbers and The H-Atom
- Topic: HW Problem 2.2 [ENDORSED]
- Replies: 3
- Views: 568
HW Problem 2.2 [ENDORSED]
Does an electron's energy increase when it moves from subshell to subshell?
- Sun Apr 29, 2018 5:17 pm
- Forum: Heisenberg Indeterminacy (Uncertainty) Equation
- Topic: Change in momentum
- Replies: 3
- Views: 365
Re: Change in momentum
What does "minimum uncertainty" mean conceptually? Mathematically it's the minimum product of a particle's position and momentum, but what's the point in knowing an electron's minimum uncertainty?
- Sun Apr 22, 2018 8:36 pm
- Forum: DeBroglie Equation
- Topic: HW 1.37 [ENDORSED]
- Replies: 6
- Views: 865
Re: HW 1.37 [ENDORSED]
Being more precise and using more decimal places got me a percent difference closer to 0, but it's probably negligible since proton and neutron masses are already pretty close in value.
- Sun Apr 22, 2018 8:30 am
- Forum: Properties of Electrons
- Topic: Diffraction meaning
- Replies: 6
- Views: 642
Re: Diffraction meaning
"Constructive" and "destructive" describe wave properties in the context of wave interference. They are used in a specific instance.
- Sun Apr 22, 2018 8:25 am
- Forum: Einstein Equation
- Topic: einstein equation and other equations [ENDORSED]
- Replies: 3
- Views: 324
Re: einstein equation and other equations [ENDORSED]
The equation can also be used to find E(photon) in the photoelectric effect equation.
- Sun Apr 15, 2018 6:25 pm
- Forum: Properties of Light
- Topic: Light is a wave and a particle?
- Replies: 5
- Views: 593
Re: Light is a wave and a particle?
Light can be both a wave and a stream of particles (photons). It travels as a wave, but when participating in chemical reactions (i.e. being absorbed or emitted by elements), transfer energy in distinct quantities/particles. The photoelectric effect is one of those example chemical reactions.
- Fri Apr 13, 2018 11:01 am
- Forum: Properties of Light
- Topic: HW 1.5 [ENDORSED]
- Replies: 7
- Views: 791
Re: HW 1.5 [ENDORSED]
The textbook table is technically correct since the energy potential of both waves have a lot of overlap. However, one can differentiate the two conceptually: gamma rays are nuclear in origin, whereas X-rays have an electronic source. I guess the solution ranked gamma radiation as higher in energy t...
- Fri Apr 13, 2018 10:46 am
- Forum: Properties of Light
- Topic: key concept 4/11/18
- Replies: 1
- Views: 194
Re: key concept 4/11/18
The variables of the light equations represent the aspects of light that contribute to its energy, which is emitted or absorbed in discrete units. In other words, this energy can be quantified. Branching off this fact, it is also true that the intensity of light is proportional to its number of phot...
- Sun Apr 08, 2018 7:36 pm
- Forum: Empirical & Molecular Formulas
- Topic: Rounding molar ratios
- Replies: 3
- Views: 12700
Re: Rounding molar ratios
I think that if you get a weird decimal by the time you start dividing by the smallest mole amount, it's likely that the calculations before that are incorrect. There were a few problems where I tried rounding up .7 and .8, and got really strange numbers for my answers. My work before that point was...
- Sun Apr 08, 2018 10:58 am
- Forum: Molarity, Solutions, Dilutions
- Topic: G.16 Part C
- Replies: 2
- Views: 262
Re: G.16 Part C
I think CuSO4 * 5H2O means that for every CuSO4 molecule, there are 5 H2O molecules attached. The 5 H2O molecules are seen as already in the solution, and all the * 5H2O represents is that the CuSO4 is hydrated. Therefore, the * 5H2O only affects the molar mass of the hydrated CuSO4 molecule, and no...
- Sat Apr 07, 2018 9:23 am
- Forum: Molarity, Solutions, Dilutions
- Topic: HW G.7
- Replies: 2
- Views: 271
HW G.7
In a solution, does the solute need to be completely dissolved in the water for the solution to be considered aqueous?