CHEMISTRY COMMUNITY

Samantha Hoegl Roy 2C

I have noticed that ln(K2/K1) = -delta H/R(1/T2 - 1/T1) and ln(K1/K2) = Ea/R(1/T2 - 1/T1) are not on the constants and formulas sheet. Are we expected to know these by heart or will they be given in the question? These are two of the harder formulas to remember, so I just want to be sure

Samantha Hoegl Roy 2C

Please post the entire question. "The following plot shows how the partial pressure of reactant and products vary with time for the decomposition of compound A into compound B and C. All three compounds are gases. Use this plot to do the following (...) b) calculate the equilibrium constant fo...

Samantha Hoegl Roy 2C

For this question, we are asked to calculate $\Delta H$ delta S and delta G
"write a balanced chemical reaction of NH3" why do they divide everything to only produce 1 Nh3? It is not stated in the question that they only want one mol to be produced.

Samantha Hoegl Roy 2C

for part b) why is every value divided by 100?
K = (Pb)(Pc)^2 / (Pa)^2
the graph shows the values A= 18 B = 10 C = 5 yet everything is divided by 100 in the equilibrium formula

Samantha Hoegl Roy 2C

How do we know that the reaction takes place at 298K?

OF2(g) + H2O(g) --> O2(g) + 2HF(g)
delta H = -318kJ

Samantha Hoegl Roy 2C

For this question, we are asked to find by what factor the rate of the reaction increases at 298K Ea without enzyme is 125kJ/mol Ea with an enzyme is 75kJ/mol For the ratio, does it matter which one we put as the numerator or denominator? and why don't they just plug in the numbers given for Ea inst...

Samantha Hoegl Roy 2C

why do they delete k2(O3) in 2k1k2(o3)^2/ (k1prime(O2) + k2(O3))? They say something about it being slow but isn't that exactly a reason to keep it because the slow step decides the overall ratel law?

Samantha Hoegl Roy 2C

Why do we have to convert Torr to atm?

Samantha Hoegl Roy 2C

For this question, the solution manual calculates the K value with n = 2, yet it seems to me like there is only one electron being transferred in the reaction
In3+(aq) + U3+(aq) --> In2+(aq) + U4+(aq)
why are 2 electrons being transferred or is it a mistake?

Samantha Hoegl Roy 2C

that makes sense mathematically, but I was more wondering was it means conceptually. Dr. Lavelle was talking about the way the molecules collide or something?

Samantha Hoegl Roy 2C

During class, we looked at two examples of second-order reactions. While it seems to make sense that they are second-order reactions, I would like to understand what exactly that means. Dr. Lavelle said something about the way the molecules interact, but I am very confused

Samantha Hoegl Roy 2C

What is the purpose of finding n? I still dont really understand what it stands for and why we need to know it

Samantha Hoegl Roy 2C

Write a cell diagram for the reaction 3NO3- (ag) + 8H+ (aq) + 6 Hg (l) --> 3Hg2 2+ (aq) + 2NO (g) + 4H2O(l) I don't even know where to start. Why is Hg on the left, but NO3-- on the right of the cell diagram? Arend both being oxidized in the equation above? ANd where does the water go and why does H...

Samantha Hoegl Roy 2C

You have to add platinum when both oxidized and reduced species are in the same solution. In this case Ce4+ and Ce3+ are in the same solution. Thus, Pt is needed

Samantha Hoegl Roy 2C

For the cell diagram notation; is the anodw always left and the cathodw always the part on the right of the expression?
How do I know which part of the reaction to reverse? (For example in 6L.3 e)?)

Samantha Hoegl Roy 2C

for 6K.3 a) why does it produce 5H2O? (in an acidic solution)

S2O3(2-) --> SO4(2-)

I always end up with two H2Os

Samantha Hoegl Roy 2C

For this question we are asked to calculate the stanfard reaction entropy, enthalpy and Gibbs free energy

A) 2 H2O2 —> 2 H2O + O2
Why do they nt divide the result by 2? I thought that for standard G,S and H, it was all for 1 mol of product and sinxe there are 2 mol of H2O2 I am a bit confused

Samantha Hoegl Roy 2C

Are the sections covered on the test 4I, 5G, 5J, and 6K or am I missing a section?
Thanks!!

Samantha Hoegl Roy 2C

So can I always assume that if the combustion happens at below 100° Celsius that water will be liquid? And if it is above 100° that water vapor will be released instead?

Samantha Hoegl Roy 2C

how do we know that for the combustion of C6H6(l), H2O will be created in liquid form? Is this always the case?

Samantha Hoegl Roy 2C

"how ∆S is related to ∆H for a change at constant temperature and pressure and explain
the relationship"
Is this the proof we did in class where we divided H by -T? If yes can someone quickly explain it

Samantha Hoegl Roy 2C

thanks guys!

Samantha Hoegl Roy 2C

Does anyone have an idea which formulas will be given to us? I was looking at the formulas that were given to us for the first test, but, if I remember correctly, Dr. Lavelle uses a different formula booklet. Are there any we need to know by heart?

Samantha Hoegl Roy 2C

Dr.Lavelle stated that we have to know everything up to entropy. I was wondering which sections of the book he wants us to cover. Is it 4F to 4I?

Samantha Hoegl Roy 2C

OF2 + H20 -> O2 + 2HF
ΔH = - 318kJ

what is the change in internal energy for the reaction of 1.00 mol OF2?
why is -PΔV = -ΔnRT used? isnt the change is ΔU = q + w; where does -ΔnRT come from?

Samantha Hoegl Roy 2C

for 4A3) the equation given in the solution manual is w = - (2.00 atm)(-0.14L)(101.325J/Latm) what does the 101,325 J mean? it's not part of the equation w = -PΔV

Samantha Hoegl Roy 2C

what does w = -nRTln(v2/v1) mean? I don't think it was discussed in class, but since it is in the assigned reading we probably have to know it. Can anyone explain the ln(v2/v1) part? thanks!!

Samantha Hoegl Roy 2C

A calorimeter was calibrated with an electric heater, which supplied 22.5 KJ of energy as heat to the calorimeter and increased the temperature from 22.45 to 23.97. what is the heat capacity of the calorimeter? I don't really understand how to tackle this problem; how would you go about it (the step...

Samantha Hoegl Roy 2C

the bond enthalpy of a diatomic molecule is the exact enthalpy needed to break the bond. For other bonds, the bond enthalpy is the average enthalpy of breaking this bond in several different molecules. This makes the number rather incorrect since it is just the average and not the exact enthalpy for...

Samantha Hoegl Roy 2C

can someone quickly remind me what the difference is? I have a hard time remembering the difference!

Samantha Hoegl Roy 2C

Do we have to know all 3 methods or can we focus on the one we prefer?

Samantha Hoegl Roy 2C

On Friday we covered buffer questions, yet, on the acid and bases outline, buffers are never mentioned. Are we supposed to know what to do with buffer questions although it not written on the outline for the test next week?

Samantha Hoegl Roy 2C

A sample of CH3NH3CL of mass 15.5g is dissolved in water to make 450ml of solution. what is the pH of the solution?
I was wondering where they found the Ka value because I can't find it in any of the tables.

Samantha Hoegl Roy 2C

Dr. Lavelle started to list the anions and cations that can be ignored in a solution as they do not affect the pH.
cations: Group 1 and 2 do not affect pH
anions: Cl, Br, I do not affect pH

are there any other elements that do not affect the pH?

Samantha Hoegl Roy 2C

For ii) I just calculated the pOH: -log(1.5) = 0.176
14 - pOH = pH thus the pH is 13.824. to find the H3o+ concentration i did 10^-13.824, which gives you 1.499 x 10^-14

Samantha Hoegl Roy 2C

I still have difficulties figuring out if a substance is a weak acid or base; for example, NH3. Does anyone have any advice and tips to make it easier?

Samantha Hoegl Roy 2C

Chem_Mod wrote:Hi,
Could you show where you get this?

page 412 in the 7th edition, topic 5H.3

Samantha Hoegl Roy 2C

do we need to know/understand K = (cRT/P)^nr(Kc)? If yes, can someone explain it?

Samantha Hoegl Roy 2C

P: I think is bar or atm
V: Liter
n: mole
r: constant
T: kelvin

Samantha Hoegl Roy 2C

the ratio of [O2]/[O3] is not the same because it is not balanced. It is therefore not K and just represents the concentration of both O2 and O3 present. since both samples have different concentrations, [O2]/[O3] cannot be the same

Samantha Hoegl Roy 2C

Both essentially mean there are more products than reactants, but I'm assuming "lie to the right" refers to when the reaction has not yet reached equilibrium yet, while "equilibrium shifted to the right" has the equation already at equilibrium. that makes sense! But what does it...

Samantha Hoegl Roy 2C

In the first auto visual focus-topic, some questions ask about the meaning of "Lie to the right" and "shifted to the right": With respect to equilibrium constants, what does it mean when a reaction is said to “lie to the right”? With respect to equilibrium constants, what does it...

Samantha Hoegl Roy 2C

Chem_Mod wrote:Could you provide more information? What exactly are the reactants?

"Decide whether an aqueous solution of each of the following salts has a pH equal to, greater than, or less than 7. write a chemical equation to justify your answer.

Samantha Hoegl Roy 2C

why is H2O2 a lewis base and SO3 a lewis acid? doesn't SO3 have more lone pairs to donate?

Samantha Hoegl Roy 2C

for e) AlCl3 and f) Cu(NO3)2 how would you know how to write the chemical equation?

Samantha Hoegl Roy 2C

hi can you clarify why Na, K and Br "do nothing"? What do you mean by that and how did you know<?

Samantha Hoegl Roy 2C

For part i) why is the OH- concentration 1.5 x 10^-14? I thought the equation for was a concentration of H3o+ multiplied by the concentration of OH- = 10 x 10^-14
thus OH- conc = 10 x 10^-14 / 1.5 but that seems to be wrong

Samantha Hoegl Roy 2C

oh, that makes sense! What about J9) b). no water is produced, so how can I make the equation?

Samantha Hoegl Roy 2C

select an acid and a base for a neutralization reaction that results in the formation of a) potassium bromide b) zinc nitrate
how would you go about answering this question? how do you chose the bases and acids; is the a rule to follow?

Samantha Hoegl Roy 2C

coordination number is the number of points at which ligands are attached to the central atom 4 in Ni(CO)4 and 6 in (Fe(CN)6)4- thus, for a polydentate ligand, I would assume you just multiply the number of ligands present with the number of bonds it can form to find the coordination number. For exa...

Samantha Hoegl Roy 2C

Do we now have to know what all the names stand for? like ammonium nitrate and stuff like that?

Samantha Hoegl Roy 2C

What does the alpha stand for?

Samantha Hoegl Roy 2C

Dr. Lavelle gave us the equation E is proportional to (alpha 1 * alpha2)/ r^6. Can someone explain me this formula again?

Samantha Hoegl Roy 2C

How come I3- is linear? There are three lone pair, will this not make the shape of the molecule angular?

Samantha Hoegl Roy 2C

In Dr. lavelles class, do we draw the arrows towards the negative charge of a molecule or towards the negative charge? The book says both way exists, so I just want to make sure I use the correct one.

Samantha Hoegl Roy 2C

I think the only calculations we could be asked is to “guess” the bond length in a resonance structure by knowing the double bond and signle bond length. Dr. Lavelle said several times that we would not have to calculate anything with bond length

Samantha Hoegl Roy 2C

because lone pairs repel the other atoms more as they are more electronegative (2 e- are much more strongly negative than a bond)

Samantha Hoegl Roy 2C

How come that when there is a double bond, there is one sigma bond and one pi bond? Why are not both pi bonds? Didn’t dr. Lavelle say something about bound atoms no longer being able to rotate?

Samantha Hoegl Roy 2C

I am pretty sure the angles are less than 180 and 90 degrees

Samantha Hoegl Roy 2C

if there is resonance, yes. You have to show that you know there are 3 different structures for the same molecule. if you only draw one, one could assume you believe one bond is shorter than the others

Samantha Hoegl Roy 2C

trigonal planar, trigonal pyramidal and p shaped all have three atoms; how do you tell them apart?

Samantha Hoegl Roy 2C

Which do you predict to have the strongest CX bond, where X is a halogen? a)CF4 b) CCl4 c) CBr4

how would you figure out the solution, I am not sure where to start

Samantha Hoegl Roy 2C

For CN- you have 4e- + 5e- + 1e- = 10 e-

You can not violate the octate rule with these specific elements. If you give them five bonds, this goes against the octate rule. Thus, the triple bond with the two lone pairs in the only solution that works

Samantha Hoegl Roy 2C

hi guys, I am struggling with this question. Why are there only 4 possible resonances structures? how do you know where to put the double bonds? I had like 6 models

Samantha Hoegl Roy 2C

In the solution, Br has 10 valence electrons. Is this an exception to the octet rule? I thought it only applied to elements in the third period (P, Cl, S)?

Samantha Hoegl Roy 2C

if they have low ionization energy it means that it does not take a lot of energy to take out an electron. Thus, it is easier for it to lose an electron, becoming a cation.

Samantha Hoegl Roy 2C

Hi! I am a little bit confused why Helium has the highest electron affinity. And what does the number stand for (He <0)? The trend is also not clear to me as there is no pattern.

Samantha Hoegl Roy 2C

Do we need to know what the alkali metals are and if yes, are there any other specific names for a group of metals I am supposed to know?

Samantha Hoegl Roy 2C

can you explain it in more detail i still don't understand because i can figure out E(n=4), E of everything, and the wavelengths of E(n=4) and E(everything - n=4)

Samantha Hoegl Roy 2C

An excited hydrogen atom emits light with a frequency of 1.14 x 1014 Hz to reach the energy level n = 4. In what principle quantum level did the electron begin?

how would you solve this question?

Samantha Hoegl Roy 2C

also magnetic quantum number

Samantha Hoegl Roy 2C

what does principal and orbital angular momentum stand for? is n principal momentum and l orbital angular momentum?

Samantha Hoegl Roy 2C

the mass of an electron is given to you m(e) = 9.1095 x 10^-31 kg

Samantha Hoegl Roy 2C

when would you use En = - hR / n^2 or En = h^2n^2/8mL^2?

Samantha Hoegl Roy 2C

1/2mV^2=hv (because you V (velocity), mass of the electron, and H (which is a constant) then you know the frequency --> c = (v)(wavelength)

Samantha Hoegl Roy 2C

i don't think we have to know that

Samantha Hoegl Roy 2C

to which size did Professor Lavelle say that the waves are detectable? Was it 10^-18 or 16?

Samantha Hoegl Roy 2C

what are the principal quantum levels of the H-atom? I know they exist and that electrons go from one level to another, but why do these levels exist? and what are they? I am a little confused! :)

Samantha Hoegl Roy 2C

Our TA said to just go with "your feeling"; like 3.9 is close enough, but 3.8 logically not. I would just always do the step, where you divide the numbers by the smallest one to be sure

Samantha Hoegl Roy 2C

can you be more specific? are you talking about the CaC2 + 2H2O --> Ca(OH)2 + C2H2 example? :)

Samantha Hoegl Roy 2C

you should probably remember that for combustion of butane (or something else) it's always: x mole of Butane (or methane..) + x mole of O2 --> x mole of CO2 + x mole of H2O

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