Search found 52 matches
- Sat Mar 16, 2019 7:10 pm
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: Catalyst in rate law?
- Replies: 6
- Views: 8188
Re: Catalyst in rate law?
They could be included because they are present in the original reactants. But i'm not sure because in class we learned that catalysts are not consumed so they in may cancel out.
- Sat Mar 16, 2019 7:05 pm
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: Intermediates in Rate Law
- Replies: 4
- Views: 464
Re: Intermediates in Rate Law
No, they are not included because they are not present in the original reactants or in the final products.
- Sat Mar 16, 2019 7:02 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: What is a porous disk?
- Replies: 3
- Views: 981
Re: What is a porous disk?
It's like a salt bridge in that it prevents ion build up by providing a pathway for ions to move to the other side. HOWEVER, in a cell diagram the salt bridge is drawn by 2 vertical lines, but a porous disk is drawn with only 1 vertical line.
- Sat Mar 16, 2019 6:57 pm
- Forum: Second Order Reactions
- Topic: reaction intermediate
- Replies: 4
- Views: 796
Re: reaction intermediate
A reaction intermediate is a molecule that is formed by the reaction, usually in step 1, and is used up by a later step of the reaction. It does not appear in the original reactants or final products.
- Sat Mar 16, 2019 6:55 pm
- Forum: General Rate Laws
- Topic: Exergonic reaction
- Replies: 3
- Views: 588
Re: Exergonic reaction
It is similar to exothermic(releases heat) in that exergonic means it is releasing energy.
- Sat Mar 16, 2019 6:51 pm
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: K'
- Replies: 4
- Views: 537
Re: K'
k' is the rate constant for the reverse reaction. It's used when your making a rate law. Remember k/k'=K(reaction equilibrium constant).
- Sat Mar 16, 2019 1:32 pm
- Forum: Calculating pH or pOH for Strong & Weak Acids & Bases
- Topic: 6B.9
- Replies: 1
- Views: 757
6B.9
I don't understand the solutions in the solution manual for this question. Why can't I divide Kw by the conc. of H3O+ to find OH-. Also, when I take the -log of the H3O+ conc it gives me a negative of the actual solution.
- Sun Mar 10, 2019 8:45 pm
- Forum: Balancing Redox Reactions
- Topic: Oxidation vs Reduction Half Rxn
- Replies: 9
- Views: 1076
Re: Oxidation vs Reduction Half Rxn
Oxidation half reaction is where electrons are being released from the reactant, so the electrons are written on the product side. Reduction half reactions is where electrons are being added to the reactant to form a product, so the electrons are written on the left side.
- Sun Mar 10, 2019 8:37 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Midterm
- Replies: 5
- Views: 555
Re: Midterm
A comment of the stability of products and reactants means an explanation of what the reaction tends to and why.
- Sun Mar 10, 2019 8:36 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Cell diagram
- Replies: 6
- Views: 619
Re: Cell diagram
To conduct electricity, move ions, the reaction needs electrodes to move them. So if there is no metal solid in the reaction there is no electrode. So platinum is used as a conductor.
- Sat Mar 02, 2019 5:58 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Order of Cell Diagrams
- Replies: 13
- Views: 1590
Re: Order of Cell Diagrams
Solids always go on the outmost side, furthest from the salt bridge. A TA told me to write the reactant on the left and product on the right. Also aq solutions should be closest to the salt bridge.
- Sat Mar 02, 2019 5:55 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Cell Diagrams (Using Platinum)
- Replies: 10
- Views: 998
Re: Cell Diagrams (Using Platinum)
A metal is used as a cathode or anode to conduct electricity so a reaction without a metal would not transfer ions. To make the circuit work for solutions with aq or gas reactants platinum needs to be added as a conductor.
- Sat Mar 02, 2019 5:52 pm
- Forum: Appications of the Nernst Equation (e.g., Concentration Cells, Non-Standard Cell Potentials, Calculating Equilibrium Constants and pH)
- Topic: E˚ vs E
- Replies: 13
- Views: 15674
Re: E˚ vs E
E˚ is the standard and E is in a specific reaction. E˚ does not change through a reaction because the element is in its most stable state but E changes as the reaction goes on because the element may change because its not in its most stable state.
- Sat Mar 02, 2019 5:49 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: w vs wmax
- Replies: 5
- Views: 624
w vs wmax
What is the difference between the measurement of work and work max. Does an expanding reaction have a work max?
- Sat Mar 02, 2019 5:48 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: H+ and OH
- Replies: 3
- Views: 434
H+ and OH
Why are H+ and OH included in the cell diagram if they are not included in the original equation and are just used to balance and sometimes cancel out?
- Sun Feb 24, 2019 10:26 pm
- Forum: Balancing Redox Reactions
- Topic: Skeleton Equations
- Replies: 3
- Views: 323
Re: Skeleton Equations
The skeleton equation doesn't include water or electrons. But water is used to balance the equation if there's an H or O on one side and not on the other.
- Sun Feb 24, 2019 10:24 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Salt Bridge
- Replies: 3
- Views: 353
Re: Salt Bridge
The salt bridge allows for ion transfer and it keeps the amount of ions at equilibrium so that there isn't an excess or not enough ions on either side to do the reaction.
- Sat Feb 23, 2019 10:09 pm
- Forum: Balancing Redox Reactions
- Topic: H OH and H20
- Replies: 2
- Views: 299
H OH and H20
How do I know what side to balance with H or OH or H20?
- Sun Feb 10, 2019 10:36 pm
- Forum: Calculating Work of Expansion
- Topic: Work Formula Involving Integral
- Replies: 3
- Views: 326
Re: Work Formula Involving Integral
In this class, yes the integral is only used to find the -PdV equation that we use. The integral is solved in order to show that pressure is constant and that volume is changing in small steps so we can just say that dV=V2-V1.
- Sun Feb 10, 2019 10:13 pm
- Forum: Calculating Work of Expansion
- Topic: Reversible Using V or P
- Replies: 1
- Views: 194
Reversible Using V or P
Since volume and pressure both change in reversible, isothermic system can you switch ln(V2/V1) and ln(P1/P2) whenever you want? Will you get the same answer?
- Sun Feb 10, 2019 2:57 pm
- Forum: Calculating Work of Expansion
- Topic: Reversible vs Irreversible
- Replies: 9
- Views: 836
Reversible vs Irreversible
What makes a reaction or movement irreversible in a system and what makes it reversible? Why are the pressures different?
- Sun Feb 03, 2019 8:41 pm
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: Isolated System Example
- Replies: 4
- Views: 1021
Re: Isolated System Example
An isolated system means that there is no matter or energy transfer between the contents in the inside and its surroundings. The most general example of a truly closed system is the universe because there is nothing that exists outside of the universe so nothing can be transferred between it and its...
- Sun Feb 03, 2019 8:34 pm
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: open system
- Replies: 8
- Views: 1383
Re: open system
An open system means that matter and energy is transferred between the solution and its surroundings. The pressure in the beaker is the same as its surroundings because it is open to air and the same as normal air. This is 1atm.
- Sun Feb 03, 2019 7:36 pm
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: 1st law of thermodynamics
- Replies: 7
- Views: 611
Re: 1st law of thermodynamics
An isolated system means that there is no matter or energy change/transfer between the internal objects and their surroundings. Using the universe as an example - there is nothing known outside of the universes therefore it is impossible for energy or matter to be transferred to the surroundings bec...
- Sun Jan 27, 2019 9:56 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Order of Hess's Law
- Replies: 1
- Views: 101
Order of Hess's Law
When adding the two enthalpies, getting the net enthalpy telling whether the whole reaction is exothermic or endothermic do all of the reactions happen simultaneously or individually depending on availability of reactants. If it is the latter could a reaction be exothermic for a set amount of time a...
- Sat Jan 26, 2019 9:22 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Sign changes
- Replies: 3
- Views: 267
Sign changes
When adding two enthalpies can the total change signs, such as if the enthalpy of the first is positive and you add a negative one and the negative one is higher and what would that mean for the reaction?
- Sat Jan 26, 2019 9:20 pm
- Forum: Phase Changes & Related Calculations
- Topic: Enthalpy signs
- Replies: 13
- Views: 1722
Enthalpy signs
When is the change in H, Enthalpy, positive and when is it negative?
- Sun Jan 13, 2019 1:25 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: (aq) in calculating K
- Replies: 9
- Views: 1356
Re: (aq) in calculating K
Aqueous and gases are included in the equilibrium constant and solids and liquids are not because molar concentrations of a pure substance, solids and liquids, does not change in a reaction.
- Sun Jan 13, 2019 1:22 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Heterogeneous and homogeneous equilibria [ENDORSED]
- Replies: 8
- Views: 769
Re: Heterogeneous and homogeneous equilibria [ENDORSED]
Homogeneous equilibria is where all reactants and products are in the same phase. Therefore if they are all gasses all of the components would be incorporated in the equilibrium constant equation. Heterogeneous equilibria is when one or more of the reactants or products are in a different phase. If ...
- Sat Jan 12, 2019 11:10 pm
- Forum: Ideal Gases
- Topic: Q
- Replies: 5
- Views: 501
Q
K is the equilibrium constant, but what is the purpose of finding Q? Specifically why do we use the same formula and what does it mean?
- Sat Dec 08, 2018 9:52 pm
- Forum: Calculating pH or pOH for Strong & Weak Acids & Bases
- Topic: pH to salt solution
- Replies: 1
- Views: 180
pH to salt solution
How do you calculate pH when you're given the molarity and volume of a basic solution like on Lyndon's review?
- Sat Dec 08, 2018 5:35 pm
- Forum: Calculating the pH of Salt Solutions
- Topic: Ph to salt solution
- Replies: 2
- Views: 386
Ph to salt solution
Given the formula and the final pH is it possible to do the formula backwards and find the original concentration?
- Sun Dec 02, 2018 10:43 pm
- Forum: Bronsted Acids & Bases
- Topic: Strong Acids
- Replies: 4
- Views: 344
Strong Acids
Why do strong acids produce more protons than a weak acid? The process.
- Sun Dec 02, 2018 8:54 pm
- Forum: Hybridization
- Topic: Hybridization Application
- Replies: 2
- Views: 303
Hybridization Application
Does every element need a hybridization formula when bonding? Or when are the circumstances when it is needed?
- Sun Dec 02, 2018 8:52 pm
- Forum: Hybridization
- Topic: P orbital
- Replies: 7
- Views: 650
P orbital
How do I know when to add the extra p orbital after the sp hybridization?
- Tue Nov 27, 2018 10:03 am
- Forum: Hybridization
- Topic: Number
- Replies: 2
- Views: 230
Number
Is hybridization based on bonds or electron regions? Do you include lone pairs?
- Mon Nov 26, 2018 5:59 pm
- Forum: Ionic & Covalent Bonds
- Topic: Polar Molecule
- Replies: 3
- Views: 1100
Polar Molecule
Is a polar molecule any molecule with charges? If there is a net charge of 0 is it non polar (ex. central atom has +2 and two bonded atoms have -1 each)?
- Mon Nov 26, 2018 5:57 pm
- Forum: Hybridization
- Topic: Pi bonds
- Replies: 3
- Views: 357
Pi bonds
How would you draw a pi bond between two different molecules? Would lone pairs on one of the molecules affect it?
- Sat Nov 24, 2018 3:41 pm
- Forum: Octet Exceptions
- Topic: Incomplete Octet
- Replies: 2
- Views: 587
Incomplete Octet
For examples like BF3 where the central atom does not have a complete octet, what are the characteristic changes that occur? Bonding wise and attraction wise? Maybe even state wise?
- Sun Nov 18, 2018 11:01 pm
- Forum: Determining Molecular Shape (VSEPR)
- Topic: Bond Angles for H2O
- Replies: 8
- Views: 8933
Re: Bond Angles for H2O
H20 has two lone pairs in order to complete the valence since 2 are being shared on each side with the hydrogens. These two lone pairs push the 2 hydrogens down because of electron repulsion. So the angle between the two hydrogens is less than 109.5. It is 104.5 because there are two lone pairs whic...
- Sun Nov 18, 2018 10:58 pm
- Forum: Determining Molecular Shape (VSEPR)
- Topic: 2 Atoms
- Replies: 1
- Views: 122
2 Atoms
What is the correct reasoning on why 2 VSEPR models with 2 atoms of elements are not regarded? Can there be a lone pair between two bonded atoms? And would it always be linear?
- Wed Nov 14, 2018 9:27 pm
- Forum: Determining Molecular Shape (VSEPR)
- Topic: 3D Structure
- Replies: 2
- Views: 196
3D Structure
When drawing a 3D structure of the VSEPR model and there is a double bond between two atoms would you draw two wedges/lines between the two atoms?
- Wed Nov 14, 2018 9:23 pm
- Forum: Ionic & Covalent Bonds
- Topic: Hydrogen Bond
- Replies: 7
- Views: 868
Hydrogen Bond
The textbook says that a hydrogen bond will dominate all other intermolecular forces, so first, is It possible for a molecule to have a covalent bond and a hydrogen bond? and second what would be the effect of that?
- Sun Nov 11, 2018 7:11 pm
- Forum: Ionic & Covalent Bonds
- Topic: Bond Length
- Replies: 3
- Views: 401
Bond Length
Is there a way to determine bond length or will it always be given?
- Sun Nov 11, 2018 7:10 pm
- Forum: Electronegativity
- Topic: Radius
- Replies: 13
- Views: 1614
Radius
How does electronegativity affect the radius of an atom? The process not just the trend.
- Wed Nov 07, 2018 12:54 pm
- Forum: Lewis Structures
- Topic: Formal Charge
- Replies: 14
- Views: 1317
Formal Charge
Is it better for the central element of the outside elements to have a charge? Why?
- Fri Nov 02, 2018 5:11 pm
- Forum: Lewis Structures
- Topic: How to decide central atom?
- Replies: 6
- Views: 964
Re: How to decide central atom?
The central atom is the atom with the lowest ionization energy, so the atom that requires the lowest amount of energy to remove an electron. The element closest to the bottom left of the periodic table.
- Fri Nov 02, 2018 5:06 pm
- Forum: Octet Exceptions
- Topic: s vs d orbital
- Replies: 2
- Views: 319
s vs d orbital
Why are some elements written with a d^10 rather than s^2 and d^8?
- Mon Oct 29, 2018 8:20 pm
- Forum: Lewis Structures
- Topic: Number of Electrons
- Replies: 2
- Views: 103
Number of Electrons
Is the number of valence electrons based on the column the element is in? Is the proton number same as the total number of electrons?
- Thu Oct 04, 2018 9:52 pm
- Forum: Balancing Chemical Reactions
- Topic: L.5 Mass
- Replies: 3
- Views: 375
L.5 Mass
For part A where it gives you the mass of one reactant and asks you to find the other, do you just use the ratio, or do you have to change it to moles and use avogadros number?
- Thu Oct 04, 2018 1:31 pm
- Forum: Accuracy, Precision, Mole, Other Definitions
- Topic: Ed. 7 E.23D Equation
- Replies: 3
- Views: 242
Ed. 7 E.23D Equation
What does the little multiplication seeming dot mean in the middle of Na2CO3*10H2O. Is it a solvent solute concept?
- Wed Oct 03, 2018 9:33 pm
- Forum: Significant Figures
- Topic: E23C Sig Figs
- Replies: 2
- Views: 237
E23C Sig Figs
How do I know how many significant figures do I add to my answer? Is it based on the 25.2kg in the question or the molar masses?