Search found 29 matches
- Fri Mar 15, 2019 4:35 am
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Specific Heat Capacity and Heat Capacity
- Replies: 2
- Views: 588
Re: Specific Heat Capacity and Heat Capacity
specific heat capacity is an intensive property and not the other way around for that reason.
- Fri Mar 15, 2019 4:33 am
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: rate constant
- Replies: 1
- Views: 241
rate constant
"Increasing the concentration of a reactant increases the rate of a reaction by increasing the rate constant in the forward direction"
Would this statement be false?? If so, could someone explain why that is?
Would this statement be false?? If so, could someone explain why that is?
- Fri Mar 15, 2019 4:28 am
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: Rate constant for large equilibrium constant
- Replies: 1
- Views: 241
Rate constant for large equilibrium constant
For a reaction with a very large equilibrium constant, would the rate constant of the forward reaction be much larger than the rate constant of the reverse reaction?
- Fri Mar 15, 2019 4:27 am
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: Rate constants at equilibrium
- Replies: 5
- Views: 624
Rate constants at equilibrium
At equilibrium, would the rate constants of the forward and reverse reactions be equal?
- Fri Mar 15, 2019 3:40 am
- Forum: Second Order Reactions
- Topic: Molecularity
- Replies: 5
- Views: 669
Re: Molecularity
Could you give an example as to how we would use the orders from the elementary steps to get the molecularity?
- Fri Mar 15, 2019 3:37 am
- Forum: Second Order Reactions
- Topic: Molecularity
- Replies: 5
- Views: 669
Re: Molecularity
could you clarify what you mean by overall order? so can we avoid the elementary steps and just look at the overall order if it is given?
- Fri Mar 15, 2019 3:34 am
- Forum: Second Order Reactions
- Topic: Molecularity
- Replies: 5
- Views: 669
Molecularity
In my notes, I have that the molecularity is based on the number of species in an elementary step but would it be different if the order of those individual species was something other than 1?
- Fri Mar 15, 2019 3:19 am
- Forum: General Rate Laws
- Topic: k'
- Replies: 3
- Views: 344
k'
so what exactly is k' and how is it used to find the overall k?
- Fri Mar 15, 2019 3:08 am
- Forum: Arrhenius Equation, Activation Energies, Catalysts
- Topic: activation energy
- Replies: 3
- Views: 419
activation energy
How would we find the activation energy, given both rate constants and temperatures?
- Fri Mar 15, 2019 2:26 am
- Forum: Second Order Reactions
- Topic: reaction intermediate
- Replies: 4
- Views: 796
reaction intermediate
For one of the homework problems, it gives the elementary steps and asks what the reaction intermediate is, what exactly would this be?
- Fri Mar 15, 2019 1:51 am
- Forum: Second Order Reactions
- Topic: First Order vs Second Order Reaction Half- Life
- Replies: 1
- Views: 467
Re: First Order vs Second Order Reaction Half- Life
you have to take the half-life to the 4th power
- Thu Mar 14, 2019 11:49 pm
- Forum: Second Order Reactions
- Topic: Question 13 6th Edition
- Replies: 2
- Views: 534
Re: Question 13 6th Edition
to find the initial reaction rate, you would just multiply the molarity of all the reactants times the k that they provided.
- Fri Mar 01, 2019 10:20 am
- Forum: Balancing Redox Reactions
- Topic: Max Potential
- Replies: 3
- Views: 448
Max Potential
Could someone explain a bit more the concept of max potential and how that gives you the cell potential? I'm confused as to how they relate.
- Fri Mar 01, 2019 5:33 am
- Forum: Balancing Redox Reactions
- Topic: Metals
- Replies: 2
- Views: 324
Metals
Why is it that metals are better conductors of electricity????
- Fri Mar 01, 2019 5:31 am
- Forum: Balancing Redox Reactions
- Topic: Strength of reducing agent
- Replies: 10
- Views: 1963
Strength of reducing agent
For one of the homework problems, it asks to rank metals of increasing strength of reducing agent. How would we go about answering these type of questions?
- Thu Feb 21, 2019 4:23 pm
- Forum: Gibbs Free Energy Concepts and Calculations
- Topic: Gibbs Free Energy and Spontaneity
- Replies: 2
- Views: 447
Gibbs Free Energy and Spontaneity
Could a reaction have a negative delta g and favor reactants or would it always favor the products?
- Thu Feb 21, 2019 3:43 pm
- Forum: Gibbs Free Energy Concepts and Calculations
- Topic: Units of Delta G
- Replies: 5
- Views: 7810
Units of Delta G
What would be the units of Gibbs Free energy?
- Thu Feb 21, 2019 3:33 pm
- Forum: Gibbs Free Energy Concepts and Calculations
- Topic: 9.53 Homework Problem
- Replies: 1
- Views: 263
9.53 Homework Problem
9.53 Calculate the change in molar Gibbs free energy for the process NH3(l) S NH3(g) at 1 atm and (a) 15.0 C; (b) 45. C (see Tables 8.3 and 9.1). In each case, indicate whether vaporization would be spontaneous. I'm confused as to how would we approach this question? Would we just be getting values ...
- Fri Feb 15, 2019 5:26 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Specific Heat capacity
- Replies: 2
- Views: 387
Specific Heat capacity
Still confused as to why specific heat capacity is intensive if the equation includes moles. Could someone explain this?
- Fri Feb 15, 2019 5:21 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: HW Problem 9.5
- Replies: 2
- Views: 399
HW Problem 9.5
9.5 What is the total entropy change of a process in which 40.0 kJ of energy is transferred as heat from a large reservoir at 800. K to one at 200. K?
For this question, would we just be finding the change in entropies for each and then adding them together?
For this question, would we just be finding the change in entropies for each and then adding them together?
- Thu Jan 31, 2019 2:16 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: HW 8.11 part b
- Replies: 2
- Views: 338
HW 8.11 part b
A piston confines 0.200 mol Ne(g) in 1.20 L at 25 C. Two experiments are performed. (a) The gas is allowed to expand through an additional 1.20 L against a constant pressure of 1.00 atm. (b) The gas is allowed to expand reversibly and isothermally to the same final volume. Which process does more wo...
- Thu Jan 31, 2019 12:35 pm
- Forum: Phase Changes & Related Calculations
- Topic: HW problem 8.5
- Replies: 3
- Views: 400
HW problem 8.5
A gas sample in a cylinder is supplied with 524 kJ of energy as heat. At the same time, a piston compresses the gas, doing 340 kJ of work. What is the change in internal energy of the gas during this process? For this problem is the 524kJ the initial energy and the 340kJ just the change? so would th...
- Thu Jan 31, 2019 11:29 am
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: 8.1 part c
- Replies: 1
- Views: 201
8.1 part c
can anybody help me understand what type of system would a bomb calorimeter in which benzene is burned would be?
- Fri Jan 25, 2019 8:14 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Standard enthalpy of formation
- Replies: 2
- Views: 207
Re: Standard enthalpy of formation
The standard enthalpy is the standard heat/energy required to form one mole of a substance in its most stable form and that value is zero which makes sense because its already in its most stable form.
- Fri Jan 25, 2019 7:57 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Stable carbon
- Replies: 3
- Views: 303
Stable carbon
Could someone explain how graphite is the most stable form of carbon?
- Fri Jan 25, 2019 7:48 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: An element's standard state
- Replies: 2
- Views: 251
Re: An element's standard state
If I'm right, I believe most reactions are given in their standard state
- Fri Jan 18, 2019 3:21 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: When is X negligible.
- Replies: 6
- Views: 560
When is X negligible.
So I'm still pretty confused as to when we should know when x can be disregarded in the denominator for the quadratic equation in an ICE problem. Is it safer to just never disregard it, or are there exceptions when it is acceptable?
- Fri Jan 18, 2019 3:14 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: ICE
- Replies: 5
- Views: 508
Re: ICE
X is the change in concentration from reactants to products, thus, the reactant's end concentration would be its initial-change(which is x), the products, on the other hand, are just x since they are equal to the change in concentration from the reactant.
- Fri Jan 18, 2019 3:07 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: ICE table
- Replies: 2
- Views: 270
ICE table
When constructing the ICE table, if there is a coefficient in front of the products, do we include that number in the quadratic, or solve for x and then multiply it by the coefficient afterward?