Search found 30 matches
- Sat Dec 08, 2018 9:30 pm
- Forum: Amphoteric Compounds
- Topic: Amphiprotic vs. Amphoteric
- Replies: 7
- Views: 600
Re: Amphiprotic vs. Amphoteric
Not all Amphoteric substances are amphiprotic. For example, Al2O3 is amphoteric but not amphiprotic.
- Thu Dec 06, 2018 8:10 pm
- Forum: Naming
- Topic: Chemical Formulas
- Replies: 2
- Views: 157
Re: Chemical Formulas
I think transition metals are almost always inside the brackets of a coordination compound.
- Thu Dec 06, 2018 8:06 pm
- Forum: Shape, Structure, Coordination Number, Ligands
- Topic: Coordination number
- Replies: 1
- Views: 134
Coordination number
Does anyone know how to find the coordination number for complexes with polydentate ligands? For example, I know EDTA4- is a hexadentate and having octahedral structures when it binds to a metal cation, but I don't know if a complex such as [Fe(EDTA)]2- should be consider as having coordination numb...
- Thu Dec 06, 2018 7:52 pm
- Forum: Acidity & Basicity Constants and The Conjugate Seesaw
- Topic: H30+ and H+
- Replies: 4
- Views: 236
Re: H30+ and H+
When HCl is deprotonated, we often write it as H+ and Cl- for simplicity. However, H+ does not exist in form of a single proton, it will bind with water and form H3O*. So it is a actually transfer of proton.
- Thu Dec 06, 2018 11:55 am
- Forum: Bronsted Acids & Bases
- Topic: Distinguishing bronsted acids vs bases
- Replies: 3
- Views: 399
Re: Distinguishing bronsted acids vs bases
In the example you give, HNO2 + HPO4 ^2- <=> NO2^- + H2PO4^-, HNO2 is the acid, because it loses (donates) a proton to HPO4^2-. HPO4 ^2- is the base, because it accepts the H+ from HNO2. You can distinguish bronsted acids and bases by finding their roles in proton transfer.
- Sun Dec 02, 2018 10:12 pm
- Forum: Dipole Moments
- Topic: Strength of intramolecular forces due to polarity
- Replies: 5
- Views: 316
Re: Strength of intramolecular forces due to polarity
Between two polar molecules, such as HF and HF, there are dipole-diploe interactions going on. It is a slightly greater intermolecular attractive force than the dispersion force between two non-polar molecules.
- Sun Dec 02, 2018 10:04 pm
- Forum: Properties & Structures of Inorganic & Organic Acids
- Topic: calcium
- Replies: 2
- Views: 146
Re: calcium
Maybe calcium oxide is called a "quicklime" just because it is very reactive.
- Sun Dec 02, 2018 10:00 pm
- Forum: Bronsted Acids & Bases
- Topic: Bronsted Acid vs Lewis Acid
- Replies: 2
- Views: 182
Re: Bronsted Acid vs Lewis Acid
A Bronsted acid is a proton (H+ ion) donor, and a Bronsted base is a proton acceptor. A Lewis acid is an electron acceptor, and a base is an electron donor. You can apply the two definitions to a single molecule. For example, ammonia is a proton acceptor, and it is also a electron donor.
- Sun Nov 25, 2018 9:54 pm
- Forum: Determining Molecular Shape (VSEPR)
- Topic: Test 3
- Replies: 38
- Views: 1324
Re: Test 3
I think the comparative strength of ion-ion, ion-dipole, dipole-dipole, dipole-induced dipole, and dispersion interactions may also on the test. Also I remember there are specific factors affecting induced dipole-induced dipole forces.
- Sun Nov 25, 2018 9:19 pm
- Forum: Determining Molecular Shape (VSEPR)
- Topic: Test 3
- Replies: 38
- Views: 1324
Re: Test 3
I think different intermolecular interactions is also included in the test.
- Sun Nov 25, 2018 9:14 pm
- Forum: *Molecular Orbital Theory (Bond Order, Diamagnetism, Paramagnetism)
- Topic: sigma and pi bonds
- Replies: 4
- Views: 252
Re: sigma and pi bonds
A sigma bond is in direction along the bond axis, like a stick connecting two balls, so atoms can rotate freely. The pi bonds is formed above and below the sigma bond, so it is only stable in one orientation and cannot rotate.
- Sun Nov 18, 2018 12:08 pm
- Forum: Determining Molecular Shape (VSEPR)
- Topic: Determining Shape
- Replies: 10
- Views: 522
Re: Determining Shape
It is hard to know the number of bonding pairs and lone pairs just by looking at the chemical formula. I think to be safe we have to draw the lewis structure.
- Sun Nov 18, 2018 12:06 pm
- Forum: Determining Molecular Shape (VSEPR)
- Topic: Bond Angle for VSEPR Name AX2E3 [ENDORSED]
- Replies: 1
- Views: 386
Re: Bond Angle for VSEPR Name AX2E3 [ENDORSED]
I think AX2E3 is linear because the repulsion force of equatorial orbitals pushes the bonding pairs to the vertical axis. If the bond angle is less than 180 degree, the bonding pairs actually gets closer to the lone pairs, which would not happen.
- Sun Nov 18, 2018 11:57 am
- Forum: Determining Molecular Shape (VSEPR)
- Topic: No central atom
- Replies: 7
- Views: 301
Re: No central atom
I think we can think of the two nitrogen atom separately. Each of the nitrogen atom has a formula AX3N1 and a trigonal pyramidal shape.
- Fri Nov 09, 2018 10:28 am
- Forum: SI Units, Unit Conversions
- Topic: Angstrom
- Replies: 5
- Views: 628
Re: Angstrom
It is convenient to use when measuring bond lengths, but it is not a IS unit.
- Fri Nov 09, 2018 10:25 am
- Forum: Bond Lengths & Energies
- Topic: Dipole interaction
- Replies: 3
- Views: 215
Re: Dipole interaction
Dipole-dipole interactions take place between two polar molecules, such as HF and HF. Because F is more electronegative, there is a slight negative charge on the F end and a slight positive charge on the H end. The attraction between the positive end of one molecule and the negative end of another m...
- Fri Nov 09, 2018 9:55 am
- Forum: Dipole Moments
- Topic: Dipole induced dipole
- Replies: 3
- Views: 171
Re: Dipole induced dipole
HCl is a polar molecule. When the Cl end comes close to a non-polar molecule N2, HCl repels the electron density of one end of N2, making that end slightly positive. This is an example of a dipole-induced dipole interaction.
- Fri Nov 09, 2018 9:48 am
- Forum: Dipole Moments
- Topic: HCl
- Replies: 6
- Views: 258
Re: HCl
HCl has a permanent dipole moment because of its polarity. Cl is more electronegative, so Cl side always has a slight negative charge.
- Sat Nov 03, 2018 12:12 am
- Forum: Wave Functions and s-, p-, d-, f- Orbitals
- Topic: Node
- Replies: 2
- Views: 201
Re: Node
A wave function node occurs at points where the wave function psi is zero and changes signs. When psi=0, psi^2=0. Because psi^2 represents the probability density of electron, an electron has zero probability of being located at a node.
- Sat Nov 03, 2018 12:07 am
- Forum: Wave Functions and s-, p-, d-, f- Orbitals
- Topic: Shells, Subshells, Orbitals
- Replies: 4
- Views: 1768
Re: Shells, Subshells, Orbitals
Shells indicates the energy of the electrons and are specified by the principal quantum number n. There are k different subshells contained in a given shell with n value= k. For example, there are only one subshell in the n=1 level. There are two subshells in the n=2 level. Subshells are related to ...
- Sat Oct 27, 2018 3:13 pm
- Forum: Trends in The Periodic Table
- Topic: Atomic Radius
- Replies: 8
- Views: 378
Re: Atomic Radius
I think knowing the general trends and being able to compare between two atoms given a periodic table is needed. We don't need to memorize the specific values.
- Sat Oct 27, 2018 3:07 pm
- Forum: Wave Functions and s-, p-, d-, f- Orbitals
- Topic: Ml Meaning
- Replies: 3
- Views: 314
Re: Ml Meaning
ml is the magnetic quantum number, it specifies the individual orbitals within a subshell and indicates orientations. There are always 2l+1 different values of ml for a given value of l.
- Sat Oct 27, 2018 2:59 pm
- Forum: Quantum Numbers and The H-Atom
- Topic: Orbitals
- Replies: 4
- Views: 223
Re: Orbitals
the outermost shell refers to the principal quantum number n and the energy level. For example, the number of electrons present in the outermost shell of a carbon atom is 4. (2s2, 2p2)
- Mon Oct 22, 2018 10:56 pm
- Forum: Wave Functions and s-, p-, d-, f- Orbitals
- Topic: Significance of XYZ to PDF orbitals
- Replies: 6
- Views: 277
Re: Significance of XYZ to PDF orbitals
I agree with you. I think they are used mainly to denote the orientations of the lobes.
- Mon Oct 22, 2018 10:51 pm
- Forum: Heisenberg Indeterminacy (Uncertainty) Equation
- Topic: Formula confusion
- Replies: 5
- Views: 124
Re: Formula confusion
They are different but related. In the Heisenberg equation, the constant you mentioned that has the value 1.05457 x 10^-34 is actually not h. It is "h bar", which means h/2pi.
- Mon Oct 22, 2018 10:47 pm
- Forum: Electron Configurations for Multi-Electron Atoms
- Topic: 1E.13 7th Edition
- Replies: 3
- Views: 150
Re: 1E.13 7th Edition
I think it is because a subshell is more stable if it gets half full or full. So when the d subshell is just one away from filled up it gets an electron from the s shell. It is similar to copper.
- Wed Oct 17, 2018 8:37 am
- Forum: Photoelectric Effect
- Topic: Module Question 29 (Part B)
- Replies: 4
- Views: 267
Re: Module Question 29 (Part B)
I think the reason we have to divide it by the Avogadro constant is that the energy is given in kJ/mol. You need to solve for the energy of an atom.
- Wed Oct 17, 2018 8:22 am
- Forum: Bohr Frequency Condition, H-Atom , Atomic Spectroscopy
- Topic: Wavelengths
- Replies: 5
- Views: 208
Re: Wavelengths
I think wavelength should be a positive value. It is a measure of length rather than displacement.
- Wed Oct 17, 2018 8:18 am
- Forum: Photoelectric Effect
- Topic: Post Module Assessment #25
- Replies: 2
- Views: 198
Re: Post Module Assessment #25
I think it might be D, because E=hv=hc/λ is connecting v, the frequency, with the energy of the photon.
- Sat Oct 06, 2018 9:23 pm
- Forum: Molarity, Solutions, Dilutions
- Topic: dilutions? [ENDORSED]
- Replies: 5
- Views: 353
Re: dilutions? [ENDORSED]
The exact steps may vary depends on the types of values are given. The key concept is that when diluting a solution, the moles of solute remain the same. The moles of solute = M initial × V initial = M final × V final. So it might be helpful to first think about which of those quantities were given,...