Search found 48 matches
- Sun Mar 14, 2021 12:05 pm
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: Degeneracy
- Replies: 11
- Views: 922
Re: Degeneracy
What are some examples of questions we could get asked about degeneracy.
- Sun Mar 14, 2021 12:04 pm
- Forum: Thermodynamic Definitions (isochoric/isometric, isothermal, isobaric)
- Topic: Which R to use
- Replies: 42
- Views: 3087
Re: Which R to use
The R you need to use is dependent on the units.
- Sun Mar 14, 2021 12:01 pm
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: Sapling Week9/10 #12
- Replies: 3
- Views: 323
Re: Sapling Week9/10 #12
Thanks for the help!
- Sun Mar 14, 2021 12:00 pm
- Forum: Calculating Work of Expansion
- Topic: Work and Delta V
- Replies: 20
- Views: 2597
Re: Work and Delta V
even though there is no measurable change and in volume and no source of pressure isn't the act of expansion, means work is done BY THE SYSTEM
- Sun Mar 14, 2021 11:53 am
- Forum: Environment, Ozone, CFCs
- Topic: catalysis vs intermediate
- Replies: 25
- Views: 2036
Re: catalysis vs intermediate
Malakai Espinosa 3E wrote:Also a difference to note, catalysts can be included in your rate law if they are in the slow step, but intermediates cannot!
why is the rate law governed by the slow step
- Sun Mar 14, 2021 11:51 am
- Forum: Environment, Ozone, CFCs
- Topic: catalysis vs intermediate
- Replies: 25
- Views: 2036
Re: catalysis vs intermediate
For a visual example: A + B --> C + D D + E --> B + F B would be the catalyst C would be the intermediate is B the catalyst in both? I think that this is showing the two elementary steps of the overall reaction A + E (+B) --> C + F (+B). In this case, B is a catalyst in the overall reaction because...
- Sun Mar 14, 2021 11:48 am
- Forum: Student Social/Study Group
- Topic: Final Jitters
- Replies: 457
- Views: 377861
Re: Final Jitters
every time I feel myself getting stressed, it helps to take a beat, close your eyes for a few seconds and breathe deeply.
- Sun Mar 14, 2021 11:47 am
- Forum: Arrhenius Equation, Activation Energies, Catalysts
- Topic: Free Energy of Activation
- Replies: 6
- Views: 481
Re: Free Energy of Activation
Activation energy is the energy that needs to be provided to the system for the reaction to occur.
Free energy of activation refers to Gibbs Free energy.
Free energy of activation refers to Gibbs Free energy.
- Sun Mar 14, 2021 11:42 am
- Forum: Zero Order Reactions
- Topic: Are zero order reactions always true for any condition?
- Replies: 2
- Views: 469
Re: Are zero order reactions always true for any condition?
This is really interesting, I was under the impression that reactions had fixed orders, instead of thinking of them a dependent on a set of conditions.
- Sun Mar 14, 2021 11:40 am
- Forum: Biological Examples
- Topic: Enzymes
- Replies: 13
- Views: 1799
Re: Enzymes
Are heterogenous catalysts formed again at the end of the reaction. for example, will a solid catalyst be able to be recovered at the end of a reaction ?
- Sun Mar 14, 2021 11:36 am
- Forum: First Order Reactions
- Topic: Half-life independent from initial concentration
- Replies: 8
- Views: 1647
Re: Half-life independent from initial concentration
is there any mathematical way of understanding why half like of a first order reaction is independent of the concentration - other than considering the ln2/k formula
- Sun Mar 14, 2021 11:32 am
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: pka vs ka
- Replies: 28
- Views: 1427
Re: pka vs ka
what is the difference between pka and ka and pkb and kb
- Sun Mar 14, 2021 11:30 am
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Determining The Favored Side of an Equilibrium Product
- Replies: 12
- Views: 1266
Re: Determining The Favored Side of an Equilibrium Product
does it matter how much less than or more than K, Q is.
like is there a particular threshold after which we can determine whether products or reactants will be favoured ?
like is there a particular threshold after which we can determine whether products or reactants will be favoured ?
- Sun Mar 14, 2021 11:28 am
- Forum: Administrative Questions and Class Announcements
- Topic: Saying Thank You to Dr. Lavelle
- Replies: 490
- Views: 571609
Re: Saying Thank You to Dr. Lavelle
Thank you for all the resources you provided Dr.Lavelle, all the support you provided us with in the form of UA and multiple review sessions made me wish I had taken 14A with you as well.
- Sun Mar 14, 2021 11:22 am
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: calculating H through bond enthalpies
- Replies: 4
- Views: 357
Re: calculating H through bond enthalpies
Is there any case where breaking bonds is not endothermic process, ie, the sign of the enthalpy change is not positive and therefore negative.
- Sun Mar 14, 2021 11:20 am
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Self Test 4A.3A
- Replies: 4
- Views: 598
Re: Self Test 4A.3A
How are we supposed to know whether work done on a system is positive or negative If the work you calculate is positive then work is being done ON the system. If the work is negative, then work is being done by the system. If you think about it conceptually, when work is positive then work is being...
- Sun Mar 14, 2021 7:19 am
- Forum: Administrative Questions and Class Announcements
- Topic: Spring Forward March 14! Make sure to set your clocks!
- Replies: 18
- Views: 1815
Re: Spring Forward March 14! Make sure to set your clocks!
I thought I should also tell all my fellow international students to be wary of this - especially because we have to account for daylight savings and time difference now.
Good Luck !
Good Luck !
- Sun Mar 14, 2021 1:56 am
- Forum: Balancing Redox Reactions
- Topic: oxidation numbers
- Replies: 9
- Views: 698
oxidation numbers
What are the steps for determining oxidation number ?
- Fri Mar 12, 2021 10:34 pm
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: Sapling Week9/10 #12
- Replies: 3
- Views: 323
Sapling Week9/10 #12
Can someone explain the steps for solving this question
- Fri Mar 12, 2021 9:28 pm
- Forum: General Rate Laws
- Topic: Order of a reaction
- Replies: 10
- Views: 707
Re: Order of a reaction
The order for each reactant/product is typically obtained through experiments. Looking at a table which contains the initial concentrations of the reactants/products, and the initial rates, you are able to determine the order of the reactants/products. Remember the general rate law equation, which ...
- Sun Mar 07, 2021 9:47 am
- Forum: General Rate Laws
- Topic: Sapling 9/10 #5
- Replies: 10
- Views: 2950
Re: Sapling 9/10 #5
Hi! For problems like this, I like to substitute the "new" concentrations into the equation. For example, for [A] halved and [B] tripled, the new rate equation would be rate = k[1/2A][3B]^2, then I move the constants to the front so rate = 9/2 k[A][B]^2. Since k[A][B]^2 is equal to the or...
- Sun Mar 07, 2021 9:32 am
- Forum: General Rate Laws
- Topic: Week 9/10 Sapling #3
- Replies: 6
- Views: 379
Re: Week 9/10 Sapling #3
Hi! I used the point (80, .2) with the given value .35 for 40 from the table. (.2-.35)/(80-40) gave me the correct answer! I formatted it as .00375. Lemme know if you need anything. Thats so odd, because the feedback that I got for the question if what told me to use the point 0,0.48. Thanks for le...
- Sun Mar 07, 2021 7:55 am
- Forum: General Rate Laws
- Topic: Order of a reaction
- Replies: 10
- Views: 707
Order of a reaction
How are we supposed to determine the order of a reaction. In the textbook, it has been stated that decomposition of N205 has a=1 and N02 has a=2. How is this obtained. I remember seeing somewhere that an order of a reaction if influenced by the order of the reactants and products. if this is true, h...
- Sun Mar 07, 2021 4:58 am
- Forum: General Rate Laws
- Topic: Week 9/10 Sapling #3
- Replies: 6
- Views: 379
Week 9/10 Sapling #3
For this question, I followed the steps correctly, even tried to do the sum twice, but my answer seems to be wrong. I calculated the slope of the tangent at t=40 s and used the points (0,0.48) and ( 40, 0.35)
- Sun Mar 07, 2021 4:20 am
- Forum: Student Social/Study Group
- Topic: 14B Final
- Replies: 22
- Views: 1070
Re: 14B Final
yes, of someone could share a sample study schedule that would be very helpful
- Sun Mar 07, 2021 4:08 am
- Forum: Student Social/Study Group
- Topic: What do you miss / What are you looking forward to?
- Replies: 92
- Views: 10451
Re: What do you miss / What are you looking forward to?
I'm a sophomore, so I had a few months to experience campus before I had to leave. One of the things I miss the most is being in the LA timezone. I feel so disconnected from everything I can't even believe that my second year of college is almost over. I miss the Study at 2 am, and walking to class ...
- Sun Mar 07, 2021 3:37 am
- Forum: Student Social/Study Group
- Topic: Final Study Tips!
- Replies: 38
- Views: 2347
Re: Final Study Tips!
Last quarter, I found that the most helpful for me was probably the outlines and the older sapling assignments. The outlines for me help because it breaks it up into the sections we learned it and when I review it in the order we learned it it helps me. Also I think the older sapling assignments ar...
- Sun Mar 07, 2021 3:21 am
- Forum: Zero Order Reactions
- Topic: Sapling Question week 9/10
- Replies: 18
- Views: 4085
Re: Sapling Question week 9/10
Can you explain how you found the order of the reactant
- Sun Feb 28, 2021 11:32 pm
- Forum: Balancing Redox Reactions
- Topic: Sapling Week 7/8 #5
- Replies: 9
- Views: 499
Re: Sapling Week 7/8 #5
Samir 3I wrote:Pratika Nagpal wrote:I'm having a similar problem, but with this question. Could someone help please ?
The balanced equation would be 2MnO4- +3S2- +4H2O ---> 3S +2MnO2 +8OH-
Great, Thanks so much, would you be able to explain the steps to me, so I can understand the process of getting this balancing better.
- Sun Feb 28, 2021 10:49 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: Sapling #12
- Replies: 4
- Views: 273
Re: Sapling #12
I followed all these steps, but I wasn't able to get the correct answer, does anyone have any idea what I might be doing wrong
- Sun Feb 28, 2021 10:44 pm
- Forum: Balancing Redox Reactions
- Topic: Sapling Week 7/8 question 5
- Replies: 2
- Views: 185
Sapling Week 7/8 question 5
I can't seem to figure this out. I know I need to balance it using OH- since it is in basic solution, but I cant figure out to balance the hydrogens out after that
- Sun Feb 28, 2021 10:41 pm
- Forum: Balancing Redox Reactions
- Topic: Sapling Week 7/8 #5
- Replies: 9
- Views: 499
Re: Sapling Week 7/8 #5
I'm having a similar problem, but with this question. Could someone help please ?
- Sun Feb 28, 2021 10:30 pm
- Forum: Balancing Redox Reactions
- Topic: Sapling Week 7/8 Question 5
- Replies: 2
- Views: 281
Re: Sapling Week 7/8 Question 5
The answer you should get for this is :
[Pb(OH)4]2−(aq)+ClO−(aq)⟶PbO2(s)+Cl−(aq)+H2O(l)+2OH−(aq)
[Pb(OH)4]2−(aq)+ClO−(aq)⟶PbO2(s)+Cl−(aq)+H2O(l)+2OH−(aq)
- Sun Feb 28, 2021 9:30 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: Sapling Week 7/8 question 15
- Replies: 6
- Views: 427
Re: Sapling Week 7/8 question 15
All of these responses are super helpful. Thank you !
- Sun Feb 28, 2021 9:03 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: Sapling Week 7/8 question 15
- Replies: 6
- Views: 427
Sapling Week 7/8 question 15
Can someone help me with the steps to solve this.
- Sun Feb 28, 2021 6:58 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: Sapling Week 7/8 question 18
- Replies: 3
- Views: 232
Re: Sapling Week 7/8 question 18
removing the parenthesises worked. Thanks a lot
- Sun Feb 28, 2021 6:56 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: Sapling Week 7/8 #7
- Replies: 10
- Views: 522
Re: Sapling Week 7/8 #7
This helped, Thank you .
- Sun Feb 28, 2021 6:53 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: Sapling Week 7/8 #7
- Replies: 10
- Views: 653
Re: Sapling Week 7/8 #7
I didn't get it right when I flipped them either.
- Sun Feb 28, 2021 3:11 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: Sapling Week 7/8 question 18
- Replies: 3
- Views: 232
Sapling Week 7/8 question 18
Could someone please help me understand what Is wrong about my balanced equation - I can't find any error but Sapling won't accept the answer. I tried it with the phases too, it was still marked incorrect.
See attachment.
See attachment.
- Sun Feb 28, 2021 2:45 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: Sapling Week 7/8 #7
- Replies: 10
- Views: 653
Sapling Week 7/8 #7
Can someone help me out with this. I keep trying, but I can't seem to figure it out.
- Sun Feb 28, 2021 1:52 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: Sapling Week 7/8 #7
- Replies: 10
- Views: 522
Sapling Week 7/8 #7
Can someone help me out with this. I keep trying, but I can't seem to figure it out.
- Sun Feb 28, 2021 1:24 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: Sapling #9
- Replies: 3
- Views: 257
Re: Sapling #9
Is there any way to know which is at the cathode/anode or which is being reduced/oxidized just from looking at the values of the standard reduction potentials ?
- Mon Feb 22, 2021 12:26 am
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Work in a Constant Volume
- Replies: 13
- Views: 953
Re: Work in a Constant Volume
I don't exactly know how to relate this to neutralization of a reaction, but a neutralisation reaction is basically the reaction between an acid and a base to form a soluble salt and water. Neturalisation reactions are usually exothermic due to the formation of the bond between hydrogen and oxygen t...
- Sun Feb 21, 2021 11:37 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Work in a Constant Volume
- Replies: 13
- Views: 953
Re: Work in a Constant Volume
There are 2 ways to think about this, either conceptually or mathematically - the formula for work is PdeltaV and no change in volume delta v =0 , and therefore w=0. Another way to think about it since there is no expansion, there is no work done by the system. and therefore work is 0
- Fri Feb 19, 2021 6:34 am
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Self Test 4A.3A
- Replies: 4
- Views: 598
Re: Self Test 4A.3A
How are we supposed to know whether work done on a system is positive or negative
- Sun Feb 14, 2021 1:10 pm
- Forum: Entropy Changes Due to Changes in Volume and Temperature
- Topic: W5/6 Sapling #6
- Replies: 6
- Views: 520
Re: W5/6 Sapling #6
You will need to multiply the Cvm by the number of moles to get the Cv, which you can then plug into your equation. It is important to note whether the value being given is the molar heat capacity or the heat capacity
- Wed Jan 27, 2021 9:38 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Concentration, Volume, and Pressure
- Replies: 3
- Views: 111
Re: Concentration, Volume, and Pressure
Why is this statement false
(c) If one starts with a higher pressure of reactant, the equilibrium constant will be larger.
(c) If one starts with a higher pressure of reactant, the equilibrium constant will be larger.
- Sun Jan 10, 2021 9:02 pm
- Forum: Administrative Questions and Class Announcements
- Topic: Accessing the E-textbook [ENDORSED]
- Replies: 125
- Views: 33062
Re: Accessing the E-textbook [ENDORSED]
When we purchase Sapling, do we get an access code, online or do we have to get the physical access card shipped to us.
Is there anyway to get the code online, for International Students - since shipping it would be an expense almost the price of the code itself
Is there anyway to get the code online, for International Students - since shipping it would be an expense almost the price of the code itself