Search found 48 matches

by Pratika Nagpal
Sun Mar 14, 2021 12:05 pm
Forum: Thermodynamic Systems (Open, Closed, Isolated)
Topic: Degeneracy
Replies: 11
Views: 922

Re: Degeneracy

What are some examples of questions we could get asked about degeneracy.
by Pratika Nagpal
Sun Mar 14, 2021 12:04 pm
Forum: Thermodynamic Definitions (isochoric/isometric, isothermal, isobaric)
Topic: Which R to use
Replies: 42
Views: 3087

Re: Which R to use

The R you need to use is dependent on the units.
by Pratika Nagpal
Sun Mar 14, 2021 12:01 pm
Forum: Reaction Mechanisms, Reaction Profiles
Topic: Sapling Week9/10 #12
Replies: 3
Views: 323

Re: Sapling Week9/10 #12

Thanks for the help!
by Pratika Nagpal
Sun Mar 14, 2021 12:00 pm
Forum: Calculating Work of Expansion
Topic: Work and Delta V
Replies: 20
Views: 2597

Re: Work and Delta V

even though there is no measurable change and in volume and no source of pressure isn't the act of expansion, means work is done BY THE SYSTEM
by Pratika Nagpal
Sun Mar 14, 2021 11:53 am
Forum: Environment, Ozone, CFCs
Topic: catalysis vs intermediate
Replies: 25
Views: 2036

Re: catalysis vs intermediate

Malakai Espinosa 3E wrote:Also a difference to note, catalysts can be included in your rate law if they are in the slow step, but intermediates cannot!


why is the rate law governed by the slow step
by Pratika Nagpal
Sun Mar 14, 2021 11:51 am
Forum: Environment, Ozone, CFCs
Topic: catalysis vs intermediate
Replies: 25
Views: 2036

Re: catalysis vs intermediate

For a visual example: A + B --> C + D D + E --> B + F B would be the catalyst C would be the intermediate is B the catalyst in both? I think that this is showing the two elementary steps of the overall reaction A + E (+B) --> C + F (+B). In this case, B is a catalyst in the overall reaction because...
by Pratika Nagpal
Sun Mar 14, 2021 11:48 am
Forum: Student Social/Study Group
Topic: Final Jitters
Replies: 457
Views: 377861

Re: Final Jitters

every time I feel myself getting stressed, it helps to take a beat, close your eyes for a few seconds and breathe deeply.
by Pratika Nagpal
Sun Mar 14, 2021 11:47 am
Forum: Arrhenius Equation, Activation Energies, Catalysts
Topic: Free Energy of Activation
Replies: 6
Views: 481

Re: Free Energy of Activation

Activation energy is the energy that needs to be provided to the system for the reaction to occur.

Free energy of activation refers to Gibbs Free energy.
by Pratika Nagpal
Sun Mar 14, 2021 11:42 am
Forum: Zero Order Reactions
Topic: Are zero order reactions always true for any condition?
Replies: 2
Views: 469

Re: Are zero order reactions always true for any condition?

This is really interesting, I was under the impression that reactions had fixed orders, instead of thinking of them a dependent on a set of conditions.
by Pratika Nagpal
Sun Mar 14, 2021 11:40 am
Forum: Biological Examples
Topic: Enzymes
Replies: 13
Views: 1799

Re: Enzymes

Are heterogenous catalysts formed again at the end of the reaction. for example, will a solid catalyst be able to be recovered at the end of a reaction ?
by Pratika Nagpal
Sun Mar 14, 2021 11:36 am
Forum: First Order Reactions
Topic: Half-life independent from initial concentration
Replies: 8
Views: 1647

Re: Half-life independent from initial concentration

is there any mathematical way of understanding why half like of a first order reaction is independent of the concentration - other than considering the ln2/k formula
by Pratika Nagpal
Sun Mar 14, 2021 11:32 am
Forum: Equilibrium Constants & Calculating Concentrations
Topic: pka vs ka
Replies: 28
Views: 1427

Re: pka vs ka

what is the difference between pka and ka and pkb and kb
by Pratika Nagpal
Sun Mar 14, 2021 11:30 am
Forum: Equilibrium Constants & Calculating Concentrations
Topic: Determining The Favored Side of an Equilibrium Product
Replies: 12
Views: 1266

Re: Determining The Favored Side of an Equilibrium Product

does it matter how much less than or more than K, Q is.

like is there a particular threshold after which we can determine whether products or reactants will be favoured ?
by Pratika Nagpal
Sun Mar 14, 2021 11:28 am
Forum: Administrative Questions and Class Announcements
Topic: Saying Thank You to Dr. Lavelle
Replies: 490
Views: 571609

Re: Saying Thank You to Dr. Lavelle

Thank you for all the resources you provided Dr.Lavelle, all the support you provided us with in the form of UA and multiple review sessions made me wish I had taken 14A with you as well.
by Pratika Nagpal
Sun Mar 14, 2021 11:22 am
Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
Topic: calculating H through bond enthalpies
Replies: 4
Views: 357

Re: calculating H through bond enthalpies

Is there any case where breaking bonds is not endothermic process, ie, the sign of the enthalpy change is not positive and therefore negative.
by Pratika Nagpal
Sun Mar 14, 2021 11:20 am
Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
Topic: Self Test 4A.3A
Replies: 4
Views: 598

Re: Self Test 4A.3A

How are we supposed to know whether work done on a system is positive or negative If the work you calculate is positive then work is being done ON the system. If the work is negative, then work is being done by the system. If you think about it conceptually, when work is positive then work is being...
by Pratika Nagpal
Sun Mar 14, 2021 7:19 am
Forum: Administrative Questions and Class Announcements
Topic: Spring Forward March 14! Make sure to set your clocks!
Replies: 18
Views: 1815

Re: Spring Forward March 14! Make sure to set your clocks!

I thought I should also tell all my fellow international students to be wary of this - especially because we have to account for daylight savings and time difference now.
Good Luck !
by Pratika Nagpal
Sun Mar 14, 2021 1:56 am
Forum: Balancing Redox Reactions
Topic: oxidation numbers
Replies: 9
Views: 698

oxidation numbers

What are the steps for determining oxidation number ?
by Pratika Nagpal
Fri Mar 12, 2021 10:34 pm
Forum: Reaction Mechanisms, Reaction Profiles
Topic: Sapling Week9/10 #12
Replies: 3
Views: 323

Sapling Week9/10 #12

Can someone explain the steps for solving this question
by Pratika Nagpal
Fri Mar 12, 2021 9:28 pm
Forum: General Rate Laws
Topic: Order of a reaction
Replies: 10
Views: 707

Re: Order of a reaction

The order for each reactant/product is typically obtained through experiments. Looking at a table which contains the initial concentrations of the reactants/products, and the initial rates, you are able to determine the order of the reactants/products. Remember the general rate law equation, which ...
by Pratika Nagpal
Sun Mar 07, 2021 9:47 am
Forum: General Rate Laws
Topic: Sapling 9/10 #5
Replies: 10
Views: 2950

Re: Sapling 9/10 #5

Hi! For problems like this, I like to substitute the "new" concentrations into the equation. For example, for [A] halved and [B] tripled, the new rate equation would be rate = k[1/2A][3B]^2, then I move the constants to the front so rate = 9/2 k[A][B]^2. Since k[A][B]^2 is equal to the or...
by Pratika Nagpal
Sun Mar 07, 2021 9:32 am
Forum: General Rate Laws
Topic: Week 9/10 Sapling #3
Replies: 6
Views: 379

Re: Week 9/10 Sapling #3

Hi! I used the point (80, .2) with the given value .35 for 40 from the table. (.2-.35)/(80-40) gave me the correct answer! I formatted it as .00375. Lemme know if you need anything. Thats so odd, because the feedback that I got for the question if what told me to use the point 0,0.48. Thanks for le...
by Pratika Nagpal
Sun Mar 07, 2021 7:55 am
Forum: General Rate Laws
Topic: Order of a reaction
Replies: 10
Views: 707

Order of a reaction

How are we supposed to determine the order of a reaction. In the textbook, it has been stated that decomposition of N205 has a=1 and N02 has a=2. How is this obtained. I remember seeing somewhere that an order of a reaction if influenced by the order of the reactants and products. if this is true, h...
by Pratika Nagpal
Sun Mar 07, 2021 4:58 am
Forum: General Rate Laws
Topic: Week 9/10 Sapling #3
Replies: 6
Views: 379

Week 9/10 Sapling #3

For this question, I followed the steps correctly, even tried to do the sum twice, but my answer seems to be wrong. I calculated the slope of the tangent at t=40 s and used the points (0,0.48) and ( 40, 0.35)
by Pratika Nagpal
Sun Mar 07, 2021 4:20 am
Forum: Student Social/Study Group
Topic: 14B Final
Replies: 22
Views: 1070

Re: 14B Final

yes, of someone could share a sample study schedule that would be very helpful
by Pratika Nagpal
Sun Mar 07, 2021 4:08 am
Forum: Student Social/Study Group
Topic: What do you miss / What are you looking forward to?
Replies: 92
Views: 10451

Re: What do you miss / What are you looking forward to?

I'm a sophomore, so I had a few months to experience campus before I had to leave. One of the things I miss the most is being in the LA timezone. I feel so disconnected from everything I can't even believe that my second year of college is almost over. I miss the Study at 2 am, and walking to class ...
by Pratika Nagpal
Sun Mar 07, 2021 3:37 am
Forum: Student Social/Study Group
Topic: Final Study Tips!
Replies: 38
Views: 2347

Re: Final Study Tips!

Last quarter, I found that the most helpful for me was probably the outlines and the older sapling assignments. The outlines for me help because it breaks it up into the sections we learned it and when I review it in the order we learned it it helps me. Also I think the older sapling assignments ar...
by Pratika Nagpal
Sun Mar 07, 2021 3:21 am
Forum: Zero Order Reactions
Topic: Sapling Question week 9/10
Replies: 18
Views: 4085

Re: Sapling Question week 9/10

Can you explain how you found the order of the reactant
by Pratika Nagpal
Sun Feb 28, 2021 11:32 pm
Forum: Balancing Redox Reactions
Topic: Sapling Week 7/8 #5
Replies: 9
Views: 499

Re: Sapling Week 7/8 #5

Samir 3I wrote:
Pratika Nagpal wrote:I'm having a similar problem, but with this question. Could someone help please ?

The balanced equation would be 2MnO4- +3S2- +4H2O ---> 3S +2MnO2 +8OH-


Great, Thanks so much, would you be able to explain the steps to me, so I can understand the process of getting this balancing better.
by Pratika Nagpal
Sun Feb 28, 2021 10:49 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: Sapling #12
Replies: 4
Views: 273

Re: Sapling #12

I followed all these steps, but I wasn't able to get the correct answer, does anyone have any idea what I might be doing wrong
by Pratika Nagpal
Sun Feb 28, 2021 10:44 pm
Forum: Balancing Redox Reactions
Topic: Sapling Week 7/8 question 5
Replies: 2
Views: 185

Sapling Week 7/8 question 5

I can't seem to figure this out. I know I need to balance it using OH- since it is in basic solution, but I cant figure out to balance the hydrogens out after that
by Pratika Nagpal
Sun Feb 28, 2021 10:41 pm
Forum: Balancing Redox Reactions
Topic: Sapling Week 7/8 #5
Replies: 9
Views: 499

Re: Sapling Week 7/8 #5

I'm having a similar problem, but with this question. Could someone help please ?
by Pratika Nagpal
Sun Feb 28, 2021 10:30 pm
Forum: Balancing Redox Reactions
Topic: Sapling Week 7/8 Question 5
Replies: 2
Views: 281

Re: Sapling Week 7/8 Question 5

The answer you should get for this is :
[Pb(OH)4]2−(aq)+ClO−(aq)⟶PbO2(s)+Cl−(aq)+H2O(l)+2OH−(aq)
by Pratika Nagpal
Sun Feb 28, 2021 9:30 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: Sapling Week 7/8 question 15
Replies: 6
Views: 427

Re: Sapling Week 7/8 question 15

All of these responses are super helpful. Thank you !
by Pratika Nagpal
Sun Feb 28, 2021 9:03 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: Sapling Week 7/8 question 15
Replies: 6
Views: 427

Sapling Week 7/8 question 15

Can someone help me with the steps to solve this.
by Pratika Nagpal
Sun Feb 28, 2021 6:58 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: Sapling Week 7/8 question 18
Replies: 3
Views: 232

Re: Sapling Week 7/8 question 18

removing the parenthesises worked. Thanks a lot
by Pratika Nagpal
Sun Feb 28, 2021 6:56 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: Sapling Week 7/8 #7
Replies: 10
Views: 522

Re: Sapling Week 7/8 #7

This helped, Thank you .
by Pratika Nagpal
Sun Feb 28, 2021 6:53 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: Sapling Week 7/8 #7
Replies: 10
Views: 653

Re: Sapling Week 7/8 #7

I didn't get it right when I flipped them either.
by Pratika Nagpal
Sun Feb 28, 2021 3:11 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: Sapling Week 7/8 question 18
Replies: 3
Views: 232

Sapling Week 7/8 question 18

Could someone please help me understand what Is wrong about my balanced equation - I can't find any error but Sapling won't accept the answer. I tried it with the phases too, it was still marked incorrect.

See attachment.
by Pratika Nagpal
Sun Feb 28, 2021 2:45 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: Sapling Week 7/8 #7
Replies: 10
Views: 653

Sapling Week 7/8 #7

Can someone help me out with this. I keep trying, but I can't seem to figure it out.
by Pratika Nagpal
Sun Feb 28, 2021 1:52 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: Sapling Week 7/8 #7
Replies: 10
Views: 522

Sapling Week 7/8 #7

Can someone help me out with this. I keep trying, but I can't seem to figure it out.
by Pratika Nagpal
Sun Feb 28, 2021 1:24 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: Sapling #9
Replies: 3
Views: 257

Re: Sapling #9

Is there any way to know which is at the cathode/anode or which is being reduced/oxidized just from looking at the values of the standard reduction potentials ?
by Pratika Nagpal
Mon Feb 22, 2021 12:26 am
Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
Topic: Work in a Constant Volume
Replies: 13
Views: 953

Re: Work in a Constant Volume

I don't exactly know how to relate this to neutralization of a reaction, but a neutralisation reaction is basically the reaction between an acid and a base to form a soluble salt and water. Neturalisation reactions are usually exothermic due to the formation of the bond between hydrogen and oxygen t...
by Pratika Nagpal
Sun Feb 21, 2021 11:37 pm
Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
Topic: Work in a Constant Volume
Replies: 13
Views: 953

Re: Work in a Constant Volume

There are 2 ways to think about this, either conceptually or mathematically - the formula for work is PdeltaV and no change in volume delta v =0 , and therefore w=0. Another way to think about it since there is no expansion, there is no work done by the system. and therefore work is 0
by Pratika Nagpal
Fri Feb 19, 2021 6:34 am
Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
Topic: Self Test 4A.3A
Replies: 4
Views: 598

Re: Self Test 4A.3A

How are we supposed to know whether work done on a system is positive or negative
by Pratika Nagpal
Sun Feb 14, 2021 1:10 pm
Forum: Entropy Changes Due to Changes in Volume and Temperature
Topic: W5/6 Sapling #6
Replies: 6
Views: 520

Re: W5/6 Sapling #6

You will need to multiply the Cvm by the number of moles to get the Cv, which you can then plug into your equation. It is important to note whether the value being given is the molar heat capacity or the heat capacity
by Pratika Nagpal
Wed Jan 27, 2021 9:38 pm
Forum: Equilibrium Constants & Calculating Concentrations
Topic: Concentration, Volume, and Pressure
Replies: 3
Views: 111

Re: Concentration, Volume, and Pressure

Why is this statement false
(c) If one starts with a higher pressure of reactant, the equilibrium constant will be larger.
by Pratika Nagpal
Sun Jan 10, 2021 9:02 pm
Forum: Administrative Questions and Class Announcements
Topic: Accessing the E-textbook [ENDORSED]
Replies: 125
Views: 33062

Re: Accessing the E-textbook [ENDORSED]

When we purchase Sapling, do we get an access code, online or do we have to get the physical access card shipped to us.
Is there anyway to get the code online, for International Students - since shipping it would be an expense almost the price of the code itself

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