Search found 108 matches

by Isabel_Eslabon_2G
Mon Mar 15, 2021 9:56 am
Forum: Concepts & Calculations Using First Law of Thermodynamics
Topic: Calorimeter
Replies: 6
Views: 611

Re: Calorimeter

I don’t know if this is correct, but I just use q = C(delta)T.
by Isabel_Eslabon_2G
Mon Mar 15, 2021 9:54 am
Forum: First Order Reactions
Topic: Half Life Unit
Replies: 38
Views: 1649

Re: Half Life Unit

If you’re solving for half life, then the units really depend on the units of k. Just remember to write out your units when you do the math.

It can be in seconds, minutes, hours, whatever the problem (or answer choices) say it is.
by Isabel_Eslabon_2G
Mon Mar 15, 2021 9:52 am
Forum: Zero Order Reactions
Topic: Overall order of the reaction
Replies: 45
Views: 2084

Re: Overall order of the reaction

The overall order of a reaction is the sum of the orders of the reaction’s elementary steps.
by Isabel_Eslabon_2G
Mon Mar 15, 2021 9:49 am
Forum: General Science Questions
Topic: Final thoughts
Replies: 28
Views: 4924

Re: Final thoughts

I thought the final was a lot easier than the one from 14A. I also had an easier time with the final compared to midterm 2, which I thought was the hardest exam this quarter. Maybe it’s because I’m just not as strong in thermo relative to equilibrium, redox, & kinetics.
by Isabel_Eslabon_2G
Mon Mar 15, 2021 9:47 am
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: Cell Diagrams
Replies: 2
Views: 306

Re: Cell Diagrams

You include Pt when there isn’t a solid electrode in the cell where a reduction or oxidation reaction is occurring.

Pt is an inert electrode and won’t be involved in the redox reaction.
by Isabel_Eslabon_2G
Sat Mar 13, 2021 3:11 am
Forum: Arrhenius Equation, Activation Energies, Catalysts
Topic: Catalysts and intermediates
Replies: 10
Views: 639

Re: Catalysts and intermediates

This is how I reason through it: Usually, an intermediate is produced by one of the elementary steps and is consumed as a reactant of another elementary step (appears in the product side of one step, appears in reactant side of following step). This intermediate was consumed. A catalyst first comes ...
by Isabel_Eslabon_2G
Wed Mar 10, 2021 7:20 am
Forum: Student Social/Study Group
Topic: Calculators
Replies: 52
Views: 3539

Re: Calculators

I think the scientific calculators are preferred, but as long as you aren't using the graphing calculator-exclusive functions (like storing equations, etc.), then it's fine. During exams people show their graphing calculators when showing their other papers and the TAs seem fine with it.
by Isabel_Eslabon_2G
Wed Mar 10, 2021 7:19 am
Forum: Method of Initial Rates (To Determine n and k)
Topic: Initial Rates = Maximum rates [ENDORSED]
Replies: 9
Views: 867

Re: Initial Rates = Maximum rates [ENDORSED]

I think the initial rate is considered the maximum rate because there is the most reactant available. Once the reaction starts occurring, the amount of reactant decreases. During the initial rate, there is very little product formed, so the reverse reaction is considered to not be taking place (of c...
by Isabel_Eslabon_2G
Wed Mar 10, 2021 7:12 am
Forum: Kinetics vs. Thermodynamics Controlling a Reaction
Topic: Exergonic vs Exothermic [ENDORSED]
Replies: 4
Views: 411

Re: Exergonic vs Exothermic [ENDORSED]

Exergonic and endergonic usually refer to Gibbs free energy.

Endothermic & exothermic refer to enthalpy.

I remember it because exergonic & endergonic have "g" like Gibbs while endothermic & exothermic have "th" like enthalpy.
by Isabel_Eslabon_2G
Wed Mar 10, 2021 7:10 am
Forum: Kinetics vs. Thermodynamics Controlling a Reaction
Topic: What was your favorite chem topic?
Replies: 137
Views: 11702

Re: What was your favorite chem topic?

I think I enjoyed chemical equilibrium at the beginning of 14B the most. Second is probably Lewis Structures and things related to that.
by Isabel_Eslabon_2G
Sun Mar 07, 2021 10:14 pm
Forum: Administrative Questions and Class Announcements
Topic: FINAL EXAM QUESTIONS
Replies: 40
Views: 2799

Re: FINAL EXAM QUESTIONS

Based on past experience with Chem 14A, there is probably going to be some problems from the textbook, but the majority will not be directly from the textbook. That being said, doing textbook problems are still a really good way to study for the final.
by Isabel_Eslabon_2G
Sun Mar 07, 2021 9:06 pm
Forum: Reaction Mechanisms, Reaction Profiles
Topic: Catalysts
Replies: 4
Views: 307

Re: Catalysts

I think Ian Wheeler is correct about poisoning. From my understanding, enzymes can be inhibited by poisons when those poisons act as competitive or noncompetitive inhibitors. Competitive inhibitors bind to the active site of enzymes (site on enzyme where they catalyze a reaction, thus blocking subst...
by Isabel_Eslabon_2G
Sun Mar 07, 2021 8:57 pm
Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
Topic: Cell Notation
Replies: 5
Views: 433

Re: Cell Notation

I think the solid compound is the electrode. Example: Cu(s) | Cu2+(aq) || Fe3+(aq), Fe2+(aq) | Pt(s) This represents the redox reaction Fe3+(aq) + Cu(s) → Cu2+(aq) + Fe2+(aq). On the left side, Cu(s) is being oxidized to Cu2+(aq). Cu(s) on the left and Cu2+(aq) on the right represents the direction ...
by Isabel_Eslabon_2G
Sun Mar 07, 2021 8:48 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: E° vs. E and G° vs. G
Replies: 25
Views: 1083

Re: E° vs. E and G° vs. G

Yes, you are correct. Standard conditions are when something occurs at 1 atm or 1 M and at 298 K or 25°C. The E° and G° are used as standards because these values don't actually change. They serve as a sort of "base" or comparison to measure E & G values when certain factors are change...
by Isabel_Eslabon_2G
Sun Mar 07, 2021 8:41 pm
Forum: Student Social/Study Group
Topic: How do you deal with burnout?
Replies: 144
Views: 17163

Re: How do you deal with burnout?

I don't know if this works for everyone, but I usually feel burnt out if I do a lot of work in one sitting without break (sometimes I get a burst of motivation and ride that wave until I can't work any longer). Afterwards I am unmotivated to work for a very long time. Especially because everything's...
by Isabel_Eslabon_2G
Sun Feb 28, 2021 11:37 pm
Forum: *Organic Reaction Mechanisms in General
Topic: K meaning
Replies: 29
Views: 2290

Re: K meaning

is Boltzmann's constant and is
It is located on the very top right on the Constants and Formulas Sheet.
by Isabel_Eslabon_2G
Sun Feb 28, 2021 9:53 pm
Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
Topic: Salt Bridges
Replies: 41
Views: 3220

Re: Salt Bridges

Salt bridges help keep electrons moving from the anode to the cathode. Spectator ions move from one solution to another via the salt bridge. This prevents the charge from evening out across both sides of the cell, which would prevent electrons from continuously flowing in one direction.
by Isabel_Eslabon_2G
Sun Feb 28, 2021 9:48 pm
Forum: Balancing Redox Reactions
Topic: Sapling Week 7/8 #18 Clarification
Replies: 2
Views: 190

Sapling Week 7/8 #18 Clarification

Hello.

The problem involves iron(III) oxide trihydrate. What is a hydrate and do we need to determine what hydrates' chemical formulas are for the test?
by Isabel_Eslabon_2G
Sun Feb 28, 2021 9:44 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: E vs E naught
Replies: 36
Views: 1734

Re: E vs E naught

E° is just E under standard conditions, which are 1 M, 1 atm, & at 25°C (or 298 K).
by Isabel_Eslabon_2G
Thu Feb 25, 2021 12:16 pm
Forum: Balancing Redox Reactions
Topic: Oxidizing vs Reducing
Replies: 55
Views: 2672

Re: Oxidizing vs Reducing

I just remember that in a redox reaction, if one species is being reduced, another is being oxidized. OILRIG (oxidation is loss, reduction is gain) If Species X is being reduced, it is causing Species Y to be oxidized because X gains the electrons that Y lost. What is being reduced is the oxidizing ...
by Isabel_Eslabon_2G
Sun Feb 21, 2021 11:13 pm
Forum: Ideal Gases
Topic: Temperature
Replies: 99
Views: 7031

Re: Temperature

If it isn't given in a problem, you usually assume it's 298 K (or 25°C). I used to wonder this too but that is how it is in a lot of the Sapling textbook questions. If there is any ambiguity during an exam and you just want to be safe, I'm sure your TA will clarify it anyway.
by Isabel_Eslabon_2G
Fri Feb 19, 2021 1:18 am
Forum: Calculating Standard Reaction Entropies (e.g. , Using Standard Molar Entropies)
Topic: Textbook 4.37
Replies: 1
Views: 182

Textbook 4.37

The question is: Under what conditions, if any, does the sign of each of the following quantities provide a criterion for assessing the spontaneity of a reaction? (a) ΔG°; (b) ΔH°; (c) ΔS°; (d) ΔS(total). Answers: ∆G° < 0 ∆H°: unable to tell ∆S°: unable to tell ∆S(total) > 0 What is the difference b...
by Isabel_Eslabon_2G
Thu Feb 18, 2021 7:15 pm
Forum: Calculating Standard Reaction Entropies (e.g. , Using Standard Molar Entropies)
Topic: Entropies of Solid Products vs. Solid Reactants?
Replies: 2
Views: 286

Entropies of Solid Products vs. Solid Reactants?

The textbook problem 4H.11 asks you to find ∆S for reactions using the reactants' & products' standard molar entropies. For the reaction: 4KClO_{3(s)} \rightarrow 3KClO_{4(s)} + KCl_{(s)} ∆S° for the reaction = -36.81 J/(K•mol) We have to explain why the entropy is decrea...
by Isabel_Eslabon_2G
Thu Feb 18, 2021 1:21 am
Forum: Calculating Work of Expansion
Topic: Textbook Problem 4A.3
Replies: 3
Views: 260

Textbook Problem 4A.3

For part a, you find work by multiplying pressure, volume, and another value.

w = -(2.00 atm)(-0.14 L)(101.325 J/(L•atm)) = 28 J

What is the 101.325 J/(L•atm) value? I can't seem to find it in my notes. And why do we multiply it with the pressure & volume?
by Isabel_Eslabon_2G
Wed Feb 17, 2021 8:45 pm
Forum: Thermodynamic Systems (Open, Closed, Isolated)
Topic: R gas constant and kPa or Pa
Replies: 9
Views: 3282

R gas constant and kPa or Pa

I was going over the Sapling homework and problem #5 gives pressure in kPa.

What gas constant would we use when given that unit of pressure? Do we use 8.314 J/(K•mol)?
Also, why is the 8.314 J/(K•mol) the only value of R that doesn't have a unit of pressure in the units?
by Isabel_Eslabon_2G
Wed Feb 17, 2021 8:02 pm
Forum: Calculating Standard Reaction Entropies (e.g. , Using Standard Molar Entropies)
Topic: Sapling Week 5/6 #7 Feedback Question
Replies: 1
Views: 128

Sapling Week 5/6 #7 Feedback Question

So I was completing a Sapling homework problem where we had to list compounds from most to least ordered according to ∆S(vap). I got it wrong the first time (got it right the 2nd time), but I was confused about this text from the feedback: "A larger molar entropy of vaporization, which correlat...
by Isabel_Eslabon_2G
Sun Feb 14, 2021 7:39 pm
Forum: Calculating Work of Expansion
Topic: irreversible vs reversible
Replies: 14
Views: 735

Re: irreversible vs reversible

Reversible expansions occur slower than irreversible expansions. If an expansion is "quick" or "sudden", then it's most likely irreversible. If the expansion is "slow" or "gradual", then it is most likely reversible.
by Isabel_Eslabon_2G
Sun Feb 14, 2021 7:36 pm
Forum: Van't Hoff Equation
Topic: Celcius vs Kelvin for T1 and T2
Replies: 84
Views: 7118

Re: Celcius vs Kelvin for T1 and T2

I usually always convert to Kelvin because most of our constants use Kelvin. Unless a constant given specifically uses Celsius or the question asks you to use/give your answer in Celsius, just use Kelvin.
by Isabel_Eslabon_2G
Sun Feb 14, 2021 7:31 pm
Forum: Thermodynamic Definitions (isochoric/isometric, isothermal, isobaric)
Topic: Sapling 3
Replies: 13
Views: 606

Re: Sapling 3

This is how I worked it out (I'll use water as a place holder): Solid to Liquid: +∆H & +∆S energy + H2O(s) → H2O(l) Ice becomes liquid when energy (heat) is added to it. This would mean the reaction is endothermic (+∆H). When a solid becomes a liquid, entropy increases because the # of possible ...
by Isabel_Eslabon_2G
Sun Feb 14, 2021 7:24 pm
Forum: Gibbs Free Energy Concepts and Calculations
Topic: Likeliness to form products/reactants
Replies: 27
Views: 988

Re: Likeliness to form products/reactants

For A + B → C:
If ∆G < 0 (is negative), then the reaction is spontaneous. This means the forward reaction is favored (producing C).
If ∆G > 0 (is positive), then the reaction isn't spontaneous (in the forward direction). This means the reverse reaction is favored (producing A & B).
by Isabel_Eslabon_2G
Sun Feb 14, 2021 7:18 pm
Forum: Administrative Questions and Class Announcements
Topic: struggling
Replies: 73
Views: 4109

Re: struggling

Hello. The UA sessions are pretty helpful. Even if you can't catch one of their sessions, it's helpful to do the problems they go over. I think usually someone uploads the worksheets after. Make sure not to overwork yourself before the exam. I've done that in the past trying to get lots of studying ...
by Isabel_Eslabon_2G
Sat Feb 06, 2021 10:39 pm
Forum: Concepts & Calculations Using First Law of Thermodynamics
Topic: Key points of First Law
Replies: 8
Views: 248

Re: Key points of First Law

I think that Conservation of Energy is just remembering that energy is moving between system & surrounding. Energy doesn't just "disappear" (it can escape into surroundings).
by Isabel_Eslabon_2G
Sat Feb 06, 2021 10:32 pm
Forum: Student Social/Study Group
Topic: Study tips for thermo
Replies: 14
Views: 883

Re: Study tips for thermo

I don't know how much it will help you, but here are some things that I do: Usually looking at my notes for lectures is overwhelming since it's multiple pages. I make a 1-page sum-up of what we learned per week or per outline. If I don't get ideas from the lecture or from the textbook, I ask Chemist...
by Isabel_Eslabon_2G
Sat Feb 06, 2021 10:29 pm
Forum: General Science Questions
Topic: Careless Mistakes
Replies: 54
Views: 3892

Re: Careless Mistakes

Hello. I don't know if this helps, but after doing lots of practice problems, I have a good idea of what a "reasonable" number would be for my calculation. Like if I was converting grams to moles, usually I wouldn't get a number like 5,000 moles. When I look at intermediate values while ca...
by Isabel_Eslabon_2G
Sat Feb 06, 2021 10:20 pm
Forum: Thermodynamic Systems (Open, Closed, Isolated)
Topic: R Constant
Replies: 91
Views: 6811

Re: R Constant

Whichever R value you use depends on the units of the other values you are given in a problem.
by Isabel_Eslabon_2G
Sat Feb 06, 2021 10:18 pm
Forum: Student Social/Study Group
Topic: Study routine.
Replies: 51
Views: 2747

Re: Study routine.

I would try to do lots of practice problems throughout the weeks before the midterm (not just doing them all right before the midterm; I've done it and for me at least it is not as effective). I think that if you are not doing well when reading the textbook, you should try to listen to videos (Khan ...
by Isabel_Eslabon_2G
Sat Feb 06, 2021 10:11 pm
Forum: Thermodynamic Systems (Open, Closed, Isolated)
Topic: Sapling Week 3/4 #19
Replies: 6
Views: 221

Sapling Week 3/4 #19

Hello. Here is the problem: A constant‑volume calorimeter was calibrated by carrying out a reaction known to release 1.11 kJ of heat in 0.600 L of solution in the calorimeter (q=−1.11 kJ) , resulting in a temperature rise of 2.10 ∘C . In a subsequent experiment, 300.0 mL of 0.10 M HClO2(aq) and 300....
by Isabel_Eslabon_2G
Sat Feb 06, 2021 10:04 pm
Forum: Student Social/Study Group
Topic: Silly Mistakes?
Replies: 72
Views: 6502

Re: Silly Mistakes?

I never really thought about "silly mistakes" in this way before. Thank you for sharing this. I think a lot of people (including myself) are too hard on ourselves for those types of mistakes.
by Isabel_Eslabon_2G
Wed Feb 03, 2021 7:51 pm
Forum: Ideal Gases
Topic: Units for K
Replies: 29
Views: 1300

Re: Units for K

I think because it's a ratio, it has no units. Not 100% sure if that's the correct explanation but that's what a teacher told me in high school.
by Isabel_Eslabon_2G
Sun Jan 31, 2021 11:15 pm
Forum: General Science Questions
Topic: Midterm 1 Reactions
Replies: 70
Views: 5123

Re: Midterm 1 Reactions

I thought it was similar to the midterms from Lavelle's Chem 14A, so I wasn't too surprised. Of course, still anxious to see my score. I hope I didn't make a dumb mistake that I wouldn't have made if I was going slower, but that's just how tests go.
by Isabel_Eslabon_2G
Thu Jan 28, 2021 1:32 pm
Forum: Equilibrium Constants & Calculating Concentrations
Topic: Acid & Base Dissociation Values
Replies: 1
Views: 82

Acid & Base Dissociation Values

When asked to compare the strengths of 2 acids or bases, are we going to be given pKa/pKb or Ka/Kb values? For example, here is the problem that made me think of this question: Textbook Question 6C.17 Which is the stronger base, the hypobromite ion, BrO−, or morphine, C17H19O3N? Justify your answer....
by Isabel_Eslabon_2G
Thu Jan 28, 2021 1:25 pm
Forum: Equilibrium Constants & Calculating Concentrations
Topic: Textbook 6C.15 [ENDORSED]
Replies: 2
Views: 302

Textbook 6C.15 [ENDORSED]

The question is: The pKa of HIO(aq), hypoiodous acid, is 10.64 and that of HIO3(aq), iodic acid, is 0.77. Account for the difference in strength. The answer talks about how there are more electronegative O atoms around the central atom in HIO3, which makes the central atom's oxidation number greater...
by Isabel_Eslabon_2G
Mon Jan 25, 2021 3:37 pm
Forum: Equilibrium Constants & Calculating Concentrations
Topic: Textbook Problem 5.35
Replies: 1
Views: 70

Textbook Problem 5.35

Hello.

Part B of this problem asks you to calculate K for the reaction.

In the solution to the problem, when finding K you take the pressures in the graph and divide by 100. Why do you do that?
by Isabel_Eslabon_2G
Mon Jan 25, 2021 3:12 pm
Forum: Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions
Topic: Textbook Question 5J.5, element "D"?
Replies: 2
Views: 150

Textbook Question 5J.5, element "D"?

Hello.

Part d of 5J.5 asks about the reaction:
2HD(g) ⇌ H2(g) + D2(g)

What element is "D" in this problem? Maybe I'm just missing it but I can't find it on the periodic table?
by Isabel_Eslabon_2G
Sat Jan 23, 2021 10:04 pm
Forum: Equilibrium Constants & Calculating Concentrations
Topic: Solids in Ice Tables
Replies: 11
Views: 1044

Re: Solids in Ice Tables

From what I remember, you can disregard the concentrations of solids & liquids in ICE tables.
by Isabel_Eslabon_2G
Sat Jan 23, 2021 10:01 pm
Forum: Equilibrium Constants & Calculating Concentrations
Topic: How to fill in 2nd row of ICE table?
Replies: 25
Views: 899

Re: How to fill in 2nd row of ICE table?

I think you need to determine what direction the reaction is going. In many cases, if you only start with reactants, then the reaction would create products. If you are given a K value and have concentrations for all reactant & product species, you can calculate Q and compare the two. If Q > K, ...
by Isabel_Eslabon_2G
Sat Jan 23, 2021 9:56 pm
Forum: Student Social/Study Group
Topic: Midterm Study Tips
Replies: 41
Views: 1869

Re: Midterm Study Tips

When doing UA, textbook, or online Sapling problems, I would do the hard problems and progressing to the easier ones. If you can't do the hardest problem, go to the second hardest, and onward. In my opinion, you waste less time on simple problems that you've already gotten the hang of.
by Isabel_Eslabon_2G
Sat Jan 23, 2021 9:54 pm
Forum: Non-Equilibrium Conditions & The Reaction Quotient
Topic: amphoteric vs amphiprotic
Replies: 10
Views: 343

Re: amphoteric vs amphiprotic

Amphoteric means that a species can react as a base or acid.

Amphiprotic means that a species can donate or accept a proton (an H+ ion).

From my understanding, all amphiprotic species are technically amphoteric, but not all amphoteric species count as amphiprotic.
by Isabel_Eslabon_2G
Sun Jan 17, 2021 1:59 pm
Forum: Equilibrium Constants & Calculating Concentrations
Topic: Amphiprotic
Replies: 8
Views: 375

Re: Amphiprotic

Hello.

Amphiprotic species can act as a Brønsted-Lowry acid or base, meaning it can act as a proton (H+) donor & acceptor. One example is water, as it can donate a proton (OH-) or accept a proton (H3O+).

Hope that helps.
by Isabel_Eslabon_2G
Sun Jan 17, 2021 1:55 pm
Forum: Equilibrium Constants & Calculating Concentrations
Topic: ICE Chart with Gas Pressures
Replies: 8
Views: 329

ICE Chart with Gas Pressures

Hello.

So when we are given Kp and pressures of compounds in bar, do we just use those pressures in the ICE chart instead of molarity amounts? Adding onto that, do we need to convert to atm?
by Isabel_Eslabon_2G
Sun Jan 17, 2021 1:40 pm
Forum: Equilibrium Constants & Calculating Concentrations
Topic: Textbook Problem 5I.25
Replies: 1
Views: 69

Re: Textbook Problem 5I.25

Hello. I think your K equation: (0.02 + x)(0.03 + x) / (0.02 - x)(0.04 - x) = 85.0 is correct. Your quadratic formula 54x^2 - 5.6x + 0.06794 = 0 differs from the correct one: 84x^2 - 5.15x + 0.0674 = 0 There must have been some algebra mistake between those steps which got you to the wrong answer, b...
by Isabel_Eslabon_2G
Sun Jan 10, 2021 10:49 am
Forum: Non-Equilibrium Conditions & The Reaction Quotient
Topic: Q>K
Replies: 10
Views: 373

Re: Q>K

I think one example of when Q > K is when the reaction is not quite at equilibrium yet so there are still products that are forming reactants. Because K & Q = [Products]/[Reactants], if Q > K, then there are more products that are still forming those reactants. This can also occur if more produc...
by Isabel_Eslabon_2G
Sun Jan 10, 2021 10:46 am
Forum: Administrative Questions and Class Announcements
Topic: 14B Midterm Content
Replies: 4
Views: 348

14B Midterm Content

Hi. For our final & midterms, are we only being tested on content that we learned in 14B or also 14A? I know that some foundation from 14A will be utilized when understanding certain concepts from 14B, but for example, will topics related to quantum mechanics be on those exams? I don't remember ...
by Isabel_Eslabon_2G
Sun Jan 10, 2021 10:41 am
Forum: Equilibrium Constants & Calculating Concentrations
Topic: Equilibrium constant between 10^-3 and 10^3
Replies: 6
Views: 701

Re: Equilibrium constant between 10^-3 and 10^3

I think Lavelle said that if 10^-3 < K < 10^3 (intermediate values of K), then neither reactants nor products are strongly favored in that reaction (from the lecture on 1/6).
by Isabel_Eslabon_2G
Sun Jan 10, 2021 10:39 am
Forum: Equilibrium Constants & Calculating Concentrations
Topic: K vs Q
Replies: 7
Views: 258

Re: K vs Q

Hello. I'm pretty sure both K & Q are found by dividing product concentrations (to the power of their coefficients) by the reactant concentrations (to the power of their coefficients). The difference is that K uses equilibrium concentrations. When you are given concentrations of reactants & ...
by Isabel_Eslabon_2G
Mon Jan 04, 2021 4:20 pm
Forum: Equilibrium Constants & Calculating Concentrations
Topic: Sapling Week 1 Problem #1
Replies: 5
Views: 354

Sapling Week 1 Problem #1

The question is: "Select all of the true statements regarding chemical equilibrium:" Two of the options are: 1. "The concentrations of the reactants and products are equal" 2. "The concentrations of the reactants and products remain constant" #2 is true and #1 is false....
by Isabel_Eslabon_2G
Wed Dec 16, 2020 6:41 pm
Forum: General Science Questions
Topic: final timing
Replies: 25
Views: 1575

Re: final timing

I usually finish exams (especially multiple choice ones) with a moderate amount of time to spare, but this exam went by pretty fast. But I kind of expected it because it was a final and braced myself for the possibility that I may not finish. Personally, the questions with finding empirical formula ...
by Isabel_Eslabon_2G
Wed Dec 16, 2020 6:34 pm
Forum: Properties & Structures of Inorganic & Organic Acids
Topic: Why isn't HF a strong acid?
Replies: 23
Views: 7482

Re: Why isn't HF a strong acid?

F is very electronegative, so it does not want to dissociate with the H atom. This is why it is not a strong acid.

Among HCl, HBr, and HI, HI is the strongest acid because it gives up protons the easiest. The bond for HI is the longest, so it is the weakest.
by Isabel_Eslabon_2G
Wed Dec 09, 2020 7:16 pm
Forum: Hybridization
Topic: What is s-character?
Replies: 1
Views: 243

What is s-character?

Textbook problem 2F.15 asks "Noting that the bond angle of an sp3 hybridized atom is 109.58 and that of an sp2 hybridized atom is 1208, do you expect the bond angle between two hybrid orbitals to increase or decrease as the s-character of the hybrids is increased?" The answer is "As t...
by Isabel_Eslabon_2G
Tue Dec 08, 2020 4:21 pm
Forum: Industrial Examples
Topic: What are these?
Replies: 2
Views: 682

Re: What are these?

I don't remember many examples, but Lavelle did mention , which removes metals from solutions (from lecture on 11/25).
by Isabel_Eslabon_2G
Tue Dec 08, 2020 3:58 pm
Forum: Identifying Acidic & Basic Salts
Topic: Sapling #7
Replies: 3
Views: 242

Re: Sapling #7

Memorizing if salts are acidic/basic/neutral seems pretty difficult considering there could be other salts on the exam that you didn't prepare for. From my understanding, you need to determine what acid & base reacted to produce that salt. Looking at the strengths of both reactants will determin...
by Isabel_Eslabon_2G
Tue Dec 08, 2020 3:52 pm
Forum: Significant Figures
Topic: Things to remember for final?
Replies: 20
Views: 1344

Re: Things to remember for final?

You only really need to know which acids/bases are strong and if you know the general rules for whether something is an acid or base, you can rule out if it's strong. There's too many weak acids/bases to memorize, but you can remember the strong ones easily.
by Isabel_Eslabon_2G
Tue Dec 08, 2020 3:49 pm
Forum: Calculating the pH of Salt Solutions
Topic: -OH vs OH-
Replies: 36
Views: 1436

Re: -OH vs OH-

It's the same thing. In general, is how you'd normally write it when writing a chemical equation. is used more when writing diagrams or mechanisms to emphasize that the negative charge is from the oxygen, not the hydrogen.
by Isabel_Eslabon_2G
Wed Dec 02, 2020 9:55 pm
Forum: Lewis Acids & Bases
Topic: Lewis Acids & Bases
Replies: 12
Views: 1177

Re: Lewis Acids & Bases

Lewis Acids are electron acceptors (I remember that because acids and acceptor both start with 'a'). These acids are electron deficient. I usually remember that if it has a positive charge, it can accept an electron (cations). Lewis Bases are electron donors. These bases may have negative charges (a...
by Isabel_Eslabon_2G
Wed Dec 02, 2020 9:42 pm
Forum: Lewis Acids & Bases
Topic: Ligands
Replies: 6
Views: 498

Re: Ligands

Ligands are ions/molecules that form coordinate covalent bonds by donating both electrons involved in the covalent bond. Because it donates electron pair(s), if you draw out the Lewis structure, it should have lone electron pairs. It is also generally a nonmetal in a coordination compound.
by Isabel_Eslabon_2G
Wed Dec 02, 2020 9:38 pm
Forum: Student Social/Study Group
Topic: Final Exam Study Tips
Replies: 48
Views: 2614

Re: Final Exam Study Tips

My plan is to do the textbook problems listed in the outline. Since this final is cumulative, you also have to find time to review material from the previous 2 midterms. I suggest doing some of the harder textbook problems to review past content because I think it was mentioned some difficult questi...
by Isabel_Eslabon_2G
Wed Dec 02, 2020 9:33 pm
Forum: Shape, Structure, Coordination Number, Ligands
Topic: Sapling Week 9 HW Question 2
Replies: 11
Views: 631

Re: Sapling Week 9 HW Question 2

Hello. When determining coordination number, the coordination sphere consists of the elements in brackets. At first I thought the coordination number was 2, but that's because I was looking at Ba, which was outside the brackets. Fe is the central atom and has 4 Br atoms bound to it, which means the ...
by Isabel_Eslabon_2G
Sun Nov 29, 2020 5:32 pm
Forum: Determining Molecular Shape (VSEPR)
Topic: Textbook Problem 2E5
Replies: 3
Views: 197

Re: Textbook Problem 2E5

a) The shape of the ion is bent/angular.
b) The bond angle between the two O atoms are slightly less than 120 degrees due to the presence of a lone electron pair.
by Isabel_Eslabon_2G
Sat Nov 28, 2020 7:57 pm
Forum: Hybridization
Topic: Multiple Bonds with Hybridization
Replies: 6
Views: 350

Re: Multiple Bonds with Hybridization

I'm not sure if this is the right way to explain this, but when determining hybridization of an atom you look at the number of atoms it's attached to and the number of lone pairs that it has. The number of bonds between the atoms does not affect it. I am assuming Molecule #1 has a central atom with ...
by Isabel_Eslabon_2G
Sat Nov 28, 2020 7:11 pm
Forum: Octet Exceptions
Topic: Textbook Question 2.61
Replies: 3
Views: 347

Re: Textbook Question 2.61

I am not sure if this is correct, but I tried looking at alternate structures where the lone electron is not on the C. The structure where the lone electron is on C is the favored structure because that structure has all atoms with a formal charge of 0. If the lone electron is on an oxygen, the form...
by Isabel_Eslabon_2G
Sat Nov 28, 2020 7:02 pm
Forum: Student Social/Study Group
Topic: Midterm/Final Success?
Replies: 17
Views: 838

Re: Midterm/Final Success?

In my experience, I do all of the textbook problems in the outline and the UA problems on my own. When I have questions about certain topics, I utilize both this forum and chemistry videos on YouTube (I used these in high school and they really helped me). It's helpful to compile a list of condensed...
by Isabel_Eslabon_2G
Tue Nov 17, 2020 4:03 pm
Forum: Electron Configurations for Multi-Electron Atoms
Topic: d vs s orbitals
Replies: 7
Views: 1054

Re: d vs s orbitals

Hello. From how I understand it: 1. Electrons are added to the 4s orbitals before the 3d orbitals because the 4s orbitals are lower in energy when both are unoccupied. The 4s and 3d orbitals are very close in energy. After 4s orbitals are occupied, electrons must enter 3d state (then 3d is lower in ...
by Isabel_Eslabon_2G
Tue Nov 17, 2020 3:54 pm
Forum: Dipole Moments
Topic: dipoles and polarity
Replies: 2
Views: 188

Re: dipoles and polarity

I am pretty sure the answer is yes. A polar molecule is a molecule whose covalently shared electrons are shared unevenly. If a molecule has a permanent dipole moment, that would mean there is a permanent difference in charge in different regions of the molecule. Lavelle points out in the lecture on ...
by Isabel_Eslabon_2G
Tue Nov 17, 2020 3:49 pm
Forum: Bond Lengths & Energies
Topic: Higher Melting Point
Replies: 28
Views: 2688

Re: Higher Melting Point

Comparing melting points involves looking at intermolecular attraction. To solve this you need to compare the London dispersion forces of CHI3 and CHF3. When comparing dispersion forces, CHI3's is stronger than CHF3's because the iodine in CHI3 has more electrons than the fluorine in CHF3. For dispe...
by Isabel_Eslabon_2G
Tue Nov 17, 2020 3:45 pm
Forum: Quantum Numbers and The H-Atom
Topic: Cr+ Ground State Electron Configuration
Replies: 2
Views: 268

Re: Cr+ Ground State Electron Configuration

I'm pretty sure that the 4s orbital has 1 electron because that is more stable that way. Lavelle explained it in the lecture on 10/26/2020.
by Isabel_Eslabon_2G
Tue Nov 17, 2020 3:41 pm
Forum: Electron Configurations for Multi-Electron Atoms
Topic: Textbook Problem 2A.3
Replies: 1
Views: 108

Re: Textbook Problem 2A.3

Hello.

I think that's actually problem 2A.4. 2A.3 asks for the configurations of

I think your answers for V4+ & Fe3+ are correct.
by Isabel_Eslabon_2G
Fri Nov 13, 2020 10:51 pm
Forum: Resonance Structures
Topic: Delocalized Electrons
Replies: 7
Views: 372

Re: Delocalized Electrons

From my understanding, delocalized electrons are electrons not associated with single atom or covalent bond. Resonance structures represent possible structures of a molecule because there are electrons not bound to a single atom/bond.
by Isabel_Eslabon_2G
Fri Nov 13, 2020 10:35 pm
Forum: Interionic and Intermolecular Forces (Ion-Ion, Ion-Dipole, Dipole-Dipole, Dipole-Induced Dipole, Dispersion/Induced Dipole-Induced Dipole/London Forces, Hydrogen Bonding)
Topic: Textbook Problem 3f.5
Replies: 2
Views: 191

Re: Textbook Problem 3f.5

B) Butanol is more likely due to hydrogen bonding (this isn't present in diethyl ether). C) CHI3 is more likely. When comparing London dispersion forces, CHI3's is stronger than CHF3's because the iodine in CHI3 has more electrons than the fluorine in CHF3. Just to be clear, in CHF3 there is no hydr...
by Isabel_Eslabon_2G
Thu Nov 12, 2020 9:13 am
Forum: Electron Configurations for Multi-Electron Atoms
Topic: Orbital levels
Replies: 1
Views: 93

Re: Orbital levels

Hello, From my understanding, the 4s orbital is lower in energy than the 3d orbital, but only slightly (in general, as energy levels increase; as they increase energies of orbitals become closer). After the 4s state is occupied, electrons must enter 3d state. Then 3d is lower in energy than 4s. When...
by Isabel_Eslabon_2G
Mon Nov 09, 2020 7:25 pm
Forum: Ionic & Covalent Bonds
Topic: # of Valence Electrons for Transition Metals [ENDORSED]
Replies: 1
Views: 406

# of Valence Electrons for Transition Metals [ENDORSED]

Hello.

This is a bit of a simple question but I am having some trouble understanding how to determine the number of valence electrons in transition metals?

I know that K has 1, C has 4, O has 6, etc. but what about ones like V and Ni?
by Isabel_Eslabon_2G
Mon Nov 09, 2020 7:21 pm
Forum: Ionic & Covalent Bonds
Topic: Textbook Question 2A.15 Part D
Replies: 1
Views: 127

Textbook Question 2A.15 Part D

Hello.

The question asks to write the most likely charge for the ions formed by Ga.

The answer is 3+. Why is this (my initial answer was 1+)?
My reasoning was because then there are full subshells now that there are no electrons in 4p?
by Isabel_Eslabon_2G
Thu Nov 05, 2020 5:05 pm
Forum: Student Social/Study Group
Topic: Studying Tips
Replies: 23
Views: 964

Re: Studying Tips

Hello! As many have already recommended, doing the textbook problems that Lavelle has in the Outlines on his website are super helpful. I would like to add that the last problems for each section are usually more important to understand because they are harder, so if you're short on time & feel ...
by Isabel_Eslabon_2G
Thu Nov 05, 2020 5:01 pm
Forum: Trends in The Periodic Table
Topic: Midterm 2 Study Group
Replies: 7
Views: 477

Re: Midterm 2 Study Group

I would like to be a part of this study group :). I think this would be very helpful. How would you like me & others to contact you?
by Isabel_Eslabon_2G
Thu Nov 05, 2020 9:21 am
Forum: Ionic & Covalent Bonds
Topic: Sapling Week 5/6 #16
Replies: 2
Views: 127

Sapling Week 5/6 #16

Hello, I am struggling with understanding this question: A cross-link is an ionic, covalent, or hydrogen bond that links one polymer chain to another and reduces the flexibility of the polymer chains. Several possible hydrogen bond cross links are shown between the two polymer chains in the image. I...
by Isabel_Eslabon_2G
Thu Nov 05, 2020 8:50 am
Forum: Ionic & Covalent Bonds
Topic: Lengths of Single & Double Bonds
Replies: 4
Views: 266

Lengths of Single & Double Bonds

I don't remember if Lavelle spoke on this already, so I will just ask about it here.
If we are asked about lengths of single & double bonds on exams, do we need to memorize common ones (like C=C, or C-H) or will they be given in the question? Or do we get a reference chart for it?
by Isabel_Eslabon_2G
Thu Nov 05, 2020 7:36 am
Forum: Student Social/Study Group
Topic: Post All Chemistry Jokes Here
Replies: 9651
Views: 3695816

Re: Post All Chemistry Jokes Here

Not sure if this is chem-related but oh well.

Before heading out to the store, my sister told me "Hey, we're out of salt" to which I replied "0mg".
by Isabel_Eslabon_2G
Wed Oct 28, 2020 1:34 pm
Forum: Trends in The Periodic Table
Topic: Electron Affinity
Replies: 10
Views: 541

Re: Electron Affinity

Hello. A higher electron affinity means an atom is more readily accepting of electrons. In terms of energy, whenever atoms gain electrons, they release energy. From my understanding, this occurs whenever electrons are gained, whether they have high or low electron affinities, but because atoms with ...
by Isabel_Eslabon_2G
Wed Oct 28, 2020 1:30 pm
Forum: Properties of Light
Topic: UA Workshop Question
Replies: 4
Views: 244

UA Workshop Question

Hello, I am struggling with this problem: It is generally accepted that UVC lamps with 40 mJ/cm² at a wavelength of 250 nm can be used to disinfect surfaces and kill pathogens. If you leave a UVC lamp on to disinfect a 5 m² area, how many high energy photons are produced? The answer key says 2.52*10...
by Isabel_Eslabon_2G
Wed Oct 28, 2020 1:21 pm
Forum: Empirical & Molecular Formulas
Topic: Textbook Problem M.19
Replies: 8
Views: 528

Re: Textbook Problem M.19

Hello. I like to write the chemical equation out like this: (?) + O2 -> CO2 + H2O + N2 I just write caffeine as (?) because we don't know its molecular formula You need to use the masses of CO2, H20, & N2 to find the moles of C, H, & N (using stoichiometry). Use the masses of C, H, & N (...
by Isabel_Eslabon_2G
Wed Oct 28, 2020 9:43 am
Forum: Balancing Chemical Reactions
Topic: Problem for UA Workshop 1
Replies: 2
Views: 356

Problem for UA Workshop 1

Hello. I've had a bit of trouble balancing this one chemical equation: NaHCO_3 + C_6H_8O_7\rightarrow Na_3C_6H_5O_7+H_2O+CO_2 Can anyone help me? Also does anyone have tips about how to balance equations like this? I don't want to spend too much time on these questions on the midterm (I either take ...
by Isabel_Eslabon_2G
Wed Oct 28, 2020 9:34 am
Forum: Molarity, Solutions, Dilutions
Topic: UA Session Question
Replies: 2
Views: 265

Re: UA Session Question

Hello.

For part B you need to use the molarity from part A & use this formula:



M1=Molarity from Part A
V1= You are solving for this.
M2=5.60*10^-7
V2=0.235L

I did the conversion, but this formula needs to be in liters, so once you find the value of V1, convert back to mL.
by Isabel_Eslabon_2G
Wed Oct 21, 2020 2:27 pm
Forum: Bohr Frequency Condition, H-Atom , Atomic Spectroscopy
Topic: Homework problem #8
Replies: 3
Views: 152

Re: Homework problem #8

The Lyman Series all contain the transition n=2 to n=1 and Balmer Series all contain the transition n=3 to n=2 From my understanding, these are the "common transitions" because they are the biggest energy gaps in the series (the energy levels converge as they increase). In all honesty, I d...
by Isabel_Eslabon_2G
Wed Oct 21, 2020 2:21 pm
Forum: Einstein Equation
Topic: 1B.9 (7th edition)
Replies: 8
Views: 841

Re: 1B.9 (7th edition)

ohhh what okay then my textbook is messed up that makes so much more sense!!! Mine looks like this "1B.9 A lamp rated at emits violet light of wavelength 420 nm. How many photons of violet light can the lamp generate in 2.0 s? How many moles of photons are emitted in that time interval?" ...
by Isabel_Eslabon_2G
Wed Oct 21, 2020 2:14 pm
Forum: Bohr Frequency Condition, H-Atom , Atomic Spectroscopy
Topic: Variables in Rydberg Equation
Replies: 5
Views: 220

Re: Variables in Rydberg Equation

Frequency is not the same thing as energy level.

When you are solving the problem, you solve for the frequency and use the frequency to find the energy level. This equation involves both frequency and energy level:

by Isabel_Eslabon_2G
Wed Oct 21, 2020 2:11 pm
Forum: Einstein Equation
Topic: 1B.9 (7th edition)
Replies: 8
Views: 841

Re: 1B.9 (7th edition)

Where does the 32W come from in this problem?? I'm confused? The 32W is given in the problem: 1B.9 A lamp rated at 32W(1W=1J⋅s^−1) emits violet light of wavelength 420 nm. How many photons of violet light can the lamp generate in 2.0 s? How many moles of photons are emitted in that time interval? o...
by Isabel_Eslabon_2G
Wed Oct 21, 2020 2:04 pm
Forum: Einstein Equation
Topic: 1B.9 (7th edition)
Replies: 8
Views: 841

Re: 1B.9 (7th edition)

Tikva Cohen 2I wrote:Where does the 32W come from in this problem?? I'm confused?


The 32W is given in the problem:

1B.9 A lamp rated at 32W(1W=1J⋅s^−1) emits violet light of wavelength 420 nm. How many photons of violet light can the lamp generate in 2.0 s? How many moles of photons are emitted in that time interval?
by Isabel_Eslabon_2G
Wed Oct 21, 2020 2:01 pm
Forum: Administrative Questions and Class Announcements
Topic: The Midterm Topics
Replies: 5
Views: 247

Re: The Midterm Topics

On Lavelle's CHEM14A website he posted an announcement saying: Midterm 1 covers material up to Wednesday of Week 3. This is up to Q19 in Sapling (quantum) homework. In Outline 2 below, all topics except the last 8 listed. MT 1 is to the end of 1D.2 in textbook. Quantum numbers, shape of orbitals, et...
by Isabel_Eslabon_2G
Wed Oct 21, 2020 1:57 pm
Forum: Properties of Light
Topic: Electromagnetic Sepectrum
Replies: 3
Views: 233

Re: Electromagnetic Sepectrum

From the practice/homework questions, I assume that we need to know wavelength boundaries for x-rays, infrared, microwaves, and others because those were asked in the homework. To memorize the general order, I use the mnemonic: Roman Men Invented Very Unusual X-Ray Guns Radio Waves, Microwaves, Infr...
by Isabel_Eslabon_2G
Wed Oct 14, 2020 10:04 pm
Forum: General Science Questions
Topic: Balancing equations
Replies: 19
Views: 2711

Re: Balancing equations

Hello. I would just like to say that sometimes when I am deep into balancing an equation and I get something that works, what happens is I went too far and have something like: 4C_{2}H_{6} + 14O_2 \rightarrow 8CO_2 + 12H_2O when it really should be: 2C_{2}H_{6} + 7O_2 \rightarrow 4CO_2 + 6H_2O Altho...
by Isabel_Eslabon_2G
Wed Oct 14, 2020 9:50 pm
Forum: Properties of Electrons
Topic: Atomic Spectra and Exciting Electrons
Replies: 4
Views: 153

Re: Atomic Spectra and Exciting Electrons

I believe he mentioned this in one of the Audio-Visual Focus-Topic Videos (the Atomic Spectra video)on his website. When he was drawing out the different energy levels, he mentioned that if the frequency didn't correspond to an energy difference (n=1 to n=2 for example), then it wouldn't be absorbed...

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