Search found 100 matches
- Mon Mar 08, 2021 2:45 pm
- Forum: Arrhenius Equation, Activation Energies, Catalysts
- Topic: Frequency Factor
- Replies: 3
- Views: 228
Re: Frequency Factor
Hello! The frequency factor, A, essentially signifies the fraction of molecules that have the correct orientation so that when they collide, they can cause a reaction to occur from this collision. However, for a reaction to occur, the two molecules must have the correct orientation when they collide...
- Mon Mar 08, 2021 2:33 pm
- Forum: Arrhenius Equation, Activation Energies, Catalysts
- Topic: Activation energy
- Replies: 6
- Views: 449
Re: Activation energy
Hello! When using the Arrhenius Equation, if we are using the rate constant R = 8.314 J/(K mol), then for this rate constant, the activation energy, Ea, would have units of J/mol . This would allow all the units to cancel, which is needed when you take the exponent of (-Ea/RT) in the Arrhenius Equat...
- Mon Mar 08, 2021 2:26 pm
- Forum: Arrhenius Equation, Activation Energies, Catalysts
- Topic: sapling wk 9/10 #17
- Replies: 1
- Views: 152
Re: sapling wk 9/10 #17
Hello! For this problem, you can actually just draw out the reaction diagram for an endothermic reaction. Notice that you can simply subtract activation energy minus the delta H in order to find the activation energy in the reverse direction. You can see this visually below: https://cdn.kastatic.org...
- Mon Mar 08, 2021 2:16 pm
- Forum: General Rate Laws
- Topic: Wk 9/10 Sapling #13
- Replies: 8
- Views: 468
Re: Wk 9/10 Sapling #13
Hello! You are correct that the slowest step is the rate-determining step, so it's rate law will determine the overall rate law. However, the slow step's rate law includes [HClO] is an intermediate reactant, and we don't include intermediates in the overall rate law. To solve this, we have to consid...
- Mon Mar 08, 2021 2:06 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Writing Balanced reactions from Galvanic Cells
- Replies: 2
- Views: 213
Re: Writing Balanced reactions from Galvanic Cells
Hello! When you're given a cell diagram and are asked to write the overall reaction, you'll want to write out the half-reactions so that the left side of the diagram is an oxidized half-reaction, and the right side of the diagram is a reduced half-reaction. For example, in part (b), you would write ...
- Mon Mar 01, 2021 3:55 pm
- Forum: Interesting Applications: Rechargeable Batteries (Cell Phones, Notebooks, Cars), Fuel Cells (Space Shuttle), Photovoltaic Cells (Solar Panels), Electrolysis, Rust
- Topic: Metals in solution
- Replies: 2
- Views: 199
Re: Metals in solution
Hello! I believe that this point is asking you to determine whether the metal will be reduced or oxidized in a given galvanic cell. You would be given a metal half-cell as well as some other half-cell, and you would have to compare the half-cell's standard reduction potentials. If the metal in quest...
- Mon Mar 01, 2021 3:47 pm
- Forum: Balancing Redox Reactions
- Topic: Balancing reactions with 1 compound as the reducing and oxidizing agent
- Replies: 2
- Views: 176
Re: Balancing reactions with 1 compound as the reducing and oxidizing agent
Hello! Even if a reactant is both the reducing and oxidizing agent, I still find it helpful to break the redox reaction into half-reactions. You would therefore have that reactant in both of the half-reactions, and you would follow all the steps of balancing O by the addition of H20 and balancing H ...
- Mon Mar 01, 2021 3:36 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Single line vs. comma
- Replies: 2
- Views: 159
Re: Single line vs. comma
Hello! A comma is used to separate species in a cell diagram that are of the same phase (both species are aqueous, for example). On the other hand, a line is used to separate species in a cell diagram that are of a different phase (one species is aqueous, the other is gaseous, for example). Hope thi...
- Mon Mar 01, 2021 3:33 pm
- Forum: Appications of the Nernst Equation (e.g., Concentration Cells, Non-Standard Cell Potentials, Calculating Equilibrium Constants and pH)
- Topic: Textbook 6N.13a
- Replies: 3
- Views: 225
Re: Textbook 6N.13a
Hello! I also got the answer Q=2.7x10^6, using the same process of finding the cell potential and using the Nernst equation to find the Q value. I believe that the solutions manual provided a very simplified answer, but I believe that the answer you provided is correct.
Hope this helps!
Hope this helps!
- Mon Mar 01, 2021 3:26 pm
- Forum: Appications of the Nernst Equation (e.g., Concentration Cells, Non-Standard Cell Potentials, Calculating Equilibrium Constants and pH)
- Topic: Effect of concentration
- Replies: 4
- Views: 262
Re: Effect of concentration
Hello! The Nernst equation that relates Ecell to E°cell would be the quantitative way of predicting changes in concentration on the cell potential. Since E° is the cell potential under standard conditions (where the concentrations are all 1 mol/L), then for any nonstandard concentrations, you would ...
- Mon Feb 22, 2021 9:24 pm
- Forum: Appications of the Nernst Equation (e.g., Concentration Cells, Non-Standard Cell Potentials, Calculating Equilibrium Constants and pH)
- Topic: Question about Monday lecture (2/22/21)
- Replies: 5
- Views: 346
Re: Question about Monday lecture (2/22/21)
Hello! As we learned in the beginning of Chem 14B, Le Chatelier's Principle can be used to determine that when we increase the concentration of reactants or products, then the K value will shift by this principle. Therefore, once we apply Le Chatelier's Principle to figure out in which direction the...
- Mon Feb 22, 2021 9:08 pm
- Forum: Balancing Redox Reactions
- Topic: e- in Redox Reactions
- Replies: 11
- Views: 584
Re: e- in Redox Reactions
Hello! Yes, you can assume this. Since a reduction half-reaction involves the gaining of electrons, then the electrons can be treated as a reactant that will be integrated into the other reactant. Similarly, since an oxidation half-reaction involves the losing of electrons, then the electrons will b...
- Mon Feb 22, 2021 7:30 pm
- Forum: Interesting Applications: Rechargeable Batteries (Cell Phones, Notebooks, Cars), Fuel Cells (Space Shuttle), Photovoltaic Cells (Solar Panels), Electrolysis, Rust
- Topic: Recharging batteries
- Replies: 3
- Views: 311
Re: Recharging batteries
Hello! When we 'recharge' batteries, we are essentially using electricity on the battery to reverse the redox reaction. This is because the reverse direction of a redox reaction in a battery would have be spontaneous and would have a positive ΔG value. This means that energy is the form of electrici...
- Mon Feb 22, 2021 7:25 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Le Chatlier's with Cell Potentials
- Replies: 3
- Views: 214
Re: Le Chatlier's with Cell Potentials
Hello! This is true! For redox reactions, we can qualitatively predict a shift in equilibrium when we apply Le Chatelier's principle. This can then be applied to determine whether the cell potential of the redox reaction has increased and decreased.
Hope this helps!
Hope this helps!
- Mon Feb 22, 2021 6:53 pm
- Forum: Balancing Redox Reactions
- Topic: 6K.1 - Oxidation number for carbon
- Replies: 2
- Views: 190
Re: 6K.1 - Oxidation number for carbon
Hello! According to oxidation number rules, O will always have a -2 oxidation number, and H will have a +1 oxidation number. Since C2H5OH is a neutral compound, then the sum of the oxidation numbers should equal 0. We can multiply O and H's oxidation numbers by the number of those atoms in the compo...
- Wed Feb 17, 2021 7:06 pm
- Forum: Balancing Redox Reactions
- Topic: clarification
- Replies: 4
- Views: 285
Re: clarification
Hello! The Boltzmann equation is one equation to calculate entropy, using concepts like degeneracy (W) to determine this entropy. Therefore, you can think of the Boltzmann equation as a method to calculate entropy. On the other hand, the Second Law of Thermo states that for a spontaneous process to ...
- Wed Feb 17, 2021 6:54 pm
- Forum: Calculating Work of Expansion
- Topic: Textbook Question 4A11
- Replies: 3
- Views: 261
Re: Textbook Question 4A11
Hello! The question is asking for heat capacity (not specific heat capacity), so therefore, heat capacity does not include the amount of substance (in grams or moles) of the substance in its expression. It's simply asking you to find the amount of heat needed to raise the temperature of the substanc...
- Wed Feb 17, 2021 6:48 pm
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: Specific Heat
- Replies: 9
- Views: 692
Re: Specific Heat
Hello! The main difference between specific heat capacity and heat capacity is that: heat capacity is the energy (in J) to raise the temperature of a substance by 1 °C (depends on the amount of substance). On the other hand, specific heat capacity is the energy (in J) to raise 1 gram of a substance ...
- Wed Feb 17, 2021 6:40 pm
- Forum: Calculating Work of Expansion
- Topic: Textbook 4D.7
- Replies: 2
- Views: 282
Re: Textbook 4D.7
Hello! When the when we see problems like 4D.7 where the ideal gas law is being implemented, then we can assume that the system will be at 25 degrees Celsius. Of course, when we convert this temperature to Kelvin, the equivalent temperature will be 298.15 K. When the temperature is not explicitly st...
- Wed Feb 17, 2021 6:28 pm
- Forum: Entropy Changes Due to Changes in Volume and Temperature
- Topic: Residual vs Positional Entropy
- Replies: 4
- Views: 322
Re: Residual vs Positional Entropy
Hello! For this class, I believe that we can interpret that they are the same type of entropy. Residual entropy arises when there's the possibility of different orientation of the particles when we approach 0 Kelvin, so the position (orientation) of the particles results in residual entropy that we ...
- Tue Feb 09, 2021 5:35 pm
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: molar heat capacity
- Replies: 9
- Views: 509
Re: molar heat capacity
Hello! A system's change in enthalpy is a measure of the heat released or absorbed when a chemical reaction proceeds. You can think of this as the heat that enters or leaves the system for a given reaction. And the molar heat capacity for a substance is the amount of energy that's needed to raise th...
- Tue Feb 09, 2021 5:27 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Heat of vaporization
- Replies: 2
- Views: 175
Re: Heat of vaporization
Hello! Since the heat of vaporization is usually in the units of kJ/mol, then if the mass is given, you should use the molar mass of the given substance to convert from the mass of the substance to moles. This will allow you to convert between mass and moles, so then you can calculate the heat of va...
- Tue Feb 09, 2021 10:58 am
- Forum: Thermodynamic Definitions (isochoric/isometric, isothermal, isobaric)
- Topic: isothermal reversible expansion
- Replies: 2
- Views: 158
Re: isothermal reversible expansion
Hello! When you're referring to an isothermal reversible expansion that's twice its volume, this is referring to the example when a system reversibly expands from its initial volume to a final volume that is 2x its initial volume. The "twice its volume" simply specifies the degree to which...
- Tue Feb 09, 2021 10:51 am
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: Bomb Calorimeter
- Replies: 17
- Views: 925
Re: Bomb Calorimeter
Hello! If you see bomb calorimeters in a question, it's probably safe to assume that they are referring to an isolated system. This is because bomb calorimeters are sealed, so there's no exchange of mass with the system's surroundings. And since it is insulated, there would also be no energy exchang...
- Tue Feb 09, 2021 9:14 am
- Forum: Phase Changes & Related Calculations
- Topic: 4D.1
- Replies: 2
- Views: 103
Re: 4D.1
Hello! In the problem, it says that the piston is compressing the gas. This means that work is being done on the system in order to compress this system inside the vessel. Therefore, since the system is being compressed, the work will be positive , because energy is entering the system via work. Hop...
- Tue Feb 02, 2021 8:10 pm
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: internal energy
- Replies: 4
- Views: 123
Re: internal energy
Hello! Yes, you are thinking about this correctly. If the given system is cooling, then this means that heat is leaving the system, which in turn means that q will be a negative value. And when the system is performing work on its surroundings (by expanding), then this means that the system is losin...
- Tue Feb 02, 2021 7:59 pm
- Forum: Calculating Work of Expansion
- Topic: negative q?
- Replies: 3
- Views: 127
Re: negative q?
When we see that the surrounding "cooling system" absorbs heat, then we know that the reaction must be transferring energy from the reaction to that cooling system. Because of the reaction's loss of energy to the surrounding cooling system, then we know that the reaction must have a negati...
- Tue Feb 02, 2021 3:23 pm
- Forum: Calculating Work of Expansion
- Topic: Work on surrounding
- Replies: 12
- Views: 484
Re: Work on surrounding
Hello! Because according to the chemical reaction, A is in solid state, we would not consider its contribution to the pressure since it's a solid. Therefore, when we examine the moles of gas, we see that as the reaction proceeds, there's a net increase in moles of gas, so therefore it would exert wo...
- Tue Feb 02, 2021 1:27 pm
- Forum: Concepts & Calculations Using First Law of Thermodynamics
- Topic: Postive vs. negative work
- Replies: 18
- Views: 1077
Re: Postive vs. negative work
Hello! When work is being done on the system, energy is being transferred into the given system, which means that the system is obtaining energy from the external work being applied. This allows the work to be positive when work is applied on a system, since it is obtaining energy. On the other hand...
- Tue Feb 02, 2021 1:24 pm
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: Closed System Volume Changes
- Replies: 4
- Views: 457
Re: Closed System Volume Changes
Hello! Yes, in a closed system, you can have energy transfer through heat, but closed systems can still have volume changes. So in the scenario where you have a moveable piston, this will be a closed system (because matter cannot be exchanged with the system's surroundings), but the volume of the sy...
- Thu Jan 28, 2021 2:01 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Ka and Kb
- Replies: 2
- Views: 240
Re: Ka and Kb
Hello! You would actually use the equation (Ka)(Kb)=Kw to calculate the different equilibrium constant for the conjugate acid/base. For example, if you know a value of Ka for a certain equation, you can rearrange this equation such as Kb=Kw/Ka, in order to calculate the corresponding Kb value. Hope ...
- Thu Jan 28, 2021 1:22 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Homework number 6
- Replies: 2
- Views: 136
Re: Homework number 6
Hello! The goal of this question is to identify that the given reaction is a combustion reaction, specifically for the molecule CH4. We can identify this reaction because combustion reactions involve the reaction of a molecule (such as a hydrocarbon) with O2 to yield CO2 and H20. Because we see that...
- Thu Jan 28, 2021 1:16 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Percentage in equilibrium concentration
- Replies: 3
- Views: 395
Re: Percentage in equilibrium concentration
Hello! When you see a statement like that, for example, "41.2% of A has been ionized to reach equilibrium," then because we're usually given the initial concentration of A, we can use that percentage to calculate the equilibrium concentration of A. This is because the remaining amount of A...
- Thu Jan 28, 2021 12:48 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Textbook 6A21
- Replies: 2
- Views: 80
Re: Textbook 6A21
Hello! Yes, we will assume that water is neutral, and because water is neutral, this will let us conclude that [OH-] = [H30+]. This of course will allow us to use the given equilibrium constant (Kw) to calculate the equivalent equilibrium concentrations, under the assumption that we're considering n...
- Thu Jan 28, 2021 12:44 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Heating a reaction at equilibrium
- Replies: 3
- Views: 95
Re: Heating a reaction at equilibrium
Hello! You can look and compare the different K values that different temperatures for the reaction. Since the K value decreases when we increase the temperature from 600 to 700K, then then this means that as we increase temperature, the reaction will be shifting to favor the reactions. Therefore, s...
- Tue Jan 19, 2021 4:09 pm
- Forum: Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions
- Topic: textbook 6.19
- Replies: 2
- Views: 84
Re: textbook 6.19
Hello! We know that lactic acid will increase the concentration of [H30+], so therefore, we can look at how to effectively minimize the change when we increase the concentration of H30+. For example, in part (a), when we increase [H30+], we want to minimize this change by using up this added H30+. I...
- Tue Jan 19, 2021 4:01 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Textbook Question 6A21
- Replies: 3
- Views: 194
Re: Textbook Question 6A21
Hello! The question is asking what the molar concentrations of H30+ and OH- are in neutral solution. We learned earlier in the lectures that neutral solutions will have [H30+] = [OH-], since they will neutralize each other, resulting in a neutral solution. Therefore, the molar concentrations must eq...
- Tue Jan 19, 2021 12:55 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: A + B
- Replies: 5
- Views: 334
Re: A + B
Hello! For general chemical reactions like A + B ⇌ C, if the state of the reactants and products is not provided in the question, then it's okay to assume that the concentrations of the reactants and products will all be included. However, if the state is given, then you have to take into considerat...
- Tue Jan 19, 2021 12:51 pm
- Forum: Ideal Gases
- Topic: Gas Constant Value
- Replies: 43
- Views: 1843
Re: Gas Constant Value
Hello! On the "Constant and Equations" sheet (found on Professor Lavelle's website), the sheet has all the different gas constants for different units that may arise. I believe we are permitted to use the Constants and Equations reference sheet on the midterms, so you can simply refer to t...
- Tue Jan 19, 2021 12:46 pm
- Forum: Ideal Gases
- Topic: Omitting solid/liquid
- Replies: 19
- Views: 808
Re: Omitting solid/liquid
Hello! In a chemical reaction, solids and liquids will have a constant concentration as we proceed through the chemical reaction. In other words, the reaction does not change the concentration of solids or liquids. As a result, even if we included their concentrations in the equilibrium expression, ...
- Mon Jan 11, 2021 5:46 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: H30+ and OH-
- Replies: 4
- Views: 484
Re: H30+ and OH-
I believe that Professor Lavelle was referring to a neutral solution. Assuming that we’re discussing about a neutral solution, then we know that H3O+ and OH- neutralize each other. Then therefore, if [H3O+] = [OH-] , then this results in a neutral solution. However, the Kw constant will stay the sam...
- Mon Jan 11, 2021 5:18 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Approximations
- Replies: 4
- Views: 216
Re: Approximations
Yes we can approximate values when K is very small. A good rule of thumb is that if Kc < 10^-4, then the approximations will be valid. Therefore, if K is within that guideline, the approximation covered in class will work.
Hope this helps!
Hope this helps!
- Mon Jan 11, 2021 4:49 pm
- Forum: Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions
- Topic: Textbook Problem 5.J.5 part B
- Replies: 5
- Views: 335
Re: Textbook Problem 5.J.5 part B
By Le Chatelier's principle, we want to minimize the effect of the pressure increase (resulting from a volume decrease). When we are looking at the given reaction, we see that 1 mole of gas on the reactant side, and 2 moles of gas (in total) on the product side. Therefore, to reduce pressure, the re...
- Mon Jan 11, 2021 2:51 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Outline 1 Learning Objective [ENDORSED]
- Replies: 5
- Views: 330
Re: Outline 1 Learning Objective [ENDORSED]
You are correct. If K has a large value, then this means that the equilibrium will sit to the right. This means that there will be a high concentration of products at equilibrium, which means the reaction is readily soluble, simply because the K has a large value.
Hope this helps!
Hope this helps!
- Mon Jan 11, 2021 2:44 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Kw
- Replies: 9
- Views: 469
Re: Kw
I believe it is found through experimentation But can someone explain why [H3O+] and [OH-] concentrations need to be equal? When [H3O+] and [OH-] are equal, then these two substances will neutralize each other. If we are talking about a neutral solution, then we must make [H3O+] = [OH-] in order fo...
- Mon Jan 04, 2021 6:05 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Equilibrium vs Initial Concentration
- Replies: 5
- Views: 716
Re: Equilibrium vs Initial Concentration
Hello! The initial concentrations refer to the concentrations of the reactants and products when we first proceed with the reaction. These initial concentrations are measured when the reaction has just started, and this reaction is not in equilibrium. On the other hand, equilibrium concentrations re...
- Mon Jan 04, 2021 5:18 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Lecture Clarification
- Replies: 2
- Views: 185
Re: Lecture Clarification
Hello! In lecture, Professor Lavelle mentioned that in chemical reactions, solvents change very little in concentration. This is because there is usually a very large amount of solvent, so even if some amount of the solvent is consumed in the chemical reaction, overall the change in concentration of...
- Mon Jan 04, 2021 4:08 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Energy Difference
- Replies: 2
- Views: 69
Re: Energy Difference
Hello! In lecture, Professor Lavelle mentioned that a reaction will favor the reactants or products according to the stability of the structures of the reactants and products. Because the highest stabilities have the lowest energies, then the equilibrium is shifted toward the most stable, lowest ene...
- Mon Jan 04, 2021 1:57 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Solids Not Having Concentration
- Replies: 7
- Views: 473
Re: Solids Not Having Concentration
Hello! When Professor Lavelle mentioned that solids aren't included in the equilibrium expression, he meant that solids do not change in concentration in a chemical reaction (this is the same for pure liquids as well). This is because solids are virtually incompressible, so as a chemical reaction pr...
- Mon Jan 04, 2021 12:29 pm
- Forum: Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions
- Topic: Chem Equilibrium Module
- Replies: 3
- Views: 166
Re: Chem Equilibrium Module
Hello! When we see that there's a negative delta H value, this means that heat is released and therefore the reaction is exothermic. On the other hand, when the delta H value is positive, then heat is absorbed and the reaction is therefore endothermic. Therefore, now we can look at the two reactions...
- Mon Dec 07, 2020 5:13 pm
- Forum: Bronsted Acids & Bases
- Topic: Sapling #6 week 10
- Replies: 4
- Views: 389
Re: Sapling #6 week 10
Hello! We know that according to the Bronsted definition of an acid, a substance is an acid if it is a H+ donor. Now let's look at HCN. We see that it has a H atom attached to the N atom. This H atom, in the presence of a base, can be removed from the HCN molecule as a H+. Therefore, we can say that...
- Mon Dec 07, 2020 4:25 pm
- Forum: Identifying Acidic & Basic Salts
- Topic: Ions as acids
- Replies: 2
- Views: 186
Re: Ions as acids
Hello! In the lecture, Cl- is excluded because this species is not strong enough to affect the pH of the solution. This is because while there is attraction between the Cl- and the surrounding H2O molecules, this attraction is not strong enough to actually protonate the Cl- to yield HCl. Therefore, ...
- Mon Dec 07, 2020 3:16 pm
- Forum: Amphoteric Compounds
- Topic: Amphoteric Compounds
- Replies: 4
- Views: 569
Re: Amphoteric Compounds
Hello! I believe that both of those substances are amphoteric, which depends on whether the substances are in the presence of an acid or base. In the case of HSO4-, the substance could gain a H+ (in the presence of a separate acid), which would yield H2SO4. Or HSO4- could lose a H+ (in the presence ...
- Mon Dec 07, 2020 3:08 pm
- Forum: Acidity & Basicity Constants and The Conjugate Seesaw
- Topic: Effect of pKa on Proton Being Accepted/Donated
- Replies: 2
- Views: 117
Re: Effect of pKa on Proton Being Accepted/Donated
Hello! The pH is a measurement of the concentration of [H+] of the solution that the given acid is placed into. On the other hand, the pKa value is associated with the acid that we're considering. Therefore, the question posed in class has to do with the relative pH values of the solution and the gi...
- Mon Dec 07, 2020 2:36 pm
- Forum: Calculating pH or pOH for Strong & Weak Acids & Bases
- Topic: pH 10^-14
- Replies: 3
- Views: 274
Re: pH 10^-14
Hello! pH 7 is the value that we get when the concentration of the [OH-] and [H+] are equal. Of course, when the concentrations are equal, this means that the species completely neutralize each other and you yield a neutral solution. Therefore, the pH and pOH will always add up to 14, since if you d...
- Mon Nov 30, 2020 5:58 pm
- Forum: Shape, Structure, Coordination Number, Ligands
- Topic: Coordination Number and Geometry
- Replies: 3
- Views: 165
Re: Coordination Number and Geometry
Hello! The Coordination Number is the number of bonds that the central metal atom is involved with the ligands of the coordination sphere. We find the coordination number by simply counting the number of ligands within the coordination compound, and taking into consideration whether any of the ligan...
- Mon Nov 30, 2020 4:53 pm
- Forum: Determining Molecular Shape (VSEPR)
- Topic: Bond Angles
- Replies: 13
- Views: 1572
Re: Bond Angles
Hello! A good way of remembering if a bond angle is less than 109.5 or 120, for instance, is when lone pairs are present . This is because the repulsion between lone pairs and bonding pair electrons are stronger than the repulsion between two bonding pairs of electrons. This greater repulsion, cause...
- Mon Nov 30, 2020 4:47 pm
- Forum: Naming
- Topic: Coordination Compound Naming
- Replies: 3
- Views: 234
Re: Coordination Compound Naming
Hello! Yes, you did the problem correctly! For every ligand that is in the quantity of two or more (within the coordination sphere of a given coordination compound), we will always put the Greek prefix (e.g. di, tri, tetra, etc) before the ligand when naming the coordination compound. So therefore, ...
- Mon Nov 30, 2020 4:42 pm
- Forum: Shape, Structure, Coordination Number, Ligands
- Topic: Coordination Number
- Replies: 3
- Views: 182
Re: Coordination Number
Hello! To determine the coordination number, we can simply count the number of ligands within the brackets (which identifies the species within the coordination sphere). The number of bonding ligands to the central metal atom signifies the coordination number. Make sure to consider any ligands that ...
- Mon Nov 30, 2020 4:36 pm
- Forum: Hybridization
- Topic: Question 2F.15
- Replies: 6
- Views: 376
Re: Question 2F.15
Hello! S-character simply refers to the degree/amount that the s orbital contributes to the hybrid orbital. Remember that hybrid orbitals, like sp2 or sp3 mentioned in the problem, are a combination of s and p orbitals. Therefore, when you increase s character, you increase the extent to which the s...
- Wed Nov 25, 2020 8:47 pm
- Forum: Determining Molecular Shape (VSEPR)
- Topic: Bent Shape NonPolar
- Replies: 2
- Views: 193
Re: Bent Shape NonPolar
Hello! A bent molecular structure signifies that the associated atoms are not positioned directly opposite of each other (like that in a linear molecular shape). As a result, the bonds' dipole moments don't cancel, which results in a net polar molecule. In other words, even if the atoms are the same...
- Wed Nov 25, 2020 6:48 pm
- Forum: Sigma & Pi Bonds
- Topic: delocalized pi bonds and resonance clarification
- Replies: 3
- Views: 236
Re: delocalized pi bonds and resonance clarification
Hello! I believe that you are thinking about it correctly. Since resonance structures are equally-likely structures of a certain molecule, a double bond will be involved. This is because a molecule involving purely single bonds wouldn't have any place for differing resonance structures. And then of ...
- Wed Nov 25, 2020 6:09 pm
- Forum: Hybridization
- Topic: Hybridization with double bonds
- Replies: 4
- Views: 216
Re: Hybridization with double bonds
Hello! Double bonds will constitute a single region of electron density, even though it's a double bond. So then, when we see that a molecule has 3 regions of electron density (1 double bond, 2 single bonds), this always points to sp2 hybridization. This is because sp2 hybrid orbitals result in thre...
- Wed Nov 25, 2020 6:04 pm
- Forum: Determining Molecular Shape (VSEPR)
- Topic: t shape
- Replies: 4
- Views: 239
Re: t shape
Hello! We take atoms off of the equatorial positions (not axial positions) because this minimizes repulsions. Repulsions will be minimized when an equatorial position atom is removed, since it is not as close to other atoms compared to the axial position atoms. So therefore, by the VSEPR Model, we f...
- Wed Nov 25, 2020 5:57 pm
- Forum: Sigma & Pi Bonds
- Topic: Delocalized Pi Bonds
- Replies: 4
- Views: 626
Re: Delocalized Pi Bonds
Hello! From my understanding, delocalized pi bonds arise from resonance, where a double bond can be placed in different locations by differing resonance structures. Since in reality the structure of the given molecule will be a resonance hybrid , this double bond is delocalized throughout the entire...
- Mon Nov 16, 2020 2:12 pm
- Forum: Resonance Structures
- Topic: Bond Lengths in Po4 3-
- Replies: 2
- Views: 1149
Re: Bond Lengths in Po4 3-
Hello! When drawing the Lewis structure for the phosphate ion, we notice that we can place the double bond between any of the P-O bonds. Therefore, we can indicate that phosphate ion experiences resonance. And resonance implies that we have a resonance hybrid, or an average/mix of the different reso...
- Mon Nov 16, 2020 2:03 pm
- Forum: Lewis Structures
- Topic: OF2
- Replies: 2
- Views: 179
Re: OF2
When we draw out the Lewis structure for OF2, we will notice that OF2 has a lone pair of electrons. Because OF2 has a lone pair, this is a good indicator that it is a Lewis Base (remember that Lewis bases= electron donors). So therefore, OF2 has electrons (its lone pair electrons) to donate, making ...
- Mon Nov 16, 2020 1:58 pm
- Forum: Dipole Moments
- Topic: london dispersion forces
- Replies: 5
- Views: 320
Re: london dispersion forces
Hello! We know that all intermolecular attractions contain London forces. However, only nonpolar molecules will solely experience only London forces. This is because non-polar bonds would not experience dipole-dipole attraction or hydrogen bonding. So, to check if a molecule only has London forces, ...
- Mon Nov 16, 2020 1:51 pm
- Forum: Lewis Structures
- Topic: Identifying lewis acids and bases
- Replies: 5
- Views: 588
Re: Identifying lewis acids and bases
Hello! As said above, Lewis acids are electron accepters, while Lewis bases are electron donors. One thing I'll add is that we see that the Br becomes an anion once it's a product. This will help us indicate that it gained electrons, so the Br in the CH3Br will accept electrons in the process of thi...
- Mon Nov 16, 2020 1:44 pm
- Forum: Dipole Moments
- Topic: Dipole moment vs dipole bond
- Replies: 5
- Views: 502
Re: Dipole moment vs dipole bond
Hello! A dipole moment is a measure of the polarity of a certain bond. Therefore, if we have a polar bond, then it will have a non-zero dipole moment. Of course, a polar bond arises from the unequal sharing of electrons between atoms (differences in electronegativity), so a dipole moment is also a m...
- Mon Nov 09, 2020 7:57 pm
- Forum: Electron Configurations for Multi-Electron Atoms
- Topic: expanding the octet
- Replies: 3
- Views: 157
Re: expanding the octet
Hello! Elements in period 3 and beyond will be able to have an expanded octet. This will occur because when we're in n=3, this means that the s, p, and d sub shell are open in the valence shell to receive electrons. So therefore along with the 8 electrons that the s and p sub shells can hold, the d ...
- Mon Nov 09, 2020 5:24 pm
- Forum: Electronegativity
- Topic: Finding electronegativity values
- Replies: 6
- Views: 247
Re: Finding electronegativity values
Hello! We don't have to memorize any specific electronegativity values for any elements. However, we are expected to know the trends of electronegativity (as well as ionization energy trends) in the periodic table. Specifically, you should be familiar the trends that electronegativity generally incr...
- Mon Nov 09, 2020 5:20 pm
- Forum: Lewis Structures
- Topic: Resonance structure
- Replies: 3
- Views: 99
Re: Resonance structure
Hello! Resonance structures simply denote the electronic structure of a molecule which has equally likely structures to occur. When we refer to a resonance hybrid, we are talking about the average or combination of these resonance structures, where the structure is a "hybrid" of the given ...
- Mon Nov 09, 2020 1:09 pm
- Forum: Ionic & Covalent Bonds
- Topic: Temporary vs Permanent Dipole Moments
- Replies: 2
- Views: 676
Re: Temporary vs Permanent Dipole Moments
Hello! So a permanent dipole comes in the the form of a polar covalent bond, where the two involved atoms unequally share their electrons (different electronegativities. On the other hand, a temporary dipole arises from the fluctuation of electron density in a covalent bond. If at one point the elec...
- Mon Nov 09, 2020 12:17 pm
- Forum: Ionic & Covalent Bonds
- Topic: negative energies for attractive interactions
- Replies: 7
- Views: 332
Re: negative energies for attractive interactions
Hello! One way to think about it is that a lower energy system translates to a more stable system . So therefore, in forming a bond, when energy is released, this lowers the overall energy of the system, which results in a more stable system. This is why when bonds form, they will release energy. Ho...
- Mon Nov 02, 2020 9:19 pm
- Forum: Quantum Numbers and The H-Atom
- Topic: Energy Between Subshells
- Replies: 2
- Views: 172
Re: Energy Between Subshells
Hello! As the "l" quantum number increases (aka as you progress from s → p → d → f ...), the energy of these subshells will increase. In other words, as you fill the sub shells within a given shell, the energy will increase from s → p → d → f and so forth. You can observe this trend throug...
- Mon Nov 02, 2020 6:25 pm
- Forum: Electron Configurations for Multi-Electron Atoms
- Topic: Electron Configurations Sapling Homework
- Replies: 3
- Views: 144
Re: Electron Configurations Sapling Homework
Yes, both versions of the electron configurations would be correct. Specifying which p suborbital the electron is in (3px^1 3py^1 3pz^1) will simply be a more specific version of the same electron configuration. So both of the electron configurations would be valid; it's just that specifying the p s...
- Mon Nov 02, 2020 12:55 pm
- Forum: Octet Exceptions
- Topic: Sulfur Octet Exception
- Replies: 2
- Views: 184
Re: Sulfur Octet Exception
Yes, your reasoning is correct! For elements in Period 3, the valence shell has the 3s orbital (which can hold up to 2 electrons), the 3p orbitals (which can hold up to 6 electrons) and then the 3d orbitals (which can hold up to 10 electrons). We can add all these electrons together to get a total o...
- Mon Nov 02, 2020 12:34 pm
- Forum: Lewis Structures
- Topic: Differences in Bond Length
- Replies: 6
- Views: 573
Re: Differences in Bond Length
Hello! Conceptually, you can also think of the difference in bond lengths as a result of the strength of the single/double bond. Since double bonds involve more electrons, they are stronger, and they will pull the atoms closer together, resulting in a shorter bond length . On the other hand, a singl...
- Mon Nov 02, 2020 12:24 pm
- Forum: Wave Functions and s-, p-, d-, f- Orbitals
- Topic: S and P electrons
- Replies: 14
- Views: 1597
Re: S and P electrons
Hello! I'll add that because the p orbitals are further away from the nucleus, this increases the electrostatic potential energy between the positively-charged nucleus and the negatively-charged electron. Remember that the PE increases as the distance between the electron and nucleus increases, so b...
- Tue Oct 27, 2020 10:58 am
- Forum: Properties of Electrons
- Topic: Wave Properties and Electrons Post-Assessment #18
- Replies: 3
- Views: 123
Re: Wave Properties and Electrons Post-Assessment #18
Hello! The significance of two holes is that this gives rise to the diffraction pattern . Therefore, the light passes through these two holes, and the wave patterns emitted from these two slits thus interact with each other, producing a diffraction pattern. In other words, diffraction patterns arise...
- Tue Oct 27, 2020 10:03 am
- Forum: Properties of Electrons
- Topic: Constructive vs Destructive
- Replies: 6
- Views: 366
Re: Constructive vs Destructive
Hello! Conceptually, constructive interference occurs when the troughs line up with each other, and when the peaks line up with each other. This results in constructive interference because in either case, the amplitude will increase . And because the amplitude increases, this signals that construct...
- Mon Oct 26, 2020 8:18 pm
- Forum: Heisenberg Indeterminacy (Uncertainty) Equation
- Topic: Change in Velocity Uncertainty
- Replies: 4
- Views: 201
Re: Change in Velocity Uncertainty
Hello! Usually, if the problem gives a range of values (e.g. 500 m/s ± 1m/s), then we will use that range of values and multiply by 2 to get the uncertainty. However, if the problem explicitly says "The uncertainty in __ is ...", then this is a signal for you to just use that exact value a...
- Mon Oct 26, 2020 8:13 pm
- Forum: Photoelectric Effect
- Topic: Finding the wavelength of an ejected atom
- Replies: 4
- Views: 251
Re: Finding the wavelength of an ejected atom
Hello! The best way to solve these type of problem is to find the velocity of the electron, with the equation KE=(1/2)mv^2. If you know the KE of the electron, plug this into the equation to solve for the velocity of the electron. Once we know the velocity of the ejected electron, then we can apply ...
- Mon Oct 26, 2020 7:19 pm
- Forum: Properties of Electrons
- Topic: Energy emitted per grams of atoms.
- Replies: 2
- Views: 75
Re: Energy emitted per grams of atoms.
Hello! We multiply by the energy found in Part A because we're trying to find the t otal amount of energy produced by 5.00 mg of sodium atoms. I'll list the steps of unit conversions from mg of sodium atoms to the total energy of these sodium atoms. 1. So if we start with 5.00 mg of atoms, then we d...
- Tue Oct 20, 2020 6:46 pm
- Forum: DeBroglie Equation
- Topic: DeBroglie Importance
- Replies: 8
- Views: 236
Re: DeBroglie Importance
Hello! One application of knowing that electrons have wave-like properties is that it can help shape the model of electron orbitals around an atom. In other words, because by the De Broglie equation we know that electrons can act as waves, this later influenced other scientists to create the atomic ...
- Tue Oct 20, 2020 6:41 pm
- Forum: Properties of Electrons
- Topic: Wave properties of electrons and diffraction
- Replies: 3
- Views: 151
Re: Wave properties of electrons and diffraction
As mentioned above, diffraction occurs because of the constructive and destructive interference of two waves. In constructive interference, the amplitude of the 2 interaction waves are additive, while in destructive interference, the amplitude of the combined wave is cancel each other out partially,...
- Tue Oct 20, 2020 12:27 pm
- Forum: Properties of Electrons
- Topic: Bound vs Free
- Replies: 4
- Views: 202
Re: Bound vs Free
A bound electron is one that is found in an atom, where it is traveling around the atom's nucleus. And a free electron is one that has been ejected from an atom, so it is not part of an atom anymore. When looking at electrons in chemistry, we usually deal with electrons in the context of atoms, so u...
- Mon Oct 19, 2020 8:12 pm
- Forum: DeBroglie Equation
- Topic: Difference between DeBroglie and regular wavelength
- Replies: 4
- Views: 218
Re: Difference between DeBroglie and regular wavelength
Hello! The De Broglie equation is used to the find the wavelength of a particle (i.e. an electron) with wave-like properties . Basically, for very small particles, the De Broglie equation measures the wavelength of the wave-like property that particle exhibits. The other equation you mentioned, such...
- Mon Oct 19, 2020 4:46 pm
- Forum: Photoelectric Effect
- Topic: When to use E = h(nu) and not to
- Replies: 3
- Views: 198
Re: When to use E = h(nu) and not to
Yes, this is correct. If the kinetic energy of the emitted electron (during the Photoelectric Experiment) is KE=0, then we can conclude that E=hv is equal to the Work Function of the Metal. Therefore, while E=hv represents the the energy of a photon when we know its frequency (v), this equation can ...
- Tue Oct 13, 2020 3:24 pm
- Forum: Properties of Light
- Topic: Relationship Between Wavelength and Energy
- Replies: 4
- Views: 440
Re: Relationship Between Wavelength and Energy
It is correct that wavelength is inversely proportional to the energy of a wave. We know this because we see that the energy of light (photon) is determined by the equation: E=hv. We can replace v (frequency) with its relationship to wavelength to get E=hc/λ. Therefore, by this equation, since λ is ...
- Tue Oct 13, 2020 10:19 am
- Forum: Empirical & Molecular Formulas
- Topic: Empirical or Molecular
- Replies: 11
- Views: 744
Re: Empirical or Molecular
Hello! In these kinds of questions, in the problem they would usually provide the molar mass of the molecular formula . One way to find out if the empirical formula is the molecular formula is to add up all the atomic weights of the atoms found in the empirical formula. Then, if the "molar mass...
- Mon Oct 12, 2020 9:04 pm
- Forum: Photoelectric Effect
- Topic: Photoelectric Effect original purpose
- Replies: 6
- Views: 214
Re: Photoelectric Effect original purpose
Hello! In the original photoelectric experiment, the goal of the experiment was to simply determine the energy needed to eject an electron from a metal surface (the threshold energy). In other words, their goal was to measure the threshold energy of different metal surfaces. Of course, we study this...
- Mon Oct 12, 2020 3:26 pm
- Forum: General Science Questions
- Topic: Classical vs Quantum
- Replies: 6
- Views: 444
Re: Classical vs Quantum
I agree with the responses above. When chemistry is dealing with subjects on the atomic scale , often we would be dealing with quantum mechanics. This is because we are looking at discrete units that cannot be broken down further. As quantum mechanics is often dealing with subjects on a microscopic ...
- Mon Oct 12, 2020 3:14 pm
- Forum: Properties of Light
- Topic: Lecture 5 "Quantized"
- Replies: 3
- Views: 122
Re: Lecture 5 "Quantized"
When you hear “quantized”, it basically means discrete units of a value. I can provide an example: In an atom, the energy of its electrons are discrete values (in other words, electrons in atoms can’t have any energy value, but only certain discrete values of energy). Quantized values are found with...
- Wed Oct 07, 2020 10:58 am
- Forum: Limiting Reactant Calculations
- Topic: Limiting reactants
- Replies: 8
- Views: 486
Re: Limiting reactants
Hello! Yes, you are correct: in the case you described, there would be no limiting reactant, as there would be just enough of each reactant to create products. In this case you described, you can use either reactant to calculate the theoretical yield of the product (it would result in the same yield...
- Tue Oct 06, 2020 4:45 pm
- Forum: Significant Figures
- Topic: When are sig figs applied?
- Replies: 12
- Views: 315
Re: When are sig figs applied?
I would recommend implementing sig figs for the final answer . While it's possible to make sure the number of sig figs are correct in each step of the problem, ultimately the final answer should have the proper amount of significant figures. In other words, feel free to do sig figs in each step of t...
- Tue Oct 06, 2020 10:49 am
- Forum: Significant Figures
- Topic: Tips for counting sig figs?
- Replies: 9
- Views: 2547
Re: Tips for counting sig figs?
I think it's easiest to summarize the sig fig rules into 3 simple steps that determines whether the number is significant or not: 1. If the number is nonzero (3, 6, 8, etc.), then it is a significant figure . 2. If the number zero is in between two non zero numbers (606, 802, etc.), then it is a sig...
- Mon Oct 05, 2020 4:56 pm
- Forum: Balancing Chemical Reactions
- Topic: State in chemical reactions
- Replies: 13
- Views: 480
Re: State in chemical reactions
Hello! I agree with the answers given above. Including the physical state of a substance is not required to balance the chemical equation you are given. You will get the correct balanced equation whether or not you include the physical states (i.e. l, s, g, aq) in the chemical equation. However, if ...
- Mon Oct 05, 2020 3:58 pm
- Forum: Molarity, Solutions, Dilutions
- Topic: Question about Moles of Solute
- Replies: 10
- Views: 403
Re: Question about Moles of Solute
When diluting a solution, the moles of solute will always be the same. By diluting the solution (usually via adding water to that solution), you’re increasing the Volume of the Solution, while the moles Of solute remain the same. This of course will decrease the molar concentration of the solution (...