Search found 33 matches
- Sun Mar 19, 2023 7:32 am
- Forum: General Rate Laws
- Topic: Achieve week 8-10 #7
- Replies: 5
- Views: 567
Re: Achieve week 8-10 #7
To figure out the effect of each reactant on the rate you'll want to compare two experiments that differ in the concentration of only one reactant while the concentrations of the other reactants are held constant.
- Sun Mar 19, 2023 7:26 am
- Forum: Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions
- Topic: Final Review
- Replies: 3
- Views: 338
Re: Final Review
It should be endothermic if i'm not mistaken because of the fact that it's a phase change from solid --> gas. I hope this helps!
- Sun Mar 19, 2023 7:24 am
- Forum: Student Social/Study Group
- Topic: Chemistry News
- Replies: 135
- Views: 205100
Re: Chemistry News
I'm really into medical innovation so this is a cool mix of chemistry and it's application to future health innovations!
https://www.newscientist.com/article/2365043-glass-made-of-amino-acids-can-be-3d-printed-and-dissolves-in-the-body/
https://www.newscientist.com/article/2365043-glass-made-of-amino-acids-can-be-3d-printed-and-dissolves-in-the-body/
- Sun Mar 19, 2023 7:21 am
- Forum: Method of Initial Rates (To Determine n and k)
- Topic: How to determine the slow step?
- Replies: 18
- Views: 2625
Re: How to determine the slow step?
I think it was mentioned that it would be explicitly stated in the question
- Sun Mar 19, 2023 7:19 am
- Forum: Student Social/Study Group
- Topic: Post All Chemistry Jokes Here
- Replies: 9651
- Views: 4618216
Re: Post All Chemistry Jokes Here
Why do chemists enjoy working with ammonia? Because it’s pretty basic stuff!
- Sun Mar 19, 2023 7:17 am
- Forum: Student Social/Study Group
- Topic: Post All Chemistry Jokes Here
- Replies: 9651
- Views: 4618216
Re: Post All Chemistry Jokes Here
Why was the mole of oxygen molecules excited when he walked out of the singles bar? Because he got Avogadro’s number!
- Sun Mar 19, 2023 7:15 am
- Forum: First Order Reactions
- Topic: differential vs integrated
- Replies: 9
- Views: 1234
Re: differential vs integrated
Differential = Rate of RXN dependent on Reactant Concentration
Integrated = Reactant Concentration dependent on Time
Integrated = Reactant Concentration dependent on Time
- Sun Mar 19, 2023 7:12 am
- Forum: Arrhenius Equation, Activation Energies, Catalysts
- Topic: Achieve 20 week 8-10
- Replies: 6
- Views: 532
Re: Achieve 20 week 8-10
I think it's also valuable to recall the different parts of the Arrhenius equation when working this out, I'll have it listed below! > rate constant, k > the reaction at each temperature, T > the activation energy, Ea > is the universal gas constant (8.3145J⋅mol−1⋅K−1), R This is the equation you'll...
- Sun Mar 19, 2023 7:06 am
- Forum: Environment, Fossil Fuels, Alternative Fuels
- Topic: "Green" energy
- Replies: 13
- Views: 924
Re: "Green" energy
I would think that this is because, unlike fossil fuels, green energy sources release less carbon emissions. To add on to that these sources are renewable and demand less harvesting wise over the long terms. If you consider the process for continuously gathering fossil fuels and compare that to the ...
- Sun Mar 19, 2023 7:02 am
- Forum: Balancing Redox Reactions
- Topic: week 7-8 Homework #2
- Replies: 4
- Views: 636
Re: week 7-8 Homework #2
Start by balancing the charge in the half‑reactions by adding electrons.Then, balance the number of electrons transferred in each half-reaction so that it is the same in both half-reactions. In this case, the lowest common multiple is 2 e−. Once you do this sum the reactions and cancel out the elect...
- Sun Mar 19, 2023 6:57 am
- Forum: Van't Hoff Equation
- Topic: van't hoff equation
- Replies: 6
- Views: 1163
Re: van't hoff equation
You'd use the Van Hofff equation when calculating for the equilibrium constant (K) whenever there is a temperature change. I hope this helps!
- Sun Mar 19, 2023 6:54 am
- Forum: Gibbs Free Energy Concepts and Calculations
- Topic: When ∆G = 0 at equilibrium
- Replies: 9
- Views: 724
Re: When ∆G = 0 at equilibrium
Correct, when delta G is at zero this is an indicator that no work can be done since G represents Gibbs ability to do work.
- Sun Mar 19, 2023 6:49 am
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Cell Diagram and Ecell [ENDORSED]
- Replies: 29
- Views: 121779
Re: Cell Diagram and Ecell [ENDORSED]
Using what I discussed in class, and the example I did in class: ANODE (LEFT) || CATHODE (RIGHT) Cu(s) | Cu 2+ (aq) || Fe 3+ (aq), Fe 2+ (aq) | Pt(s) Put the conducting solids (electrodes) on the outside and aqueous next to the salt bridge. Always include phase in the equation and cell diagram. In ...
- Sat Mar 18, 2023 10:03 pm
- Forum: Administrative Questions and Class Announcements
- Topic: Saying Thank You to Dr. Lavelle
- Replies: 490
- Views: 929789
Re: Saying Thank You to Dr. Lavelle
Thank you Dr. Lavelle for this quarter,
I'm honestly terrible at chemistry but you've made it manageable :)
I'm honestly terrible at chemistry but you've made it manageable :)
- Sat Mar 18, 2023 10:02 pm
- Forum: Student Social/Study Group
- Topic: Post All Chemistry Jokes Here
- Replies: 9651
- Views: 4618216
Re: Post All Chemistry Jokes Here
What do you call a clown in jail? a Silicon :)
- Sat Mar 18, 2023 9:58 pm
- Forum: Student Social/Study Group
- Topic: Final Jitters
- Replies: 457
- Views: 669150
Re: Final Jitters
I always recommend investing in some quality sleep, and grounding exercises like counting things you see around you. Most importantly remember that you can do it and not to overwhelm yourself if you get stuck, just breathe and push through!
- Sat Mar 18, 2023 3:09 pm
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: K' Confusion
- Replies: 3
- Views: 468
K' Confusion
What does K' (aka K prime) refer to when solving for the equilibrium constant, K. What does it represent?
- Sat Mar 18, 2023 1:27 pm
- Forum: General Rate Laws
- Topic: Integrating Both Sides for Order RXN
- Replies: 2
- Views: 128
Integrating Both Sides for Order RXN
In the 3/6 lecture I was a bit confused of what exactly the professor meant when we "integrated both sides" for both the 1st order reaction and 2nd order reaction breakdown. If anyone can explain what's going on I'd really appreciate it! [img] Screenshot%202023-03-18%20132524.png [/img][im...
- Sat Mar 18, 2023 12:05 am
- Forum: Second Order Reactions
- Topic: Achieve Question #12
- Replies: 7
- Views: 914
Achieve Question #12
I keep trying to apply the second order kinetics equation 1/[A]t = kt + (1/[A]0) but it doesn't seem to be working, if anyone can explain the steps they did to get the correct answer I'd really appreciate it! A particular reactant decomposes with a half‑life of 125s when its initial concentration is...
- Fri Mar 17, 2023 8:12 pm
- Forum: Balancing Redox Reactions
- Topic: Balancing Equation
- Replies: 4
- Views: 317
Balancing Equation
Hi can anyone help with balancing this problem week 7/8. Balance the reaction, including the phase (solid, liquid, etc.) of each species. The reaction takes place in basic aqueous solution.
MnO−4(aq)+S2−(aq)⟶S(s)+MnO2(s)
MnO−4(aq)+S2−(aq)⟶S(s)+MnO2(s)
- Fri Mar 17, 2023 7:59 pm
- Forum: Calculating Standard Reaction Entropies (e.g. , Using Standard Molar Entropies)
- Topic: Achieve Week 5/6 Question #7
- Replies: 5
- Views: 709
Re: Achieve Week 5/6 Question #7
First, convert 3.36 min to seconds and multiply it by 500 W (recall that W is J/s) to get the energy supplied by the heater in J = 1.01 x 10^5 J Find the molar mass difference (361.6 g−90.33 g) and convert it to moles. Get the enthalpy of vaporization by 1.01 x 10^5 J /molar mass difference in mole...
- Fri Mar 17, 2023 5:11 pm
- Forum: Calculating Standard Reaction Entropies (e.g. , Using Standard Molar Entropies)
- Topic: Achieve Week 5/6 Question #7
- Replies: 5
- Views: 709
Achieve Week 5/6 Question #7
Hi I'm not sure what I'm getting wrong but if anyone can explain the steps they did to get ΔHvap of C4H10 and ΔSvap of C4H10? Three liquid samples of known masses are heated to their boiling points with the use of a heater rated at 500.0 W. Once the boiling points of each sample are reached, the sam...
- Fri Mar 17, 2023 4:28 pm
- Forum: Zero Order Reactions
- Topic: Comparing order differential rate laws
- Replies: 3
- Views: 146
Comparing order differential rate laws
Is there any rule of thumb or general advice to remember the differences/purposes between zero, first, and second-order reactions?
- Fri Mar 17, 2023 4:05 pm
- Forum: Method of Initial Rates (To Determine n and k)
- Topic: Comparing Experiments
- Replies: 5
- Views: 520
Comparing Experiments
I'm reviewing 3/3 lecture (timestamp - 41:01) and I was just a bit confused as to why we compared experiments 1 & 2 and also 2 & 3. Why not other pairings like 1 & 3? Also, why does n=1 when it states rate doubles when we compare experiments 2 & 3. Any clarification would be really h...
- Fri Mar 17, 2023 1:38 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: delta G versus delta G (knot)
- Replies: 2
- Views: 148
delta G versus delta G (knot)
whats the difference between the ∆G = -nFE and ∆G°= -nFE°? In what situation would you use one over the other?
- Fri Mar 17, 2023 1:29 pm
- Forum: Balancing Redox Reactions
- Topic: Le Chatelier's Principle
- Replies: 3
- Views: 153
Le Chatelier's Principle
what does it mean when Ecell is > or < E(knot)cell?
- Wed Mar 15, 2023 11:25 pm
- Forum: Balancing Redox Reactions
- Topic: writing cell reactions
- Replies: 2
- Views: 140
writing cell reactions
In 2/22 lecture I was a bit confused about this part (timestamp 15:25): Balance Half Reactions & Write Cell Reaction - Cathode: 2Fe3+ + 2e- --> 2Fe2+ E = 0.77 V - Anode: Cu --> Cu2+ + 2e- E = -0.34 V ------------------------------------------------------------------------ Redox RXN: 2Fe3+ + Cu -...
- Tue Mar 14, 2023 11:22 pm
- Forum: Balancing Redox Reactions
- Topic: Spontaneous
- Replies: 8
- Views: 301
Spontaneous
What does it mean when a reduction is spontaneous? In the 2/17 lecture, the slides stated that " + value means reduction is spontaneous." Can anyone is able to clarify/explain what this means exactly?
- Tue Mar 14, 2023 10:35 pm
- Forum: Balancing Redox Reactions
- Topic: H2O & H+ in redox reactions
- Replies: 2
- Views: 140
H2O & H+ in redox reactions
Im reviewing the 2/17 lecture and was a bit confused (at timestamp 14:06) as to why in the Oxidation reaction it only focuses on the Fe, but in the Reduction reaction includes H+ and H2O. If anyone could explain why this is the case I'd really appreciate it! This is how it's shown: Oxidation: 5Fe2+ ...
- Sun Mar 05, 2023 7:18 pm
- Forum: Balancing Redox Reactions
- Topic: Determining Oxidation Numbers
- Replies: 2
- Views: 158
Determining Oxidation Numbers
Hi, I'm still a bit confused on how to figure out the oxidation number for an element in a compound. Also does it vary depending on which side of the reaction it's on, if it's a product or reactant?
- Wed Feb 22, 2023 2:19 pm
- Forum: Concepts & Calculations Using Second Law of Thermodynamics
- Topic: Gas Constant Application
- Replies: 2
- Views: 118
Gas Constant Application
While doing practice problems I find that I'm using the wrong R constant from time to time (ie. 8.314 vs 8.206*10^-2). Is there a rule of thumb for when I should use each one?
- Fri Feb 10, 2023 11:32 pm
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: Work in terms of volume expansion or decreasing
- Replies: 1
- Views: 235
Work in terms of volume expansion or decreasing
In lecture 2/1 the topic of work done on or by a system was a bit confusing and I just wanted to see if anyone could clarify if this is right or correct me. So if work is done on a system and the volume of that system is decreasing this would be represented with this equation: w=P*ΔV. Then if work i...
- Wed Feb 01, 2023 1:23 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Products/Reactants & Enthalpy
- Replies: 3
- Views: 399
Products/Reactants & Enthalpy
In the 1/25/2023 lecture, I was getting confused if it was that "products have a higher enthalpy than reactants" or if it's "reactants have a higher enthalpy than products" and why? If anyone can explain