Search found 33 matches

by Emily Vargas 2I
Sun Mar 19, 2023 7:32 am
Forum: General Rate Laws
Topic: Achieve week 8-10 #7
Replies: 5
Views: 567

Re: Achieve week 8-10 #7

To figure out the effect of each reactant on the rate you'll want to compare two experiments that differ in the concentration of only one reactant while the concentrations of the other reactants are held constant.
by Emily Vargas 2I
Sun Mar 19, 2023 7:26 am
Forum: Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions
Topic: Final Review
Replies: 3
Views: 338

Re: Final Review

It should be endothermic if i'm not mistaken because of the fact that it's a phase change from solid --> gas. I hope this helps!
by Emily Vargas 2I
Sun Mar 19, 2023 7:24 am
Forum: Student Social/Study Group
Topic: Chemistry News
Replies: 135
Views: 205100

Re: Chemistry News

I'm really into medical innovation so this is a cool mix of chemistry and it's application to future health innovations!
https://www.newscientist.com/article/2365043-glass-made-of-amino-acids-can-be-3d-printed-and-dissolves-in-the-body/
by Emily Vargas 2I
Sun Mar 19, 2023 7:21 am
Forum: Method of Initial Rates (To Determine n and k)
Topic: How to determine the slow step?
Replies: 18
Views: 2625

Re: How to determine the slow step?

I think it was mentioned that it would be explicitly stated in the question
by Emily Vargas 2I
Sun Mar 19, 2023 7:19 am
Forum: Student Social/Study Group
Topic: Post All Chemistry Jokes Here
Replies: 9651
Views: 4618216

Re: Post All Chemistry Jokes Here

Why do chemists enjoy working with ammonia? Because it’s pretty basic stuff!
by Emily Vargas 2I
Sun Mar 19, 2023 7:17 am
Forum: Student Social/Study Group
Topic: Post All Chemistry Jokes Here
Replies: 9651
Views: 4618216

Re: Post All Chemistry Jokes Here

Why was the mole of oxygen molecules excited when he walked out of the singles bar? Because he got Avogadro’s number!
by Emily Vargas 2I
Sun Mar 19, 2023 7:15 am
Forum: First Order Reactions
Topic: differential vs integrated
Replies: 9
Views: 1234

Re: differential vs integrated

Differential = Rate of RXN dependent on Reactant Concentration
Integrated = Reactant Concentration dependent on Time
by Emily Vargas 2I
Sun Mar 19, 2023 7:12 am
Forum: Arrhenius Equation, Activation Energies, Catalysts
Topic: Achieve 20 week 8-10
Replies: 6
Views: 532

Re: Achieve 20 week 8-10

I think it's also valuable to recall the different parts of the Arrhenius equation when working this out, I'll have it listed below! > rate constant, k > the reaction at each temperature, T > the activation energy, Ea > is the universal gas constant (8.3145J⋅mol−1⋅K−1), R This is the equation you'll...
by Emily Vargas 2I
Sun Mar 19, 2023 7:06 am
Forum: Environment, Fossil Fuels, Alternative Fuels
Topic: "Green" energy
Replies: 13
Views: 924

Re: "Green" energy

I would think that this is because, unlike fossil fuels, green energy sources release less carbon emissions. To add on to that these sources are renewable and demand less harvesting wise over the long terms. If you consider the process for continuously gathering fossil fuels and compare that to the ...
by Emily Vargas 2I
Sun Mar 19, 2023 7:02 am
Forum: Balancing Redox Reactions
Topic: week 7-8 Homework #2
Replies: 4
Views: 636

Re: week 7-8 Homework #2

Start by balancing the charge in the half‑reactions by adding electrons.Then, balance the number of electrons transferred in each half-reaction so that it is the same in both half-reactions. In this case, the lowest common multiple is 2 e−. Once you do this sum the reactions and cancel out the elect...
by Emily Vargas 2I
Sun Mar 19, 2023 6:57 am
Forum: Van't Hoff Equation
Topic: van't hoff equation
Replies: 6
Views: 1163

Re: van't hoff equation

You'd use the Van Hofff equation when calculating for the equilibrium constant (K) whenever there is a temperature change. I hope this helps!
by Emily Vargas 2I
Sun Mar 19, 2023 6:54 am
Forum: Gibbs Free Energy Concepts and Calculations
Topic: When ∆G = 0 at equilibrium
Replies: 9
Views: 724

Re: When ∆G = 0 at equilibrium

Correct, when delta G is at zero this is an indicator that no work can be done since G represents Gibbs ability to do work.
by Emily Vargas 2I
Sun Mar 19, 2023 6:49 am
Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
Topic: Cell Diagram and Ecell [ENDORSED]
Replies: 29
Views: 121779

Re: Cell Diagram and Ecell [ENDORSED]

Using what I discussed in class, and the example I did in class: ANODE (LEFT) || CATHODE (RIGHT) Cu(s) | Cu 2+ (aq) || Fe 3+ (aq), Fe 2+ (aq) | Pt(s) Put the conducting solids (electrodes) on the outside and aqueous next to the salt bridge. Always include phase in the equation and cell diagram. In ...
by Emily Vargas 2I
Sat Mar 18, 2023 10:03 pm
Forum: Administrative Questions and Class Announcements
Topic: Saying Thank You to Dr. Lavelle
Replies: 490
Views: 929789

Re: Saying Thank You to Dr. Lavelle

Thank you Dr. Lavelle for this quarter,

I'm honestly terrible at chemistry but you've made it manageable :)
by Emily Vargas 2I
Sat Mar 18, 2023 10:02 pm
Forum: Student Social/Study Group
Topic: Post All Chemistry Jokes Here
Replies: 9651
Views: 4618216

Re: Post All Chemistry Jokes Here

What do you call a clown in jail? a Silicon :)
by Emily Vargas 2I
Sat Mar 18, 2023 9:58 pm
Forum: Student Social/Study Group
Topic: Final Jitters
Replies: 457
Views: 669150

Re: Final Jitters

I always recommend investing in some quality sleep, and grounding exercises like counting things you see around you. Most importantly remember that you can do it and not to overwhelm yourself if you get stuck, just breathe and push through!
by Emily Vargas 2I
Sat Mar 18, 2023 3:09 pm
Forum: Reaction Mechanisms, Reaction Profiles
Topic: K' Confusion
Replies: 3
Views: 468

K' Confusion

What does K' (aka K prime) refer to when solving for the equilibrium constant, K. What does it represent?
by Emily Vargas 2I
Sat Mar 18, 2023 1:27 pm
Forum: General Rate Laws
Topic: Integrating Both Sides for Order RXN
Replies: 2
Views: 128

Integrating Both Sides for Order RXN

In the 3/6 lecture I was a bit confused of what exactly the professor meant when we "integrated both sides" for both the 1st order reaction and 2nd order reaction breakdown. If anyone can explain what's going on I'd really appreciate it! [img] Screenshot%202023-03-18%20132524.png [/img][im...
by Emily Vargas 2I
Sat Mar 18, 2023 12:05 am
Forum: Second Order Reactions
Topic: Achieve Question #12
Replies: 7
Views: 914

Achieve Question #12

I keep trying to apply the second order kinetics equation 1/[A]t = kt + (1/[A]0) but it doesn't seem to be working, if anyone can explain the steps they did to get the correct answer I'd really appreciate it! A particular reactant decomposes with a half‑life of 125s when its initial concentration is...
by Emily Vargas 2I
Fri Mar 17, 2023 8:12 pm
Forum: Balancing Redox Reactions
Topic: Balancing Equation
Replies: 4
Views: 317

Balancing Equation

Hi can anyone help with balancing this problem week 7/8. Balance the reaction, including the phase (solid, liquid, etc.) of each species. The reaction takes place in basic aqueous solution.

MnO−4(aq)+S2−(aq)⟶S(s)+MnO2(s)
by Emily Vargas 2I
Fri Mar 17, 2023 7:59 pm
Forum: Calculating Standard Reaction Entropies (e.g. , Using Standard Molar Entropies)
Topic: Achieve Week 5/6 Question #7
Replies: 5
Views: 709

Re: Achieve Week 5/6 Question #7

First, convert 3.36 min to seconds and multiply it by 500 W (recall that W is J/s) to get the energy supplied by the heater in J = 1.01 x 10^5 J Find the molar mass difference (361.6 g−90.33 g) and convert it to moles. Get the enthalpy of vaporization by 1.01 x 10^5 J /molar mass difference in mole...
by Emily Vargas 2I
Fri Mar 17, 2023 5:11 pm
Forum: Calculating Standard Reaction Entropies (e.g. , Using Standard Molar Entropies)
Topic: Achieve Week 5/6 Question #7
Replies: 5
Views: 709

Achieve Week 5/6 Question #7

Hi I'm not sure what I'm getting wrong but if anyone can explain the steps they did to get ΔHvap of C4H10 and ΔSvap of C4H10? Three liquid samples of known masses are heated to their boiling points with the use of a heater rated at 500.0 W. Once the boiling points of each sample are reached, the sam...
by Emily Vargas 2I
Fri Mar 17, 2023 4:28 pm
Forum: Zero Order Reactions
Topic: Comparing order differential rate laws
Replies: 3
Views: 146

Comparing order differential rate laws

Is there any rule of thumb or general advice to remember the differences/purposes between zero, first, and second-order reactions?
by Emily Vargas 2I
Fri Mar 17, 2023 4:05 pm
Forum: Method of Initial Rates (To Determine n and k)
Topic: Comparing Experiments
Replies: 5
Views: 520

Comparing Experiments

I'm reviewing 3/3 lecture (timestamp - 41:01) and I was just a bit confused as to why we compared experiments 1 & 2 and also 2 & 3. Why not other pairings like 1 & 3? Also, why does n=1 when it states rate doubles when we compare experiments 2 & 3. Any clarification would be really h...
by Emily Vargas 2I
Fri Mar 17, 2023 1:38 pm
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: delta G versus delta G (knot)
Replies: 2
Views: 148

delta G versus delta G (knot)

whats the difference between the ∆G = -nFE and ∆G°= -nFE°? In what situation would you use one over the other?
by Emily Vargas 2I
Fri Mar 17, 2023 1:29 pm
Forum: Balancing Redox Reactions
Topic: Le Chatelier's Principle
Replies: 3
Views: 153

Le Chatelier's Principle

what does it mean when Ecell is > or < E(knot)cell?
by Emily Vargas 2I
Wed Mar 15, 2023 11:25 pm
Forum: Balancing Redox Reactions
Topic: writing cell reactions
Replies: 2
Views: 140

writing cell reactions

In 2/22 lecture I was a bit confused about this part (timestamp 15:25): Balance Half Reactions & Write Cell Reaction - Cathode: 2Fe3+ + 2e- --> 2Fe2+ E = 0.77 V - Anode: Cu --> Cu2+ + 2e- E = -0.34 V ------------------------------------------------------------------------ Redox RXN: 2Fe3+ + Cu -...
by Emily Vargas 2I
Tue Mar 14, 2023 11:22 pm
Forum: Balancing Redox Reactions
Topic: Spontaneous
Replies: 8
Views: 301

Spontaneous

What does it mean when a reduction is spontaneous? In the 2/17 lecture, the slides stated that " + value means reduction is spontaneous." Can anyone is able to clarify/explain what this means exactly?
by Emily Vargas 2I
Tue Mar 14, 2023 10:35 pm
Forum: Balancing Redox Reactions
Topic: H2O & H+ in redox reactions
Replies: 2
Views: 140

H2O & H+ in redox reactions

Im reviewing the 2/17 lecture and was a bit confused (at timestamp 14:06) as to why in the Oxidation reaction it only focuses on the Fe, but in the Reduction reaction includes H+ and H2O. If anyone could explain why this is the case I'd really appreciate it! This is how it's shown: Oxidation: 5Fe2+ ...
by Emily Vargas 2I
Sun Mar 05, 2023 7:18 pm
Forum: Balancing Redox Reactions
Topic: Determining Oxidation Numbers
Replies: 2
Views: 158

Determining Oxidation Numbers

Hi, I'm still a bit confused on how to figure out the oxidation number for an element in a compound. Also does it vary depending on which side of the reaction it's on, if it's a product or reactant?
by Emily Vargas 2I
Wed Feb 22, 2023 2:19 pm
Forum: Concepts & Calculations Using Second Law of Thermodynamics
Topic: Gas Constant Application
Replies: 2
Views: 118

Gas Constant Application

While doing practice problems I find that I'm using the wrong R constant from time to time (ie. 8.314 vs 8.206*10^-2). Is there a rule of thumb for when I should use each one?
by Emily Vargas 2I
Fri Feb 10, 2023 11:32 pm
Forum: Thermodynamic Systems (Open, Closed, Isolated)
Topic: Work in terms of volume expansion or decreasing
Replies: 1
Views: 235

Work in terms of volume expansion or decreasing

In lecture 2/1 the topic of work done on or by a system was a bit confusing and I just wanted to see if anyone could clarify if this is right or correct me. So if work is done on a system and the volume of that system is decreasing this would be represented with this equation: w=P*ΔV. Then if work i...
by Emily Vargas 2I
Wed Feb 01, 2023 1:23 pm
Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
Topic: Products/Reactants & Enthalpy
Replies: 3
Views: 399

Products/Reactants & Enthalpy

In the 1/25/2023 lecture, I was getting confused if it was that "products have a higher enthalpy than reactants" or if it's "reactants have a higher enthalpy than products" and why? If anyone can explain

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