Search found 40 matches
- Tue Mar 12, 2024 6:45 pm
- Forum: Arrhenius Equation, Activation Energies, Catalysts
- Topic: Temperature and Reaction rates
- Replies: 3
- Views: 46
Temperature and Reaction rates
What is the importance of the Arrhenius equation how is temperature related to reaction rates?
- Tue Mar 12, 2024 6:42 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Cell Diagram Lines vs Commas and Orders of Species
- Replies: 1
- Views: 32
Re: Cell Diagram Lines vs Commas and Orders of Species
Hi ! I think Dr. Lavelle mentioned that the reactants are specified first and the products last. And yes you should separate the same phase in the cell diagram with a comma instead of a single line.
- Tue Mar 12, 2024 6:40 pm
- Forum: Interesting Applications: Rechargeable Batteries (Cell Phones, Notebooks, Cars), Fuel Cells (Space Shuttle), Photovoltaic Cells (Solar Panels), Electrolysis, Rust
- Topic: Chromium Plating
- Replies: 2
- Views: 65
Re: Chromium Plating
While the standard reduction potential does play a role in the corrosion inhibition process, the overall effectiveness of chromium as a corrosion inhibitor for iron is primarily attributed to its ability to form a stable and protective oxide layer.
- Tue Mar 12, 2024 11:50 am
- Forum: Arrhenius Equation, Activation Energies, Catalysts
- Topic: Activation energy and enthalpy
- Replies: 2
- Views: 29
Activation energy and enthalpy
Is there a connection between activation energy and enthalpy?
- Mon Mar 04, 2024 2:44 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: diff between oxidation reduction rxn and half rxn.
- Replies: 2
- Views: 21
diff between oxidation reduction rxn and half rxn.
What is the difference between an oxidation-reduction reaction and a half-reaction?
- Mon Mar 04, 2024 2:40 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: other inert metals
- Replies: 2
- Views: 36
other inert metals
what other inert metals are there that we can put for the galvanic cell?
- Sun Mar 03, 2024 3:05 pm
- Forum: Appications of the Nernst Equation (e.g., Concentration Cells, Non-Standard Cell Potentials, Calculating Equilibrium Constants and pH)
- Topic: How do I find the n value when applying the Nernst Equation?
- Replies: 2
- Views: 41
Re: How do I find the n value when applying the Nernst Equation?
To find n, that is simply the amount of electrons you set up to balance on both sides. It doesn't matter that they cancel but that coefficient is what you input for n.
- Sun Mar 03, 2024 3:01 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Writing Galvanic Cells
- Replies: 2
- Views: 39
Re: Writing Galvanic Cells
Hi! In cell notation, a vertical line, |, denotes a phase boundary and a double line, ||, a salt bridge. The anode electrode is written to the left, followed by the anode solution, then the salt bridge, then the cathode solution, and,the cathode electrode to the right. I think Dr. Lavelle said to do...
- Tue Feb 27, 2024 12:34 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: Achieve Wk 7/8 #18
- Replies: 2
- Views: 38
Achieve Wk 7/8 #18
What does the dot represent in question 18 Wk7/8 achieve?
- Mon Feb 26, 2024 7:13 pm
- Forum: Balancing Redox Reactions
- Topic: Assigning oxidation numbers
- Replies: 3
- Views: 51
Re: Assigning oxidation numbers
Hi! To add I thought this table on this website was helpful: https://www.onlinemathlearning.com/redox-reaction.html
- Mon Feb 26, 2024 7:06 pm
- Forum: Balancing Redox Reactions
- Topic: Conceptual difference between acidic and basic solutions
- Replies: 2
- Views: 29
Re: Conceptual difference between acidic and basic solutions
And to add on to Larne's response. To balance the excess of H+ ions, you add OH- ions to form water (H2O) molecules and make the solution basic. This video was helpful for me: https://youtube.com/watch?v=N6ivvu6xlog
- Mon Feb 26, 2024 6:59 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Appendix for Standard Reduction Potential
- Replies: 1
- Views: 39
Appendix for Standard Reduction Potential
HI! Is there an appendix for the Standard reduction potentials or are they all on the table in 6L?
- Sun Feb 25, 2024 6:19 pm
- Forum: Balancing Redox Reactions
- Topic: Term Question
- Replies: 1
- Views: 32
Re: Term Question
Skeleton equations have only the chemical formulas of reactants and products, but no state is mentioned. There is also no balancing of atoms on either side of the equation.
- Sun Feb 25, 2024 6:17 pm
- Forum: Balancing Redox Reactions
- Topic: EMF
- Replies: 2
- Views: 113
Re: EMF
EMF is the maximum potential difference that can be reached between the electrodes of an electrochemical cell, and it causes electrons to flow through an external circuit until equilibrium is reached.
- Sat Feb 17, 2024 1:16 pm
- Forum: Concepts & Calculations Using First Law of Thermodynamics
- Topic: Enthalpy
- Replies: 2
- Views: 56
Re: Enthalpy
You know that the units of enthalpy of vaporization is J/mol or kJ/mol so i would kind of use the units to help solve. So you know you have to divide the q (kJ) by the number of mols to get the final units in kJ/mol! Hope this helps! - Savonnah
- Sat Feb 17, 2024 1:13 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Translational Entropy
- Replies: 1
- Views: 28
Translational Entropy
What is translational entropy?
- Tue Feb 13, 2024 1:23 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: why is delta G = 0 at boiling point?
- Replies: 2
- Views: 34
why is delta G = 0 at boiling point?
why is delta G = 0 at boiling point?
- Mon Feb 12, 2024 3:40 pm
- Forum: Calculating Work of Expansion
- Topic: Work: Positive or Negative
- Replies: 2
- Views: 42
Re: Work: Positive or Negative
work is done on the system so you know work should be positive.
- Mon Feb 12, 2024 3:38 pm
- Forum: Calculating Standard Reaction Entropies (e.g. , Using Standard Molar Entropies)
- Topic: Vibrational states
- Replies: 1
- Views: 36
Re: Vibrational states
Molecular vibration happens when atoms in a molecule are in periodic motion while the whole molecule has constant translational and rotational motion. A fundamental vibration occurs when one quanta of energy is absorbed by the molecule in its ground state. When two quanta are absorbed, the first vib...
- Mon Feb 12, 2024 3:34 pm
- Forum: Phase Changes & Related Calculations
- Topic: Changing Volume and Pressure
- Replies: 2
- Views: 58
Re: Changing Volume and Pressure
to answer your first question when both volume and pressure change, i would simply use W = p Δ V .
- Mon Feb 12, 2024 3:31 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Example of Reversible Reaction
- Replies: 1
- Views: 36
Example of Reversible Reaction
What is an example in real life of a reversible expansion? Dr. Lavelle gave an example of paint canister cooling for the sudden expansion and was wondering what about reversible expansion.
- Mon Feb 12, 2024 3:30 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Reversible reaction
- Replies: 1
- Views: 30
Reversible reaction
Does reversible reaction just mean that the surrounding and system pressures change in infinitesimally small steps?
- Mon Feb 05, 2024 2:13 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Specific heat capacity
- Replies: 2
- Views: 26
Re: Specific heat capacity
Yes! specific heat capacity are always a positive value because it's the amount of energy (heat) required to raise the system's temperature.
- Mon Feb 05, 2024 10:20 am
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Specific Heat Capacity
- Replies: 3
- Views: 56
Specific Heat Capacity
When specific heat capacity is in (J/g * K), is this interchangeable with (J/g * C) or do we need ot convert from K to C?
- Mon Feb 05, 2024 10:13 am
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: How do you know when a problem is a calorimetry problem?
- Replies: 2
- Views: 43
How do you know when a problem is a calorimetry problem?
Hi! How do you know when a problem is a calorimetry problem?
- Mon Feb 05, 2024 10:06 am
- Forum: Concepts & Calculations Using First Law of Thermodynamics
- Topic: When q or w = 0
- Replies: 2
- Views: 57
Re: When q or w = 0
when the energy of an isolated system is constant because no matter or heat can be transferred, and the system can't be physically changed. key think is an isolated system.
- Wed Jan 24, 2024 9:32 pm
- Forum: Phase Changes & Related Calculations
- Topic: Water Vapor v. Boiling Water
- Replies: 1
- Views: 39
Re: Water Vapor v. Boiling Water
It can be at the same temperature but because of the large enthalpy of condesation (vapor going to liquid) there is a lot more heat than fusion transition (liquid going to solid) compare the 40.7kJ to 5kJ.
- Wed Jan 24, 2024 9:30 pm
- Forum: Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions
- Topic: Homework Week 2-3
- Replies: 1
- Views: 40
Re: Homework Week 2-3
We find Percent ionization by (Number of ions produced / Total number of molecules) x 100
- Wed Jan 24, 2024 9:29 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: When to use Hess's Law and Bond Energies
- Replies: 1
- Views: 48
When to use Hess's Law and Bond Energies
Hi! When should you use Hess's Law and when should you use Bond Energies?
- Wed Jan 24, 2024 9:20 pm
- Forum: Properties & Structures of Inorganic & Organic Acids
- Topic: Basic vs Acidic Salt
- Replies: 1
- Views: 121
Basic vs Acidic Salt
Hi! How do you know when something is a basic or acidic salt?
- Wed Jan 17, 2024 5:36 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: ph scale
- Replies: 1
- Views: 37
Re: ph scale
A pH value can be greater than 14 for very concentrated strong bases.
- Wed Jan 17, 2024 5:34 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Change in pH
- Replies: 3
- Views: 40
Re: Change in pH
Because the pH scale is logarithmic (pH = -log[H+]), a change of one pH unit corresponds to a ten-fold change in hydrogen ion concentration. For example, a solution with a pH of 3 has 10 times more H+ than a solution with a pH of 4.
value = 10^x
x=log_10 value
value = 10^x
x=log_10 value
- Wed Jan 17, 2024 5:30 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Are the conjugates of weak acids strong bases?
- Replies: 2
- Views: 32
Re: Are the conjugates of weak acids strong bases?
Yes the conjugate base of a weak acid is strong!
- Tue Jan 16, 2024 12:19 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Factors affecting pKa
- Replies: 3
- Views: 85
Factors affecting pKa
Hi! What are the factors affecting pKa values?
- Tue Jan 16, 2024 12:18 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: pKa and Ka
- Replies: 1
- Views: 40
pKa and Ka
Hi! I was wondering what pKa and Ka were and how does pKa affect equilibrium?
- Thu Jan 11, 2024 10:12 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Barr vs Atm
- Replies: 1
- Views: 26
Barr vs Atm
What is the difference between the units barr and atm?
- Thu Jan 11, 2024 6:38 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Achieve Chemical Equilibria Hw #9
- Replies: 1
- Views: 49
Achieve Chemical Equilibria Hw #9
Hi! For question #9 for the Achieve Chemical Equilibria why is the x a negative value when it is solved for? In lecture, I thought Dr. Lavelle said that x could never be a negative value.
- Thu Jan 11, 2024 6:38 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Achieve Chemical Equilibria Hw #9
- Replies: 1
- Views: 47
Achieve Chemical Equilibria Hw #9
Hi! For question #9 for the Achieve Chemical Equilibria why is the x a negative value when it is solved for? In lecture, I thought Dr. Lavelle said that x could never be a negative value.
- Tue Jan 09, 2024 5:48 pm
- Forum: Non-Equilibrium Conditions & The Reaction Quotient
- Topic: Meaning of Kc
- Replies: 3
- Views: 264
Re: Meaning of Kc
Hi! Kc is is the ratio of the equilibrium concentrations of products over the equilibrium concentrations of reactants each raised to the power of their stoichiometric coefficients! It also tells us whether the reaction tends to have a higher concentration of products or reactants at equilibrium.
- Tue Jan 09, 2024 1:23 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Catalysts and Equilibrium Constant
- Replies: 2
- Views: 39
Re: Catalysts and Equilibrium Constant
Hi! I believe if you add a catalyst the equilibrium constant does not change. It simply speeds up the forward and reverse reaction.