Search found 21 matches
- Sat Mar 05, 2016 2:46 pm
- Forum: Thermodynamic Definitions (isochoric/isometric, isothermal, isobaric)
- Topic: Heat Capacity
- Replies: 1
- Views: 531
Re: Heat Capacity
Chem_Mod answered this question in 2013: " Ethane has more freedom due to the C-C single bond vs. ethene with a C=C double bond which is more rigid. Having more freedom means a higher heat capacity...Ethane is a more complex molecule as it contains two more hydrogens. Some of the energy when he...
- Thu Mar 03, 2016 12:26 pm
- Forum: *Nucleophiles
- Topic: Distinguishing Nucleophiles
- Replies: 1
- Views: 513
Re: Distinguishing Nucleophiles
F is an electrophile but F- is an nucleophile.
- Mon Feb 29, 2016 12:46 am
- Forum: *Alkenes
- Topic: HW Question 1.12 Numbering the structure
- Replies: 2
- Views: 639
HW Question 1.12 Numbering the structure
For homework question number 1.12, why do we number the diene before the methyl. I thought we learned to give the number of the methyl group priority when naming the structure?
- Thu Feb 18, 2016 10:18 am
- Forum: Reaction Mechanisms, Reaction Profiles
- Topic: Pre-equilibrium vs steady-state
- Replies: 2
- Views: 1188
Re: Pre-equilibrium vs steady-state
My friend and I researched this and found: The steady state method can only be used if the first step of a reaction is much slower than the second step, whereas the pre-equilibrium approximation requires the first step to be faster. I don't know if this is completely correct but this is what we found.
- Thu Feb 18, 2016 10:17 am
- Forum: Second Order Reactions
- Topic: Multi-Reactant Concentration Changes
- Replies: 1
- Views: 605
Re: Multi-Reactant Concentration Changes
You won't get a straight line for more than one of these because each graph represents a different variation of [B] vs time. [B], ln[B] and 1/[B] all have different plots.
- Fri Feb 12, 2016 6:28 pm
- Forum: Second Order Reactions
- Topic: Identifying second order RXNS
- Replies: 2
- Views: 749
Re: Identifying second order RXNS
You can identify a second order reaction by looking at the rate is would be going. Usually, second order reaction rates are proportional to the product of two reactants, with the reactants being the same or different. Like one form of a second order reaction is 2A->C or A+B->C. The rate for the firs...
- Sun Feb 07, 2016 1:38 pm
- Forum: Phase Changes & Related Calculations
- Topic: qsys=-qsurr? Winter 2013 Midterm
- Replies: 1
- Views: 4093
Re: qsys=-qsurr? Winter 2013 Midterm
The negative sign just represents what thing (water or katana) releases the heat and which absorbs the heat. Because the katana has a larger temperature, heat is going to be released from the katana to the water making q negative while the water absorbs that heat making q positive. Either of them co...
- Thu Jan 28, 2016 8:38 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Endothermic or exothermic
- Replies: 3
- Views: 577
Re: Endothermic or exothermic
Breaking a bond is always an endothermic process, but whether the reaction is endothermic or not is determined by comparing the enthalpies of the products to the enthalpies of the reactants.
- Sun Jan 24, 2016 11:25 am
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Constant P Calorimeter - Bond Formation Q???
- Replies: 2
- Views: 527
Re: Constant P Calorimeter - Bond Formation Q???
When bonds are formed energy is released because the molecules/atoms go from a unstable form to a stable one. They go from high energy to low energy and thus energy in terms of heat is released (exothermic). In order to break bonds, there must be an absorption of energy to overcome electrostatic att...
- Sun Jan 17, 2016 11:53 pm
- Forum: Thermodynamic Systems (Open, Closed, Isolated)
- Topic: Closed versus Isolated System
- Replies: 2
- Views: 615
Re: Closed versus Isolated System
I believe its still an isolated system because we are viewing it as an ideal situation. A thermos bottle, ideally, should not allow matter or energy exchange.
- Mon Jan 11, 2016 11:20 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Measurement of Enthalpy example problem in course reader
- Replies: 1
- Views: 508
Re: Measurement of Enthalpy example problem in course reader
I believe you can still do the problem but you would have to account for the fact that the concentration of one reactant is more than another and thus only a certain amount of H2O can be produced. I think this would become a limiting reactant problem because the mole ratio of reactant to product is ...
- Sat Nov 28, 2015 7:43 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Quiz #3 Problems 4 and 6 Explanation
- Replies: 1
- Views: 470
Quiz #3 Problems 4 and 6 Explanation
This video explains two problems from Quiz #3. I realize that the problem may be different for other sections but its good practice. I hope this helps anyone who needed more explanation on equilibrium expressions.
- Sun Nov 22, 2015 11:34 pm
- Forum: Shape, Structure, Coordination Number, Ligands
- Topic: Bidentate or Polydentate
- Replies: 2
- Views: 806
Re: Bidentate or Polydentate
Oxygen, in oxalato, tends to only make two bonds from the single bonded oxygens. According to electronegativity, only the oxygens with three lone pairs attracts another atom. This is the reason that it is a bidentate and not a polydentate. I know it's confusing but that is what I was told. Also, you...
- Sun Nov 22, 2015 11:22 pm
- Forum: Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions
- Topic: response of equilibria to pressure as relating to moles
- Replies: 2
- Views: 630
Re: response of equilibria to pressure as relating to moles
For this problem, think about it terms of a system as a whole. So, when you increase the pressure or decrease the volume, the molecules are hitting the walls faster causing stress on the system- an increase in the total pressure of the system. In order to reduce the stress on the system, the reactio...
- Mon Nov 09, 2015 12:51 pm
- Forum: Applying Le Chatelier's Principle to Changes in Chemical & Physical Conditions
- Topic: Pressure increase by adding another gas
- Replies: 1
- Views: 700
Re: Pressure increase by adding another gas
When you add another gas, increasing the pressure of the gas, it does not mean that the volume has changed. You can keep the volume constant and still increase pressure. For example, if you add helium gas in a constant volume, you are only increasing the pressure.When you don't change the volume, th...
- Thu Nov 05, 2015 6:57 pm
- Forum: *Molecular Orbital Theory (Bond Order, Diamagnetism, Paramagnetism)
- Topic: Valence Electron Configuration
- Replies: 2
- Views: 640
Re: Valence Electron Configuration
My TA told my discussion section that it didn't matter which way you wrote it. Our course reader combines it into (n2P)^3 however.
- Mon Oct 26, 2015 9:31 am
- Forum: Determining Molecular Shape (VSEPR)
- Topic: Bond Angles for BH3-
- Replies: 1
- Views: 7726
Re: Bond Angles for BH3-
For BH2- the molecule shape is bent or angular because it has three regions of electron density with two bonds and one lone pair of electrons. This would result in bond angles <120 degrees. The lone pairs of electrons would repel the bonded electrons causing less of a bond angle between the actual b...
- Mon Oct 26, 2015 9:17 am
- Forum: Octet Exceptions
- Topic: radical compounds
- Replies: 1
- Views: 542
Re: radical compounds
Yes radical compounds usually have an odd number of valence electrons leaving one electron unpaired. An example would be CH3. However, there doesn't always need to be an odd number of valence electrons because a biradical can have an even number of valence electrons. An example of a biradical is the...
- Fri Oct 16, 2015 5:28 pm
- Forum: Hybridization
- Topic: Electron Configuration
- Replies: 2
- Views: 808
Re: Electron Configuration
Writing electron configurations depends on the energy of the shells and orbitals. The orbital with the highest energy will always be written last. That is why, for example, the "4s" orbital is written after the "3d" orbital. However, the first two periods don't have a "d&quo...
- Sat Oct 10, 2015 12:21 pm
- Forum: Electron Configurations for Multi-Electron Atoms
- Topic: Electron Removal
- Replies: 1
- Views: 611
Re: Electron Removal
The electron will come from the 4s orbital because it has more energy. More energy means more instability and thats where the valence electrons are at. It will be easier to remove an electron from a higher energized state than a lower one hence the electron for the +1 ion of Mn coming from 4s not 3d...
- Sat Oct 03, 2015 1:43 pm
- Forum: Bohr Frequency Condition, H-Atom , Atomic Spectroscopy
- Topic: Rydberg Equation
- Replies: 1
- Views: 670
Re: Rydberg Equation
This is correct. The Balmer Series begins with n1=2 so all the wavelengths that are listed are from n2=3,4,5,6. The next line would be n2=7. You would first find the frequency of this line. V(frequency)= R(1/n1^2-1/n2^2)= (3.29x10^15 Hz)(1/2^2-1/7^2)= 7.55x10^14 Hz Then convert this to wavelength by...