Search found 14 matches

by Nhat Anh Cao 1C
Tue Mar 08, 2016 4:46 pm
Forum: *Alkanes and Substituted Alkanes (Staggered, Eclipsed, Gauche, Anti, Newman Projections)
Topic: Torsional strain
Replies: 4
Views: 1060

Torsional strain

Would torsional strain be negative if you were moving from a less stable conformation to a more stable one?
by Nhat Anh Cao 1C
Tue Mar 01, 2016 1:03 am
Forum: *Constitutional and Geometric Isomers (cis, Z and trans, E)
Topic: Preference in numbering
Replies: 10
Views: 5080

Re: Preference in numbering

Do halides have priority over double bonds? I'm referring specifically to 1,6-dichloro-cyclohexane on page 105 of the course reader.
by Nhat Anh Cao 1C
Mon Feb 29, 2016 11:03 pm
Forum: *Haloalkanes
Topic: Placement of halide substituent in IUPAC name
Replies: 1
Views: 1224

Placement of halide substituent in IUPAC name

Do halides always come first in the name or does it go alphabetically? (I.e. If there was an ethyl and a fluorine anion attached to the same carbon, which would be listed first?)
by Nhat Anh Cao 1C
Mon Feb 29, 2016 11:00 pm
Forum: *Constitutional and Geometric Isomers (cis, Z and trans, E)
Topic: Preference in numbering
Replies: 10
Views: 5080

Preference in numbering

I know you give preference to double bonds and functional groups when numbering, but which is more important? If you had a choice between setting a functional group at the second carbon or a double bond starting at the second carbon, which would you choose?
by Nhat Anh Cao 1C
Sat Feb 27, 2016 4:02 pm
Forum: *Free Energy of Activation vs Activation Energy
Topic: Possible error on page 163 of ochem textbook
Replies: 1
Views: 487

Possible error on page 163 of ochem textbook

On page 163 of the Intro to Organic Chemistry textbook, it says "When \Delta G^o r <0, the exergonic reaction is favorable and K>1. When \Delta G^o r >0, the endergonic reaction is unfavorable and K<1." I believe there's an error here, but I just wanted to make sure. Im also unsure about w...
by Nhat Anh Cao 1C
Sun Feb 21, 2016 7:03 pm
Forum: *Nucleophiles
Topic: Is it possible to have two nucleotides in a rxn?
Replies: 1
Views: 467

Is it possible to have two nucleotides in a rxn?

In example 2 on course reader page 85, it is stated that a nucleophile (denoted :Nu) donates electrons to and bonds with the central carbon atom. The Cl connected to the carbon is also electron rich because of its higher electronegativity. Is it considered a nucleoniphile as well or do nucleophiles ...
by Nhat Anh Cao 1C
Sun Feb 14, 2016 3:55 pm
Forum: Method of Initial Rates (To Determine n and k)
Topic: Equation to find k when there's more than 1 reactant
Replies: 2
Views: 564

Equation to find k when there's more than 1 reactant

On page 69 of the course reader, it says . Why is A not an initial concentration?
by Nhat Anh Cao 1C
Sun Feb 14, 2016 3:48 pm
Forum: Second Order Reactions
Topic: Converting 2nd order diff rate law to integrated rate law
Replies: 1
Views: 533

Converting 2nd order diff rate law to integrated rate law

I'm confused as to where the goes when you integrate the 2nd order differential rate law, , to get . Are we assuming a equals 1? If so, why?
by Nhat Anh Cao 1C
Sat Feb 06, 2016 1:40 am
Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
Topic: Max potential
Replies: 1
Views: 440

Max potential

It is stated that potential is maximized when the process is reversible and there's very little current, but what is the explanation behind this?
by Nhat Anh Cao 1C
Sat Feb 06, 2016 1:36 am
Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
Topic: Definition of cell and redox potential
Replies: 1
Views: 598

Definition of cell and redox potential

What is the difference between E0redox and E0cell? On page 50 of the course reader, when we are given two half reactions, we want to reverse the sign of the iron half reaction to get a positive cell potential. In the gold example on page 52, E0redox is allowed to be negative. Why is this?
by Nhat Anh Cao 1C
Sun Jan 31, 2016 11:11 pm
Forum: Third Law of Thermodynamics (For a Unique Ground State (W=1): S -> 0 as T -> 0) and Calculations Using Boltzmann Equation for Entropy
Topic: Definition of microstate
Replies: 1
Views: 1676

Definition of microstate

What exactly is a microstate? Is it a location, an energy level, or something else?
by Nhat Anh Cao 1C
Sat Jan 23, 2016 12:01 am
Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
Topic: Difference between q and delta h
Replies: 1
Views: 1056

Difference between q and delta h

If enthalpy is the amount of heat released and absorbed at a constant pressure, why does the course reader and textbook alternate between using q and ? Is used when pressure isn't constant?
by Nhat Anh Cao 1C
Sun Jan 17, 2016 1:01 am
Forum: Calculating Work of Expansion
Topic: Work and equilibrium
Replies: 1
Views: 511

Work and equilibrium

What did Prof. Lavelle mean when he said "the most efficient work is done along an equilibrium pathway"?
by Nhat Anh Cao 1C
Sun Jan 10, 2016 11:39 pm
Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
Topic: State functions
Replies: 4
Views: 823

State functions

What are some other examples of state functions?

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