Search found 28 matches
- Sat Mar 12, 2016 1:47 am
- Forum: *Cycloalkanes
- Topic: Determining Order of Substients
- Replies: 1
- Views: 498
Determining Order of Substients
In the orange organic chemistry book, on page 23 of section 1.6 why does the methylpropyl go in front of just the regular methyl? Doesn't methyl go first to make it 1-methyl-4-(1-methylpropyl)cyclohexane?
- Sun Mar 06, 2016 12:23 am
- Forum: *Alkanes and Substituted Alkanes (Staggered, Eclipsed, Gauche, Anti, Newman Projections)
- Topic: Eclipsed Conformation and Torsional Strain
- Replies: 1
- Views: 476
Eclipsed Conformation and Torsional Strain
So reviewig the kectures and my notes, I am wondering if their is a difference between torsional strain and an eclipsed conformation? An eclipsed conformation and torsional strain both relate to the highest energy state right, while staggered is the most stable?
- Sun Feb 28, 2016 9:34 pm
- Forum: *Alkanes
- Topic: Quiz 3 Preparation # 2
- Replies: 3
- Views: 536
Re: Quiz 3 Preparation # 2
Even if I ignore the t in trimethyl the e in ethyl comes before the m in methyl so shouldnt ethyl be named first?
- Sun Feb 28, 2016 8:53 pm
- Forum: *Alkanes
- Topic: Quiz 3 Preparation # 2
- Replies: 3
- Views: 536
Quiz 3 Preparation # 2
On the first Quiz 3 Preparation for number 2 why is it 2,2,4-trimethyl-3-ethylpentane instead of 3-ethyl-2,2,4-trimethylpentane. Also how do you detemine if the trimethyl has 2,2,4 instead of 2,4,4?
- Sat Feb 27, 2016 1:21 am
- Forum: *Alkanes
- Topic: Knowing Certain Common Names
- Replies: 1
- Views: 451
Knowing Certain Common Names
For benzene are we supposed to be able to know what it is based on memorization or is there a way to decipher it from its name alone? Additionally, are there other common names we should learn, whether they relate to alkanes or not?
- Sat Feb 20, 2016 1:55 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Standard Cell Potential Significant Figures on Midterm
- Replies: 3
- Views: 1175
Standard Cell Potential Significant Figures on Midterm
For the recent midterm on question 8 why is there three siginificant answers in the form of 1.20V when the two other cell standard cell potentials of .80V and -.40V only have 2 significant figures?
- Sun Feb 14, 2016 4:13 pm
- Forum: General Rate Laws
- Topic: Difference between rate of reaction and unique rate
- Replies: 2
- Views: 697
Difference between rate of reaction and unique rate
In the book I was trying to solve problems for the rate of reaction for number 3 and i assume the rate of reaction just deals with the reactant NO2, but was confused on what the unique rate of reaction referred to. Can anyone clarify the differences and how to find it?
- Sun Feb 07, 2016 4:16 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Clarification on 14.11a
- Replies: 1
- Views: 373
Clarification on 14.11a
In 14.11 a why is the sign standard cell potential for nickel remain -0.23 even though I reversed the half reaction from reduction to oxidation of nickel?
- Sat Feb 06, 2016 11:36 pm
- Forum: Balancing Redox Reactions
- Topic: Clarification on Oxidizing and Reduction Agents
- Replies: 2
- Views: 514
Clarification on Oxidizing and Reduction Agents
So, despite their names is the oxidizing agent the substance that is being reduced and vice-versa for the reducing agent? Basically they are the opposite of what their name implies.
- Sat Feb 06, 2016 9:49 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Clarification on Standard Cell Potential
- Replies: 1
- Views: 425
Clarification on Standard Cell Potential
Is the standard cell potential always positive or does it depend on whether you are undergoing reduction or oxidation? In the course reader on page 49 it says that Cu2+ and 2e- which makes Cu has a standard cell potential of .34V. Is there only a negative value if you switch the reactants and produc...
- Sat Jan 30, 2016 1:54 am
- Forum: Balancing Redox Reactions
- Topic: Oxidation of C2H2O4
- Replies: 1
- Views: 1760
Oxidation of C2H2O4
I was looking in the book and noticed that to oxidize C2H2O4 you need to identify the charges on the molecules. As far as I know C has a 4+ charge so why is it +3 on the left. Also once the oxidation takes place on the left it has a 4+ charge is there something I'm misssing?
- Sat Jan 23, 2016 6:41 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: 8.57 Clarification
- Replies: 2
- Views: 479
Re: 8.57 Clarification
Thanks I didn't see the c so I did not know it meant combustion.
- Sat Jan 23, 2016 6:14 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: 8.57 Clarification
- Replies: 2
- Views: 479
8.57 Clarification
In 8.57, in the textbook, to find the reaction enthalpy when given the final reaction, in this case the hydrogention of ethyne to ethane, how do we know how to get to that reaction with the use of other reactions. Do we always take the reactants and producta and combust them with O2?
- Sat Jan 23, 2016 6:08 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Typo in question 8.55?
- Replies: 2
- Views: 592
Re: Typo in question 8.55?
Yes because there is an Al2O3 as the product so adding a 3/2 to the O2 would balance the equation.
- Sat Jan 16, 2016 9:22 pm
- Forum: Calculating Work of Expansion
- Topic: Work equation
- Replies: 2
- Views: 853
Re: Work equation
If you are expanding a gas by a constant external pressure to match the positive difference in V you need to account for the loss in work by putting a negative sign in front of the equation.
- Sat Jan 16, 2016 9:01 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Clarification on Heat Capacity and Specific Heat Capacity
- Replies: 3
- Views: 859
Clarification on Heat Capacity and Specific Heat Capacity
So from my understanding heat capacity depends on the size of a sample right, for example, if we had a small and large piece of ice the heat capacity for the larger one would be higher since heat capacity is mass times specific heat capacity. However, I am also confused on how to determine specific ...
- Sun Jan 10, 2016 2:18 am
- Forum: Phase Changes & Related Calculations
- Topic: Explanation on State Properties
- Replies: 2
- Views: 613
Explanation on State Properties
What exactly is the criteria that differentiates whether something is considered a state property or not. Also, based on work and heat not being state properties can the explanation on them being classified so due to it, "depending on the path taken" be elaborated on.
- Thu Jan 07, 2016 10:07 pm
- Forum: Phase Changes & Related Calculations
- Topic: Enthalpy of Sublimation
- Replies: 3
- Views: 695
Re: Enthalpy of Sublimation
I'm pretty sure it relates to phase changes, such as water, in order for it to go from the liquid phase to gas phase it requires a certain amount of heat to go from liquid to vapor. Once enough heat is added the liquid can finally go to vapor and increase in temperature again as a vapor.
- Mon Nov 30, 2015 3:57 am
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: balanced reactions
- Replies: 2
- Views: 649
Re: balanced reactions
As far as I know whenever you are given a chemical equation you should always make sure that products and reactants are balanced since if you don't then calculations for equlibrium constant and such will be off.
- Sun Nov 15, 2015 11:48 pm
- Forum: Photoelectric Effect
- Topic: Photoelectric Effect Conservation of Energy
- Replies: 1
- Views: 496
Photoelectric Effect Conservation of Energy
On the midterm on question 3 I wrote out the photoelectric effect which is energy of photon- work fuction= excess energy of electron and got it wrong so does it have something to do with the mentioning of conservation of energy, if so what does it mean?
- Tue Nov 10, 2015 4:58 am
- Forum: *Molecular Orbital Theory (Bond Order, Diamagnetism, Paramagnetism)
- Topic: Video: Molecular Orbit Theory Review
- Replies: 2
- Views: 505
Video: Molecular Orbit Theory Review
I go over which MO diagram to use with examples, bond order, diamagnetism and paramagnetism, LUMO and HOMO, and molecular electron configuration.
- Mon Nov 09, 2015 2:26 pm
- Forum: Naming
- Topic: Naming in the Correct Order
- Replies: 1
- Views: 414
Re: Naming in the Correct Order
All I know is that the metal is written first in the chemical formula regardless, but the ligands are written first in alphabetical order when naming them so I would assume write them in alphabetical order as well when writing them out in the chemical formula.
- Wed Oct 28, 2015 4:06 am
- Forum: Electronegativity
- Topic: Determining Difference in Electronegativity
- Replies: 13
- Views: 1011
Determining Difference in Electronegativity
On page 75 of the course reader, it states that in order to be considered an ionic bond, heteronuclear atoms must have an electronegativity difference greater than two. How do we determine the values of electronegativity to determine if a bond should be considered ionic or covalent?
- Sun Oct 25, 2015 8:37 pm
- Forum: Octet Exceptions
- Topic: Octet Exception D-Orbitals
- Replies: 1
- Views: 399
Octet Exception D-Orbitals
So according to class lecture, an expanded octet is when an element can have more than 8 valence electrons after sharing electrons so is this rule only applicalble to those elements in the 13, 14, 15 , 16, 17, and 18th groups minus those in the 2nd period since they have an available d-orbital?
- Wed Oct 14, 2015 12:24 am
- Forum: Photoelectric Effect
- Topic: Fall 2013 Quiz Preperation Problem 10
- Replies: 4
- Views: 984
Re: Fall 2013 Quiz Preperation Problem 10
Why would I use 10.23 x 10^-19 if the least number of significant figures is 3 instead of 4?
- Mon Oct 12, 2015 1:08 am
- Forum: Photoelectric Effect
- Topic: Fall 2013 Quiz Preperation Problem 10
- Replies: 4
- Views: 984
Fall 2013 Quiz Preperation Problem 10
For the problem, it states if molybdenum is irradiated with light of wavelength of 194 nm, what is the maximum possible kinetic energy of the emitted electrons, based on problem 9 molybdenum must absorb radiation with a minimum frequency of 1.09 x 10^-15 s^-1 before it can emit an electron from its ...
- Sun Oct 04, 2015 5:37 pm
- Forum: Significant Figures
- Topic: How much of the atomic mass of an element should be used?
- Replies: 5
- Views: 1470
Re: How much of the atomic mass of an element should be used
So when using the mass of an electron for like calculating the kinetic energy of an ejected electron do we use the entire mass of 9.10938 x 10^-31 kg instead of rounding it to 9.11 x 10^-31 kg?
- Sat Oct 03, 2015 7:12 pm
- Forum: Significant Figures
- Topic: How much of the atomic mass of an element should be used?
- Replies: 5
- Views: 1470
How much of the atomic mass of an element should be used?
On page 31 of the course reader I've noticed that when calculating the mole of carbon atoms by dividing the grams of carbon given which was 40.9 g the grams per mole it was divided by was 12.01 instead of 12.011 which is given on the periodic table. Does it matter how much of the atomic mass you use...