Search found 13 matches

by anne_kleinaitis_3B
Wed Mar 02, 2016 1:02 pm
Forum: *Nucleophiles
Topic: Strength of Nucelophile
Replies: 3
Views: 668

Re: Strength of Nucelophile

It is a good nucleophile due to its size. See image
by anne_kleinaitis_3B
Wed Mar 02, 2016 12:18 pm
Forum: *Constitutional and Geometric Isomers (cis, Z and trans, E)
Topic: Drawing Constitutional and Geometric Isomers
Replies: 1
Views: 848

Re: Drawing Constitutional and Geometric Isomers

You likely won't be asked to draw all of the isomers, especially for very long chains... you will be asked to draw 3 or so. However, if is asked to "draw all isomers," follow these steps: THE FIVE STEPS FOR DRAWING ISOMERS: 1) Draw the main chain. 2) Draw the main chain minus 1 carbon, and...
by anne_kleinaitis_3B
Wed Feb 24, 2016 9:54 pm
Forum: *Free Energy of Activation vs Activation Energy
Topic: Symbols
Replies: 2
Views: 2705

Re: Symbols

if you mean the double dagger, it signifies the transition state:
by anne_kleinaitis_3B
Wed Feb 24, 2016 9:32 pm
Forum: *Free Energy of Activation vs Activation Energy
Topic: Activation Energy at Room Temperature
Replies: 1
Views: 2380

Re: Activation Energy at Room Temperature

"reactions with activation energies of less than 80 kj/mol take place at or below room temperature. reactions with higher activation energies often require heating to give the molecules enough energy to climb the activation barrier." thus, this reaction will not happen at room temperature;...
by anne_kleinaitis_3B
Tue Jan 26, 2016 6:12 pm
Forum: Concepts & Calculations Using Second Law of Thermodynamics
Topic: Which has more entropy?
Replies: 4
Views: 4035

Re: Which has more entropy?

since entropy is a measure of "disorder" or "randomness" in a system, more small molecules would have more entropy than few large molecules. for example, if you had 40 small molecules in a container, the 40 can rearrange themselves in hundreds of ways within container. if there w...
by anne_kleinaitis_3B
Wed Jan 20, 2016 10:08 pm
Forum: Thermodynamic Definitions (isochoric/isometric, isothermal, isobaric)
Topic: Enthalpy and Entropy
Replies: 3
Views: 882

Re: Enthalpy and Entropy

Enthalpy is a measure of heat content of the system, whereas entropy is the measure of change in (enthalpy/temperature). Enthalpy, H: H=U+PV heat content=internal energy + pressure*volume Entropy,S: deltaS=Q/T change in entropy=heat absorbed/temp essentially entropy measures disorder of molecules. A...
by anne_kleinaitis_3B
Thu Nov 19, 2015 1:44 pm
Forum: Naming
Topic: using bis, tris, tetrakis
Replies: 4
Views: 13267

Re: using bis, tris, tetrakis

Oxalato is bidentate which is a type of polydentate; if a ligand is polydentate, then bis, tris, tetrakis, etc are used.
by anne_kleinaitis_3B
Thu Nov 12, 2015 5:37 pm
Forum: Shape, Structure, Coordination Number, Ligands
Topic: chelates
Replies: 1
Views: 528

Re: chelates

A chelate is any metal that is attached to an anion (negatively charged group) with more than one attachment site.

It is a lengthy but doable process to identify a chelating ligand.
by anne_kleinaitis_3B
Fri Oct 30, 2015 4:30 pm
Forum: Properties of Light
Topic: Midterm 2010 #5 Strength of visible light
Replies: 1
Views: 591

Re: Midterm 2010 #5 Strength of visible light

UV light has wavelengths from 400 nm to 100 nm, and the given value is 344 nm. Thus it falls in the UV spectrum. Also, to pass a the threshold energy the wavelength must be shorter, not longer, because shorter wavelengths have more energy.
by anne_kleinaitis_3B
Fri Oct 30, 2015 4:20 pm
Forum: Hybridization
Topic: VSEPR Geometry
Replies: 2
Views: 2199

Re: VSEPR Geometry

MG: molecular geometry. EPG: electron pair geometry. Molecular geometry deals with the atoms attached to a central atom. Electron pair geometry deals with the atoms and the lone pairs attached to the central atom. Both types are considered zones of electron density, and both types create geometric s...
by anne_kleinaitis_3B
Mon Oct 26, 2015 7:29 pm
Forum: Lewis Structures
Topic: HCOOH
Replies: 1
Views: 949

HCOOH

(3.42) When I first attempted to draw a lewis structure for HCOOH, I put it in a linear structure, i.e. H-C-O-O-H. However, no matter where I put the bonds, I couldn't seem to get the right number of electrons. I had to google the molecule to see that it was H-C-O-H with an additional double bonded ...
by anne_kleinaitis_3B
Fri Oct 16, 2015 3:04 pm
Forum: Trends in The Periodic Table
Topic: Energy of Orbitals
Replies: 2
Views: 781

Re: Energy of Orbitals

I was confused on this topic too. This website explains in detail: http://chemwiki.ucdavis.edu/Inorganic_Chemistry/Electronic_Structure_of_Atoms_and_Molecules/Electronic_Configurations/The_Order_of_Filling_3d_and_4s_Orbitals"onclick="window.open(this.href);return false; Basically, 4s is let go first...
by anne_kleinaitis_3B
Sun Oct 04, 2015 10:28 pm
Forum: Photoelectric Effect
Topic: Photoelectric effect
Replies: 8
Views: 1296

Re: Photoelectric effect

short wavelengths have more energy, i.e. it has enough energy to "shake" the electron loose. alternatively, a longer wavelength carry less energy. at a certain point, the wavelength becomes too long (not enough energy) to "shake" the electron loose.

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