Search found 13 matches
- Wed Mar 02, 2016 1:02 pm
- Forum: *Nucleophiles
- Topic: Strength of Nucelophile
- Replies: 3
- Views: 668
Re: Strength of Nucelophile
It is a good nucleophile due to its size. See image
- Wed Mar 02, 2016 12:18 pm
- Forum: *Constitutional and Geometric Isomers (cis, Z and trans, E)
- Topic: Drawing Constitutional and Geometric Isomers
- Replies: 1
- Views: 848
Re: Drawing Constitutional and Geometric Isomers
You likely won't be asked to draw all of the isomers, especially for very long chains... you will be asked to draw 3 or so. However, if is asked to "draw all isomers," follow these steps: THE FIVE STEPS FOR DRAWING ISOMERS: 1) Draw the main chain. 2) Draw the main chain minus 1 carbon, and...
- Wed Feb 24, 2016 9:54 pm
- Forum: *Free Energy of Activation vs Activation Energy
- Topic: Symbols
- Replies: 2
- Views: 2705
Re: Symbols
if you mean the double dagger, it signifies the transition state:
- Wed Feb 24, 2016 9:32 pm
- Forum: *Free Energy of Activation vs Activation Energy
- Topic: Activation Energy at Room Temperature
- Replies: 1
- Views: 2380
Re: Activation Energy at Room Temperature
"reactions with activation energies of less than 80 kj/mol take place at or below room temperature. reactions with higher activation energies often require heating to give the molecules enough energy to climb the activation barrier." thus, this reaction will not happen at room temperature;...
- Tue Jan 26, 2016 6:12 pm
- Forum: Concepts & Calculations Using Second Law of Thermodynamics
- Topic: Which has more entropy?
- Replies: 4
- Views: 4035
Re: Which has more entropy?
since entropy is a measure of "disorder" or "randomness" in a system, more small molecules would have more entropy than few large molecules. for example, if you had 40 small molecules in a container, the 40 can rearrange themselves in hundreds of ways within container. if there w...
- Wed Jan 20, 2016 10:08 pm
- Forum: Thermodynamic Definitions (isochoric/isometric, isothermal, isobaric)
- Topic: Enthalpy and Entropy
- Replies: 3
- Views: 882
Re: Enthalpy and Entropy
Enthalpy is a measure of heat content of the system, whereas entropy is the measure of change in (enthalpy/temperature). Enthalpy, H: H=U+PV heat content=internal energy + pressure*volume Entropy,S: deltaS=Q/T change in entropy=heat absorbed/temp essentially entropy measures disorder of molecules. A...
- Thu Nov 19, 2015 1:44 pm
- Forum: Naming
- Topic: using bis, tris, tetrakis
- Replies: 4
- Views: 13267
Re: using bis, tris, tetrakis
Oxalato is bidentate which is a type of polydentate; if a ligand is polydentate, then bis, tris, tetrakis, etc are used.
- Thu Nov 12, 2015 5:37 pm
- Forum: Shape, Structure, Coordination Number, Ligands
- Topic: chelates
- Replies: 1
- Views: 528
Re: chelates
A chelate is any metal that is attached to an anion (negatively charged group) with more than one attachment site.
It is a lengthy but doable process to identify a chelating ligand.
It is a lengthy but doable process to identify a chelating ligand.
- Fri Oct 30, 2015 4:30 pm
- Forum: Properties of Light
- Topic: Midterm 2010 #5 Strength of visible light
- Replies: 1
- Views: 591
Re: Midterm 2010 #5 Strength of visible light
UV light has wavelengths from 400 nm to 100 nm, and the given value is 344 nm. Thus it falls in the UV spectrum. Also, to pass a the threshold energy the wavelength must be shorter, not longer, because shorter wavelengths have more energy.
- Fri Oct 30, 2015 4:20 pm
- Forum: Hybridization
- Topic: VSEPR Geometry
- Replies: 2
- Views: 2199
Re: VSEPR Geometry
MG: molecular geometry. EPG: electron pair geometry. Molecular geometry deals with the atoms attached to a central atom. Electron pair geometry deals with the atoms and the lone pairs attached to the central atom. Both types are considered zones of electron density, and both types create geometric s...
- Mon Oct 26, 2015 7:29 pm
- Forum: Lewis Structures
- Topic: HCOOH
- Replies: 1
- Views: 949
HCOOH
(3.42) When I first attempted to draw a lewis structure for HCOOH, I put it in a linear structure, i.e. H-C-O-O-H. However, no matter where I put the bonds, I couldn't seem to get the right number of electrons. I had to google the molecule to see that it was H-C-O-H with an additional double bonded ...
- Fri Oct 16, 2015 3:04 pm
- Forum: Trends in The Periodic Table
- Topic: Energy of Orbitals
- Replies: 2
- Views: 781
Re: Energy of Orbitals
I was confused on this topic too. This website explains in detail: http://chemwiki.ucdavis.edu/Inorganic_Chemistry/Electronic_Structure_of_Atoms_and_Molecules/Electronic_Configurations/The_Order_of_Filling_3d_and_4s_Orbitals"onclick="window.open(this.href);return false; Basically, 4s is let go first...
- Sun Oct 04, 2015 10:28 pm
- Forum: Photoelectric Effect
- Topic: Photoelectric effect
- Replies: 8
- Views: 1296
Re: Photoelectric effect
short wavelengths have more energy, i.e. it has enough energy to "shake" the electron loose. alternatively, a longer wavelength carry less energy. at a certain point, the wavelength becomes too long (not enough energy) to "shake" the electron loose.