## Search found 22 matches

Tue Mar 08, 2016 10:56 am
Topic: Electrophilic Addition vs SN2 and SN1
Replies: 1
Views: 668

### Re: Electrophilic Addition vs SN2 and SN1

For an electrophilic addition reaction, you start by breaking a double bond, and in the end you don't have the double bond.
Sat Mar 05, 2016 11:09 pm
Forum: *Alkanes and Substituted Alkanes (Staggered, Eclipsed, Gauche, Anti, Newman Projections)
Topic: Most stable confirmation?
Replies: 1
Views: 421

### Re: Most stable confirmation?

Each conformation corresponds to a different cycloalkane, butterfly (C4H8), envelope (C5H10), and chair (C6H12). Those are the most stable conformations for each respective cycloalkane, and the chair conformation is always more stable than boat for C6H12.
Sat Mar 05, 2016 11:04 pm
Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
Topic: Winter 2011 Final Q1A
Replies: 1
Views: 381

### Re: Winter 2011 Final Q1A

Water density is 1g/mL therefore 50mL of water is equivalent to 50g of water. It's also written on the equation sheet incase you ever forget.
Tue Mar 01, 2016 12:48 pm
Topic: Intermediates
Replies: 2
Views: 533

### Re: Intermediates

When asked how many intermediates there are in a reaction, is that asking how many valleys there are in a graph or how many molecules there are that act as intermediates?
Wed Feb 24, 2016 5:20 pm
Forum: *Cycloalkanes
Topic: Is cyclohexane the highest carbon ring?
Replies: 1
Views: 348

### Re: Is cyclohexane the highest carbon ring?

Cyclohexane is definitely not the highest carbon ring, I'm not sure what is but cyclooctane C8H16 is a molecule.
Wed Feb 17, 2016 2:45 pm
Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
Topic: midterm question of internal energy
Replies: 2
Views: 378

### Re: midterm question of internal energy

Constant temperature simply means that delta T=0 and therefore delta U=0. Heat transfer is not necessarily zero when delta T=0. For example, during a phase change the temperature stays constant but heat is still being absorbed or released.
Mon Feb 08, 2016 3:26 pm
Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
Topic: Hess' Law on Midterm 2011
Replies: 1
Views: 292

### Re: Hess' Law on Midterm 2011

The answer is -704kJ/mol because it is asking for the standard reaction enthalpy of anhydrous aluminum chloride which is measured in kJ/mol. The calculated answer is -1407.8kJ for 2 mols, so when you divide it by 2 and consider significant figures, the final answer is -704kJ/mol
Thu Feb 04, 2016 3:51 pm
Forum: Appications of the Nernst Equation (e.g., Concentration Cells, Non-Standard Cell Potentials, Calculating Equilibrium Constants and pH)
Topic: statements about E cell and E¤ cell
Replies: 1
Views: 369

### Re: statements about E cell and E¤ cell

E¤ doesn't change because it is an intensive property so it doesn't not depend on how much material there is. I think what the solutions manual means is that E cell cannot be calculated from K without knowing the value of E¤ first.
Mon Jan 25, 2016 3:43 pm
Forum: Gibbs Free Energy Concepts and Calculations
Topic: Quiz 1 Prep Winter 2014 #9
Replies: 5
Views: 845

### Re: Quiz 1 Prep Winter 2014 #9

You also need to multiply your deltaHf value by 2 because when you balance the equation there is 2HgO
Thu Jan 21, 2016 5:45 pm
Forum: Thermodynamic Systems (Open, Closed, Isolated)
Topic: Isolated System
Replies: 5
Views: 487

### Isolated System

Based on the first law of thermodynamics, can we assume that even after an infinite amount of time, ΔU in an isolated system is 0?
Sat Jan 16, 2016 3:46 pm
Forum: Concepts & Calculations Using First Law of Thermodynamics
Topic: Understanding q=-w
Replies: 2
Views: 448

### Re: Understanding q=-w

just to add, it means that the heat added to the system is being given off as work
Sat Jan 09, 2016 5:58 pm
Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
Topic: Sig figs and thermodynamics
Replies: 2
Views: 417

### Re: Sig figs and thermodynamics

yes, keep all the figures when doing the work but use correct significant figures for the final answer
Thu Dec 03, 2015 9:26 pm
Forum: Electron Configurations for Multi-Electron Atoms
Topic: Ground State Electron Configuration for Pd
Replies: 1
Views: 708

### Re: Ground State Electron Configuration for Pd

I think you mixed up Pb (lead) and Pd (Palladium)
Thu Dec 03, 2015 9:24 pm
Forum: Equilibrium Constants & Calculating Concentrations
Topic: Using Quadratic Formula vs Approximation
Replies: 1
Views: 369

### Re: Using Quadratic Formula vs Approximation

Im pretty sure its when Kc is smaller than 10^-4
Sat Nov 28, 2015 11:43 pm
Forum: Calculating pH or pOH for Strong & Weak Acids & Bases
Topic: Calculating pH and pOH
Replies: 1
Views: 381

### Calculating pH and pOH

In general, when calculating pH and pOH and using the ICE box, can we assume that the x in the denominator is 0 if Ka/Kb is a small value?
Wed Nov 18, 2015 4:36 pm
Forum: Shape, Structure, Coordination Number, Ligands
Topic: Polydentate and Lewis Structure
Replies: 4
Views: 747

### Re: Polydentate and Lewis Structure

The # of binding sites is the the same thing as the coordination #
Wed Nov 04, 2015 2:34 pm
Forum: Determining Molecular Shape (VSEPR)
Topic: Polar vs nonpolar
Replies: 3
Views: 495

### Re: Polar vs nonpolar

In general the only possible shapes that can be nonpolar are: linear, trigonal planar, tetrahedral, trigonal bipyramidal, octahedral and square planar, IF all the attached atoms are the same. If there are lone pairs or one or more different attached atoms, the structure is very likely to be polar.
Fri Oct 30, 2015 1:43 pm
Forum: Determining Molecular Shape (VSEPR)
Topic: ClO2+
Replies: 1
Views: 502

### Re: ClO2+

ClO2+ forms one double bond between Cl and O because it has doesn't have enough electrons. ClO2+ has a total of 18 electrons and the only way for all the atoms to fulfill the octet rule is if there is one double bond in the structure. The double bond can be on either O, therefore it also has resonan...
Sun Oct 25, 2015 10:48 pm
Forum: Lewis Structures
Topic: Lewis structure of chlorine monoxide, ClO
Replies: 2
Views: 3377

### Re: Lewis structure of chlorine monoxide, ClO

If you take electronegativity into consideration, O has an electronegativity of 3.5 whereas Cl has an electronegativity of 3.0. Therefore, it could be that it is more important for O to fill its octet and leave Cl with a lone electron. Then again, we might not need to take this into consideration yet.
Thu Oct 15, 2015 3:57 pm
Forum: Empirical & Molecular Formulas
Topic: Calculating molecular formula
Replies: 1
Views: 305

### Re: Calculating molecular formula

If your answer is close enough to a whole number and the rest of your answers seem correct to you, you should be safe to round up/down and not have to worry too much about it.
Sun Oct 11, 2015 8:36 pm
Forum: Limiting Reactant Calculations
Topic: Quiz 1 Preparation #2
Replies: 1
Views: 1608

### Re: Quiz 1 Preparation #2

Since the ratio of HCl to AlCl3 is 3 to 1, you would first divide .213mol by 3 before multiplying it by the molar mass of AlCl3, and your answer would be about 9.5g of AlCl3
Sun Oct 04, 2015 2:04 pm
Forum: Limiting Reactant Calculations
Topic: The equations from fundamentals until now...
Replies: 1
Views: 428

### Re: The equations from fundamentals until now...

I think the best way to approach any problem in chemistry is to first figure out what you are given and then second figure out what you are trying to find. This way, even when we are confused we can use deductive reasoning to narrow down our equation choices. As for all the equations, they might see...

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