Search found 33 matches
- Sat Mar 12, 2016 8:04 pm
- Forum: *Free Energy of Activation vs Activation Energy
- Topic: Rate constant and Ea
- Replies: 1
- Views: 381
Rate constant and Ea
Why does change in rate constant have no effect on activation energy? In the course reader, it says that catalyst speeds up the reaction (K) by lowering the Ea.
- Sun Mar 06, 2016 11:33 pm
- Forum: *Alkenes
- Topic: Vinyl substituent
- Replies: 2
- Views: 520
Vinyl substituent
We learned how to draw vinyl as a parent chain but how is it supposed to look like as a substituent?
- Sun Feb 28, 2016 8:43 pm
- Forum: *Alkanes
- Topic: 4-ethyl-2,2-dimethyl-hexane
- Replies: 1
- Views: 390
4-ethyl-2,2-dimethyl-hexane
In the course reader, why is it 4-ethyl-2,2-dimethyl-hexane instead of 3-ethyl-5,5-dimethyl-hexane? why does it not follow the "1st named group gets lower number" rule? I know the course reader says "#chain to give lowest # to substituents". Does that mean since theres 2 methyl b...
- Sun Feb 28, 2016 2:33 pm
- Forum: *Nucleophiles
- Topic: Neutral element
- Replies: 1
- Views: 484
Neutral element
Are all elements (excluding noble gas) are electrophiles if they are not negatively charged? For example C is electrophile but Carbon ion is nucleophile?
- Sat Feb 13, 2016 7:05 pm
- Forum: Kinetics vs. Thermodynamics Controlling a Reaction
- Topic: Energetically favorable
- Replies: 1
- Views: 7986
Energetically favorable
What is energetically favorable and is it the same thing with being exothermic?
Does a energetically favorable reaction not be spontaneous?
Does a energetically favorable reaction not be spontaneous?
- Sat Feb 13, 2016 6:25 pm
- Forum: Second Order Reactions
- Topic: workbook quiz2 preparation winter 2014 question.
- Replies: 2
- Views: 504
workbook quiz2 preparation winter 2014 question.
I have 2 questions from workbook quiz2 preparation winter 2014. #10 from it asks what is the activation energy for the reaction based on the K value that we have. Are we supposed to know how to do that for quiz2? If we do, please teach me #12, it tells you to graph the data, find the slope and get t...
- Sat Feb 13, 2016 4:14 pm
- Forum: First Order Reactions
- Topic: HW question 15.37
- Replies: 1
- Views: 412
HW question 15.37
Why does HW question 15.37 C) not require the volume in the calculation? Do we not have to calculate the molarity?
- Fri Feb 12, 2016 7:11 pm
- Forum: Second Order Reactions
- Topic: Half life equations
- Replies: 1
- Views: 378
Half life equations
Are we supposed to know how to derive all these integrated rate law equations and half life equations?
- Mon Feb 08, 2016 10:57 pm
- Forum: Concepts & Calculations Using First Law of Thermodynamics
- Topic: internal heat change of monotomic ideal gas
- Replies: 2
- Views: 496
internal heat change of monotomic ideal gas
does " ΔU=3/2RT" only apply to monotomic ideal gas?
- Fri Feb 05, 2016 6:10 pm
- Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
- Topic: Salt bridge
- Replies: 1
- Views: 325
Salt bridge
How exactly does the salt bridge prevent one side getting to postitive and another getting too negative? What is the detailed process?
- Sun Jan 31, 2016 4:38 pm
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: Delta G
- Replies: 1
- Views: 351
Delta G
Why is delta G= W max at constant T and P?
- Wed Jan 27, 2016 11:43 pm
- Forum: Calculating Standard Reaction Entropies (e.g. , Using Standard Molar Entropies)
- Topic: Textbook question 9.35
- Replies: 1
- Views: 330
Textbook question 9.35
Container A is fi lled with 1.0 mol of the atoms of an ideal monatomic gas. Container B has 1.0 mol of atoms bound together as diatomic molecules that are not vibrationally active. Container C has 1.0 mol of atoms bound together as diatomic molecules that are vibrationally active. The containers all...
- Tue Jan 26, 2016 7:17 pm
- Forum: Calculating Work of Expansion
- Topic: Textbook question clarification
- Replies: 2
- Views: 418
Textbook question clarification
There was a textbook question asking "Calculate the change in molar entropy of an ideal gas when it is compressed isothermally to one-third its initial volume. " Is ideal gas implaying that is 1 mol of gas? How do we know the mole of gas
- Tue Jan 26, 2016 7:15 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Textbook question
- Replies: 3
- Views: 550
Re: Textbook question
Water expands when it freezes. How much work does 100. g of water do when it freezes at 0.0 C and pushes back the metal wall of a pipe that exerts an opposing pressure of 1070 atm? The densities of water and ice at 0.0 C are 1.00 gcm3 and 0.92 gcm3, respectively. The textbook answer is -0.86KJ.
- Tue Jan 26, 2016 12:49 am
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Textbook question
- Replies: 3
- Views: 550
Textbook question
Is there something wrong with textbook question 8.1A Selftest on page264? Because I feel like the answer multiplied the mass by the density not dividing by the density
- Sun Jan 17, 2016 4:24 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Reversible and irreversible
- Replies: 2
- Views: 507
Reversible and irreversible
What is the exact difference of reversible process and irreversible process and why does reversible process always has more work done?
- Sat Jan 09, 2016 12:40 am
- Forum: Phase Changes & Related Calculations
- Topic: Heat
- Replies: 1
- Views: 327
Heat
Why is the heat equation always negative? Or is it only when it is releasing energy
- Tue Dec 01, 2015 12:53 am
- Forum: *Molecular Orbital Theory (Bond Order, Diamagnetism, Paramagnetism)
- Topic: Br2 2+
- Replies: 1
- Views: 521
Br2 2+
In one of the course reader practice final exam, it says Br2 2+ is diamagnetic. But it is supposed to be paramagnetic right?
- Thu Nov 26, 2015 10:34 pm
- Forum: Calculating the pH of Salt Solutions
- Topic: Hw question 77
- Replies: 1
- Views: 386
Hw question 77
Do we have to know the calculation involved Ka1 and ka2?
- Thu Nov 26, 2015 10:32 pm
- Forum: Calculating the pH of Salt Solutions
- Topic: AlCl3
- Replies: 3
- Views: 656
Re: AlCl3
Is it in the textbook?
- Thu Nov 26, 2015 8:04 pm
- Forum: Calculating the pH of Salt Solutions
- Topic: AlCl3
- Replies: 3
- Views: 656
AlCl3
For question 69 b), where do you get the Ka of Al3+
- Thu Nov 26, 2015 7:17 pm
- Forum: Lewis Acids & Bases
- Topic: SO2
- Replies: 2
- Views: 855
SO2
Why is SO2 a lewis acid. Apparently it can accept an electron pair, but why and how?
- Mon Nov 23, 2015 11:29 pm
- Forum: Identifying Acidic & Basic Salts
- Topic: Exceptions of anions
- Replies: 2
- Views: 499
Exceptions of anions
Why were HSO4- and H2PO4- exceptions from anions making solution basic again?
- Mon Nov 23, 2015 8:58 pm
- Forum: Calculating pH or pOH for Strong & Weak Acids & Bases
- Topic: Strength of acidity
- Replies: 1
- Views: 405
Strength of acidity
It is said that longer the A-H bond, more acidic it is. That means HI is more acidic than HCl due to the bigger size of Iodine that causese longer bond. However, second property was depedent on electronegativity, and examples were given so that CL-O-H is more acidic than I-O-H. Doesnt this contradic...
- Wed Nov 18, 2015 4:10 pm
- Forum: Equilibrium Constants & Calculating Concentrations
- Topic: Significant figure
- Replies: 1
- Views: 310
Significant figure
Hi i was confused between how to apply sigfig rules Basically if we look at the textbook question 11.57, the solution manual uses the intermediate sigfig which means it rounds up for the addition part. However, thats not how i learned in highschool and i was really confused. Do we round up the sigfi...
- Sun Nov 08, 2015 6:13 pm
- Forum: Shape, Structure, Coordination Number, Ligands
- Topic: name of iron
- Replies: 2
- Views: 382
name of iron
I realized that some of the question use the name "iron" when naming coordinate compounds and some of others use "ferrate". How do we know when to use what
- Thu Oct 29, 2015 12:30 pm
- Forum: Resonance Structures
- Topic: SO4 2-
- Replies: 1
- Views: 5792
SO4 2-
Sulfate ion has two ways of drawing its lewis structure. One is to follow the octet rule and having single bond for each oxygen each perfectly satisfies the octet rule. However, since sulfate can hold more than 8 electrons, it is better to draw the lewis structure with 2 double bond oxygens and 2 si...
- Thu Oct 29, 2015 1:19 am
- Forum: *Molecular Orbital Theory (Bond Order, Diamagnetism, Paramagnetism)
- Topic: CO mo diagram
- Replies: 1
- Views: 239
CO mo diagram
Hi, in lecture, Dr. Lavelle said that 2p and 2s orbitals of Carbon is higher than those of oxygen. Why? I did not catch what he said.
- Sun Oct 25, 2015 12:19 am
- Forum: Dipole Moments
- Topic: polarizability in ionic model
- Replies: 1
- Views: 353
polarizability in ionic model
It is said that highly distorted electron in atoms and ions are highly polarizable and that result in more covalent caracter. Why? isnt it supposed to be have more ionic ?
- Fri Oct 16, 2015 8:26 pm
- Forum: Octet Exceptions
- Topic: Octet Exception (Course Reader)
- Replies: 1
- Views: 455
Re: Octet Exception (Course Reader)
Hi Nick. Beryllium chloride has a linear shape and beryllium is an octet exception because beryllium ion loses an electron when it forms bond, and that means it has the same electron configuration as Helium, which is a duplet instead of an octet.
- Fri Oct 09, 2015 8:50 pm
- Forum: Electron Configurations for Multi-Electron Atoms
- Topic: Unpaired Electron
- Replies: 2
- Views: 1789
Re: Unpaired Electron
OMG sorry i was really dumb, this time i figured out. So basically u gotta write down the electron configuration and see. For example, if it is asking for unpaired electron of silicon, silicon's electron configuration is [Ne]3s2 3p2. According to Hund's rule, due to electron repulsion, electron in s...
- Fri Oct 09, 2015 7:02 pm
- Forum: Electron Configurations for Multi-Electron Atoms
- Topic: Unpaired Electron
- Replies: 2
- Views: 1789
Re: Unpaired Electron
Hi, you look at the periodic table and see which group it belongs to. For example, if you look at Berylium, its on the group 2, so it has 2 out of 8 electron, which means 8-2=6. so 6 unpaired elctrons. If you look at Oxygen, it is technically in group 16, but you need to ignore the d block which is ...
- Fri Oct 09, 2015 6:56 pm
- Forum: Electron Configurations for Multi-Electron Atoms
- Topic: Electron configuration for Thorium
- Replies: 1
- Views: 1388
Electron configuration for Thorium
Apparently, electron configuration for Thorium is [Rn] 6d2 7s2. However, I thought it would be [Rn] 5f1 6d1 7s2 since its on the F block right after the first 6d element (Actinium). Help!