Search found 10 matches

by nickrodgers
Sat Mar 18, 2017 10:30 pm
Forum: Appications of the Nernst Equation (e.g., Concentration Cells, Non-Standard Cell Potentials, Calculating Equilibrium Constants and pH)
Topic: Galvanic cell calculations
Replies: 2
Views: 263

Re: Galvanic cell calculations

I'm pretty sure it's the concentration of aqueous products over aqueous reactants.
by nickrodgers
Sat Mar 18, 2017 10:18 pm
Forum: Galvanic/Voltaic Cells, Calculating Standard Cell Potentials, Cell Diagrams
Topic: Number 5B from 2015 Final
Replies: 2
Views: 306

Re: Number 5B from 2015 Final

I assume we'll be given the electric potentials of the relevant half reactions, or else I don't see how it's possible to do this. In that case, the one with the more positive electric potential is the stronger reducing agent and the one with the more negative electric potential is the oxidizing agent.
by nickrodgers
Sat Mar 18, 2017 10:11 pm
Forum: *Cyclohexanes (Chair, Boat, Geometric Isomers)
Topic: Bonds
Replies: 4
Views: 503

Re: Bonds

I'm pretty sure the equatorial bonds are always horizontal and axial are vertical, right? Is there anymore to it?
by nickrodgers
Sat Mar 18, 2017 10:05 pm
Forum: Third Law of Thermodynamics (For a Unique Ground State (W=1): S -> 0 as T -> 0) and Calculations Using Boltzmann Equation for Entropy
Topic: Final 2011 #1c
Replies: 1
Views: 364

Re: Final 2011 #1c

I would guess that it's because NO can be oriented in two states (N-O and O-N) while BF3 can only be oriented in one state.
Since entropy is proportional to W, and W = (# of possible states)^(# of particles), NO would have higher residual entropy
by nickrodgers
Sat Mar 18, 2017 9:54 pm
Forum: *Cyclohexanes (Chair, Boat, Geometric Isomers)
Topic: 2014 Midterm Q7 E & F
Replies: 1
Views: 392

Re: 2014 Midterm Q7 E & F

The lowest energy Newman diagram is when the largest groups are farthest apart. CN and C(OH)3 are the two largest groups (nitrogen atom is larger than 3 hydrogen atoms) so the lowest energy diagram will be when they are in anti-conformation.
by nickrodgers
Sat Mar 18, 2017 9:49 pm
Forum: *Constitutional and Geometric Isomers (cis, Z and trans, E)
Topic: When to use Isomers
Replies: 1
Views: 426

Re: When to use Isomers

You use cis and trans in order to specify the shape/orientation of the molecule when there are multiple substituents. Cis means they are on the same side of the longest carbon chain and trans means they're on opposite sides.
by nickrodgers
Sat Mar 11, 2017 11:24 pm
Forum: *Alkanes
Topic: Naming Help
Replies: 7
Views: 693

Re: Naming Help

If there are two substituents on the cycloalkane then the substituent with the earlier name alphabetically is given the first number. If there are more than two substituents, then alphabetical naming is irrelevant to the numbering (only to the name) and the numbers are arranged so that the possible ...
by nickrodgers
Fri Mar 03, 2017 6:43 pm
Forum: Arrhenius Equation, Activation Energies, Catalysts
Topic: Quiz 3 [ENDORSED]
Replies: 14
Views: 933

Re: Quiz 3 [ENDORSED]

Riley Seid 1L wrote:Quiz 3 will include kinetics??


Dr Lavelle said that the last couple sections of kinetics will be on it. He posted exactly what's covered in another post.
by nickrodgers
Fri Mar 03, 2017 6:40 pm
Forum: Administrative Questions and Class Announcements
Topic: Quiz 3 Winter 2017
Replies: 183
Views: 15481

Re: Quiz 3 Winter 2017

How many questions will there be on Quiz 3?

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