Search found 23 matches
- Sun Mar 12, 2017 6:23 pm
- Forum: *Cycloalkanes
- Topic: Cyclo-
- Replies: 7
- Views: 2302
Re: Cyclo-
For cycloalkanes,You look at the numbering for the lowest number on substituents, and if they are equal, you number based on first named.
- Sun Mar 12, 2017 6:20 pm
- Forum: *Alkenes
- Topic: Naming what carbon the double/triple bond is on?
- Replies: 2
- Views: 653
Re: Naming what carbon the double/triple bond is on?
When naming the double and triple bonds, you number the bond based on which carbon it starts on.
- Wed Mar 08, 2017 10:36 am
- Forum: *Alkanes
- Topic: Iso and Neo Prefixes
- Replies: 5
- Views: 1324
Re: Iso and Neo Prefixes
I believe the prefix iso- is not restricted to 4 or less carbons, and you can tell when it is used when the line structure has a branch of CH(CH3)2
- Wed Mar 08, 2017 10:34 am
- Forum: General Science Questions
- Topic: Types of energy profiles
- Replies: 5
- Views: 1354
Re: Types of energy profiles
The potential energy profile is generally used by physical chemist's and refer to activation energy, while the free energy profile is generally used by organic chemists.
- Wed Mar 08, 2017 10:32 am
- Forum: *Free Energy of Activation vs Activation Energy
- Topic: Catalysts and Entropy
- Replies: 3
- Views: 1479
Re: Catalysts and Entropy
I believe that entropy is less negative because by putting the molecules in the correct order and orientation, there is greater facilitation to the reaction occurring, which leads to more entropy.
- Fri Feb 24, 2017 5:54 pm
- Forum: First Order Reactions
- Topic: Slope of k
- Replies: 3
- Views: 978
Re: Slope of k
For zero and first order reactions, the slope = -k. For second order reactions, the slope = +k.
- Tue Feb 14, 2017 9:27 am
- Forum: Work, Gibbs Free Energy, Cell (Redox) Potentials
- Topic: how to calculate n correctly
- Replies: 4
- Views: 2552
Re: how to calculate n correctly
For n, the moles of e-, does it have a unit, or is it just the number. For example, in deltaG=-nFE, if F is C/mol and E is J/C, is the n units mol so that delta G is J or is does the n have no units so that delta G =J/mol?
- Tue Feb 14, 2017 9:23 am
- Forum: Balancing Redox Reactions
- Topic: Balancing equations
- Replies: 10
- Views: 1740
Re: Balancing equations
General polyatomic ions such as NO3-, SO42-, will need to be known, as well as common charges such as O2-, H1+, and 1+ charges for alkali metals.
- Wed Feb 01, 2017 2:29 pm
- Forum: Entropy Changes Due to Changes in Volume and Temperature
- Topic: Change in entropy= q/T [ENDORSED]
- Replies: 3
- Views: 762
Re: Change in entropy= q/T [ENDORSED]
Since the change in entropy is equated by q/T, as T increases, the overall change in entropy is decreasing if the heat (q) remains the same.
- Wed Jan 25, 2017 11:55 pm
- Forum: Gibbs Free Energy Concepts and Calculations
- Topic: Gibbs v internal
- Replies: 1
- Views: 520
Re: Gibbs v internal
U stands for internal energy, and delta U stands for the change in internal energy, which can be calculated by delta U = q + w. G is for Gibbs Free Energy, and delta G stands for the change in free energy of a system, which can help determine the spontaneity and favorability of a reaction. There are...
- Sat Jan 21, 2017 7:19 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: kJ vs. kJ/mol [ENDORSED]
- Replies: 1
- Views: 431
Re: kJ vs. kJ/mol [ENDORSED]
Generally, the standard enthalpy of formation is in kJ/mol, and for the standard enthalpy of reaction, answers are generally kJ. You can determine the kJ/mol for standard enthalpy of reaction by looking at the chemical equation.
- Sun Jan 15, 2017 8:16 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Specific heat capacity [ENDORSED]
- Replies: 2
- Views: 827
Re: Specific heat capacity [ENDORSED]
In a reaction, anytime a bond is formed, it is an exothermic reaction. This is because energy is released when the bonds are formed. To express that the reaction is exothermic, the delta H is negative. In a perfect system where qsys =- qsurr, this equation is derived from the 1st Law of Thermodynami...
- Wed Nov 30, 2016 11:38 am
- Forum: Identifying Acidic & Basic Salts
- Topic: Identifying a salt
- Replies: 4
- Views: 1258
Re: Identifying a salt
So looking at NH4Cl, we have the cation NH4+ and anion Cl-. In a solution, the concentration of Cl- does not change, nor does it affect the pH of the solution. However, NH4+ is a weak acid, and so it will want to react with the water molecules to form NH3 (the more stable molecular form), and H3O+.
- Sun Nov 27, 2016 11:58 pm
- Forum: Lewis Acids & Bases
- Topic: How to determine which is an acid and which is a base?
- Replies: 5
- Views: 1279
Re: How to determine which is an acid and which is a base?
Given NH3 (aq), by memorizing the strong/weak acids and bases, we know that NH3 is a weak base. The lone pair on the nitrogen will bond with neighboring hydrogens from the H2O to form conjugate acid NH4+ and conjugate base OH-.
- Sun Nov 20, 2016 11:41 pm
- Forum: Non-Equilibrium Conditions & The Reaction Quotient
- Topic: Reaction Quotient Less than or Greater than 1 [ENDORSED]
- Replies: 3
- Views: 6763
Re: Reaction Quotient Less than or Greater than 1 [ENDORSED]
Q is the reaction quotient, which measures which direction a reaction will proceed given the initial partial pressures or concentrations. K is the equilibrium constant, which is a ration of products to reactants that does not change for the same reactions under the same conditions.
- Wed Nov 16, 2016 10:49 pm
- Forum: Naming
- Topic: Alphabetizing Ligands
- Replies: 4
- Views: 926
Re: Alphabetizing Ligands
For the formula, as long as you put the transition metal first, the ligands can be put in any order following the metal.
- Mon Nov 14, 2016 3:35 pm
- Forum: Naming
- Topic: Trans and Cis
- Replies: 3
- Views: 858
Re: Trans and Cis
An example would be the one we saw in class, where cis-diamminedichloroplatinum has the chlorides both on the left, whereas the trans-diamminedichloroplatinum has the chlorides located on opposite sides of each other.
- Sat Nov 05, 2016 3:35 pm
- Forum: Properties of Light
- Topic: Balmer and Lyman Series [ENDORSED]
- Replies: 4
- Views: 1350
Re: Balmer and Lyman Series [ENDORSED]
The principal quantum number is an integer that describes the energy level of the electron. As n increases, the number of electronic shells increases and the electron is further from the nucleus and therefore has a higher energy. To compute n, we can utilize Rydberg's equation given the energy: En=-...
- Tue Oct 25, 2016 10:30 am
- Forum: Dipole Moments
- Topic: Dipole Moment in a Lewis Structure
- Replies: 5
- Views: 2169
Re: Dipole Moment in a Lewis Structure
With the arrow showing us the delta positive pole and delta negative pole, we can determine which atom in the molecule has a higher electronegativity than the other, and will pull the shared electrons closer when sharing.
- Tue Oct 18, 2016 11:38 am
- Forum: Ionic & Covalent Bonds
- Topic: The Octet
- Replies: 3
- Views: 955
Re: The Octet
Elements that are exceptions to the octet rule include P, S, Cl. This is because they are located in period 3 on the periodic table, meaning that they have l= 0,1,2. This corresponds to the s, p, and d orbitals. Hence, in their valence shell, they have d-orbitals that can accomadate additional e-. T...
- Sat Oct 15, 2016 1:13 am
- Forum: DeBroglie Equation
- Topic: Neutrons
- Replies: 4
- Views: 1024
Re: Neutrons
In fact, all matter has wavelike properties. However, only those with small mass and high velocity have wavelike properties that could be detected. For everyday objects such as baseballs, it is difficult to detect the wavelike properties.
- Tue Oct 04, 2016 1:03 pm
- Forum: Properties of Electrons
- Topic: Energy Level Model [ENDORSED]
- Replies: 2
- Views: 886
Re: Energy Level Model [ENDORSED]
When the energy of a photon matches the energy difference between quantum levels, (which are represented by the lines shown in the model below), electrons will get excited and move to the next level. The arrows are pointing downwards as the model is showing the emission of energy as electrons return...
- Wed Sep 28, 2016 11:58 am
- Forum: Significant Figures
- Topic: Easy Way to Calculate Sigfigs
- Replies: 6
- Views: 1557
Re: Easy Way to Calculate Sigfigs
Yes, if there is a decimal, you would count the non-zero digits as sig figs. For example, 300. would be 3 sig figs. In cases such as numbers like 0.00500 however, since the preceding zeroes are simply place holders to put decimals in the correct location, the only numbers that are counted as sig fig...