Search found 12 matches

by Jamie_Cole_2N
Mon Mar 20, 2017 12:11 pm
Forum: *Cyclohexanes (Chair, Boat, Geometric Isomers)
Topic: Most stable confirmation? [ENDORSED]
Replies: 4
Views: 4611

Re: Most stable confirmation? [ENDORSED]

So, is trans- more stable in this case?
by Jamie_Cole_2N
Sun Mar 19, 2017 11:49 pm
Forum: *Cyclohexanes (Chair, Boat, Geometric Isomers)
Topic: Most stable confirmation? [ENDORSED]
Replies: 4
Views: 4611

Most stable confirmation? [ENDORSED]

For a chair conformation of cyclohexane, with IUPAC name either cis- or trans- 1,4-dimethylcyclohexane, which confirmation is the most stable? And adding the methyls to two axials H's, two equatorial H's, or one axial and one equatorial would be more stable?
by Jamie_Cole_2N
Sat Mar 18, 2017 9:33 pm
Forum: Concepts & Calculations Using Second Law of Thermodynamics
Topic: Higher Residual Entropy
Replies: 1
Views: 519

Higher Residual Entropy

Why would NO have a higher residual entropy than BF3?
by Jamie_Cole_2N
Sun Mar 12, 2017 10:15 pm
Forum: *Alkanes and Substituted Alkanes (Staggered, Eclipsed, Gauche, Anti, Newman Projections)
Topic: Cis & Trans
Replies: 3
Views: 740

Re: Cis & Trans

A tip to remember that Z stands for same side (cis) is "Zee Groups are on Zee Zame Zide."
At least as far as I know, the reason trans is E and cis is Z wasn't explicitly stated in lecture, but this trick will be helpful in remembering Z stands for cis!
by Jamie_Cole_2N
Sun Mar 05, 2017 11:29 pm
Forum: *Organic Reaction Mechanisms in General
Topic: Nucleophile strength
Replies: 2
Views: 650

Nucleophile strength

What properties about being nucleophiles make one stronger than the other, I understand how an ion with a larger source of electrons available (and higher polarizability) but how could we explain other examples like why H2O is not stronger than OH- when the book mentions there is only "some cor...
by Jamie_Cole_2N
Wed Mar 01, 2017 11:20 am
Forum: General Science Questions
Topic: Homework Problem 4.38d
Replies: 2
Views: 697

Re: Homework Problem 4.38d

Yeah it does, thank you. I couldn't remember the rule. I was reviewing my 14A material (this is textbook question 4.38d)
by Jamie_Cole_2N
Thu Feb 23, 2017 5:28 pm
Forum: General Science Questions
Topic: Homework Problem 4.38d
Replies: 2
Views: 697

Homework Problem 4.38d

For CH3NNN there are 3 resonance structures (I believe)
So, would we use the resonance structure which yields the largest hybridization as the answer, or how would we know which hybridization is correct without being given information about which resonance form the molecule is in?
by Jamie_Cole_2N
Tue Feb 14, 2017 12:53 pm
Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
Topic: Winter 2014 Q3B
Replies: 1
Views: 441

Winter 2014 Q3B

The question asks for the specific heat capacity of Squirtle's shell in KJ/ ((degrees C)* g) and for specific heat capacity the equation q = (m*C*(deltaT)) gives an answer in KJ/ ((degrees C)* g): My question is, why we don't we use 2500 degrees C for finding the specific heat capacity in this probl...
by Jamie_Cole_2N
Sun Feb 12, 2017 8:42 pm
Forum: Balancing Redox Reactions
Topic: Balancing on acidic vs basic solutions
Replies: 1
Views: 429

Re: Balancing on acidic vs basic solutions

For an acidic solution, you balance using H2O and H+ But with basic solution, you balance with H2O and OH- Basic solutions definitely require you to be more careful. You can still use H+ when solving, but keep in mind you must multiply by the same amount of OH- on both sides to cancel the H+'s For e...
by Jamie_Cole_2N
Sun Feb 05, 2017 9:08 pm
Forum: Balancing Redox Reactions
Topic: 14.17
Replies: 2
Views: 537

Re: 14.17

Potassium permanganate reacts with iron(II) chloride according to the following oxidation-reduction half-reactions: MnO4-(aq) + 8H+(aq) + 5e- ---> Mn2+(aq) + 4H2O (cathode reduction half-reaction) You first add the amount of H2O needed to balance the O's in the MnO4- portion, then add H+ that equal ...
by Jamie_Cole_2N
Sun Jan 29, 2017 10:37 pm
Forum: Phase Changes & Related Calculations
Topic: Reversible Reactions
Replies: 3
Views: 861

Re: Reversible Reactions

Reversible reactions can be reversed by infinitely small changes in a variable. For changes in pressure, Pex must ALWAYS be infinitesimally different from the pressure of the system. For a change in temperature, the temperature of the system must change by a series of infinitely small amounts of hea...
by Jamie_Cole_2N
Sun Jan 22, 2017 10:50 pm
Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
Topic: Standard Enthalpy of Formation Course Reader example
Replies: 1
Views: 462

Standard Enthalpy of Formation Course Reader example

On page 17 of the course reader, there is a standard enthalpy of formation example about using graphite and gaseous hydrogen and oxygen to form ethanol,
Why is the enthalpy of reaction divided by 2?

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