Search found 12 matches
- Mon Mar 20, 2017 12:11 pm
- Forum: *Cyclohexanes (Chair, Boat, Geometric Isomers)
- Topic: Most stable confirmation? [ENDORSED]
- Replies: 4
- Views: 4611
Re: Most stable confirmation? [ENDORSED]
So, is trans- more stable in this case?
- Sun Mar 19, 2017 11:49 pm
- Forum: *Cyclohexanes (Chair, Boat, Geometric Isomers)
- Topic: Most stable confirmation? [ENDORSED]
- Replies: 4
- Views: 4611
Most stable confirmation? [ENDORSED]
For a chair conformation of cyclohexane, with IUPAC name either cis- or trans- 1,4-dimethylcyclohexane, which confirmation is the most stable? And adding the methyls to two axials H's, two equatorial H's, or one axial and one equatorial would be more stable?
- Sat Mar 18, 2017 9:33 pm
- Forum: Concepts & Calculations Using Second Law of Thermodynamics
- Topic: Higher Residual Entropy
- Replies: 1
- Views: 519
Higher Residual Entropy
Why would NO have a higher residual entropy than BF3?
- Sun Mar 12, 2017 10:15 pm
- Forum: *Alkanes and Substituted Alkanes (Staggered, Eclipsed, Gauche, Anti, Newman Projections)
- Topic: Cis & Trans
- Replies: 3
- Views: 740
Re: Cis & Trans
A tip to remember that Z stands for same side (cis) is "Zee Groups are on Zee Zame Zide."
At least as far as I know, the reason trans is E and cis is Z wasn't explicitly stated in lecture, but this trick will be helpful in remembering Z stands for cis!
At least as far as I know, the reason trans is E and cis is Z wasn't explicitly stated in lecture, but this trick will be helpful in remembering Z stands for cis!
- Sun Mar 05, 2017 11:29 pm
- Forum: *Organic Reaction Mechanisms in General
- Topic: Nucleophile strength
- Replies: 2
- Views: 650
Nucleophile strength
What properties about being nucleophiles make one stronger than the other, I understand how an ion with a larger source of electrons available (and higher polarizability) but how could we explain other examples like why H2O is not stronger than OH- when the book mentions there is only "some cor...
- Wed Mar 01, 2017 11:20 am
- Forum: General Science Questions
- Topic: Homework Problem 4.38d
- Replies: 2
- Views: 697
Re: Homework Problem 4.38d
Yeah it does, thank you. I couldn't remember the rule. I was reviewing my 14A material (this is textbook question 4.38d)
- Thu Feb 23, 2017 5:28 pm
- Forum: General Science Questions
- Topic: Homework Problem 4.38d
- Replies: 2
- Views: 697
Homework Problem 4.38d
For CH3NNN there are 3 resonance structures (I believe)
So, would we use the resonance structure which yields the largest hybridization as the answer, or how would we know which hybridization is correct without being given information about which resonance form the molecule is in?
So, would we use the resonance structure which yields the largest hybridization as the answer, or how would we know which hybridization is correct without being given information about which resonance form the molecule is in?
- Tue Feb 14, 2017 12:53 pm
- Forum: Heat Capacities, Calorimeters & Calorimetry Calculations
- Topic: Winter 2014 Q3B
- Replies: 1
- Views: 441
Winter 2014 Q3B
The question asks for the specific heat capacity of Squirtle's shell in KJ/ ((degrees C)* g) and for specific heat capacity the equation q = (m*C*(deltaT)) gives an answer in KJ/ ((degrees C)* g): My question is, why we don't we use 2500 degrees C for finding the specific heat capacity in this probl...
- Sun Feb 12, 2017 8:42 pm
- Forum: Balancing Redox Reactions
- Topic: Balancing on acidic vs basic solutions
- Replies: 1
- Views: 429
Re: Balancing on acidic vs basic solutions
For an acidic solution, you balance using H2O and H+ But with basic solution, you balance with H2O and OH- Basic solutions definitely require you to be more careful. You can still use H+ when solving, but keep in mind you must multiply by the same amount of OH- on both sides to cancel the H+'s For e...
- Sun Feb 05, 2017 9:08 pm
- Forum: Balancing Redox Reactions
- Topic: 14.17
- Replies: 2
- Views: 537
Re: 14.17
Potassium permanganate reacts with iron(II) chloride according to the following oxidation-reduction half-reactions: MnO4-(aq) + 8H+(aq) + 5e- ---> Mn2+(aq) + 4H2O (cathode reduction half-reaction) You first add the amount of H2O needed to balance the O's in the MnO4- portion, then add H+ that equal ...
- Sun Jan 29, 2017 10:37 pm
- Forum: Phase Changes & Related Calculations
- Topic: Reversible Reactions
- Replies: 3
- Views: 861
Re: Reversible Reactions
Reversible reactions can be reversed by infinitely small changes in a variable. For changes in pressure, Pex must ALWAYS be infinitesimally different from the pressure of the system. For a change in temperature, the temperature of the system must change by a series of infinitely small amounts of hea...
- Sun Jan 22, 2017 10:50 pm
- Forum: Reaction Enthalpies (e.g., Using Hess’s Law, Bond Enthalpies, Standard Enthalpies of Formation)
- Topic: Standard Enthalpy of Formation Course Reader example
- Replies: 1
- Views: 462
Standard Enthalpy of Formation Course Reader example
On page 17 of the course reader, there is a standard enthalpy of formation example about using graphite and gaseous hydrogen and oxygen to form ethanol,
Why is the enthalpy of reaction divided by 2?
Why is the enthalpy of reaction divided by 2?