Intermediate and Transition States

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Nathan_Barney_2A
Posts: 10
Joined: Wed Sep 21, 2016 2:58 pm

Intermediate and Transition States

Postby Nathan_Barney_2A » Fri Feb 24, 2017 4:28 pm

So what are the intermediate and transition states in the electrophile and neutrophile reactions? I got lost in the explanation in lecture, so can someone please explain?

Kiara Quinn 3B
Posts: 20
Joined: Sat Jul 09, 2016 3:00 am

Re: Intermediate and Transition States

Postby Kiara Quinn 3B » Fri Feb 24, 2017 5:50 pm

Today during lecture, Professor Lavelle explained that there is one main distinction between the two:

Transition states have partially formed bonds, whereas intermediates have full formed bonds. (see page 85 in the course reader)

Derek Lam 1K
Posts: 3
Joined: Wed Sep 21, 2016 2:55 pm

Re: Intermediate and Transition States

Postby Derek Lam 1K » Sun Feb 26, 2017 8:14 pm

What does that mean to have partially formed bonds vs fully formed bonds?

Chem_Mod
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Re: Intermediate and Transition States

Postby Chem_Mod » Sun Feb 26, 2017 9:34 pm

An intermediate is a species in a chemical reaction that forms and then persists for some measurable time. A transition state is a brief moment in the reaction when the system has reached enough energy and the correct geometry to react. This cannot be isolated and will only exist for a fraction of a second.

Partially formed bonds are bonds which are not complete, but there is still some attraction felt between the two nuclei, this is similar to the electrostatic interaction seen in ions.


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