Organic Reaction Mechanisms
Posted: Mon Mar 06, 2017 8:17 pm
In the introduction to Organic Chemistry book, on page 161, there is an equation that states the following:
G*=H*-TS* (standard gibbs free energy of activation = standard enthalpy of activation - temperature*standard entropy of activation) and below it, there is a statement that says in this case delta G* is always unfavorable, meaning positive. However, why are we considering the gibbs free energy of activation to be unfavorable? why cant it be favorable for the transition state?
Thanks!
G*=H*-TS* (standard gibbs free energy of activation = standard enthalpy of activation - temperature*standard entropy of activation) and below it, there is a statement that says in this case delta G* is always unfavorable, meaning positive. However, why are we considering the gibbs free energy of activation to be unfavorable? why cant it be favorable for the transition state?
Thanks!