Standard Gibbs Free Energy of Activation

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Rachel Kipp 1I
Posts: 16
Joined: Wed Sep 21, 2016 2:55 pm

Standard Gibbs Free Energy of Activation

Postby Rachel Kipp 1I » Thu Mar 09, 2017 10:53 am

Why is standard Gibbs free energy of activation always a positive value, in terms of conceptual understanding?

Justin_Yi_1J
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Joined: Fri Jul 22, 2016 3:00 am
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Re: Standard Gibbs Free Energy of Activation

Postby Justin_Yi_1J » Thu Mar 09, 2017 11:10 am

In order to bring reactants together to undergo a chemical reaction, energy must be put into the system to do the work necessary to perform the reaction. Gibbs free energy is a measure of the energy in a system that is available to do work. A system must gain energy to do the work of the reaction, so the Gibbs free energy of activation must be positive.

Narin Maisha 2H
Posts: 100
Joined: Fri Sep 24, 2021 6:49 am

Re: Standard Gibbs Free Energy of Activation

Postby Narin Maisha 2H » Thu Mar 10, 2022 4:51 am

It is always a positive value because a reaction will only be allowed when the total entropy change of the universe is 0 or another positive integer.

Hudson2J
Posts: 99
Joined: Fri Sep 24, 2021 6:48 am

Re: Standard Gibbs Free Energy of Activation

Postby Hudson2J » Thu Mar 10, 2022 6:40 am

In order to convert reactants into products, both molecules must collide and enter an activated transition state. This must always be higher energy because additional energy is required to break bonds in the complex, which is necessary to convert reactant to product.

705748759
Posts: 33
Joined: Mon Jan 09, 2023 2:44 am

Re: Standard Gibbs Free Energy of Activation

Postby 705748759 » Sun Mar 19, 2023 11:18 pm

It is always a positive value!!!


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