Relation between k and activation energy

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Mishta Stanislaus 1H
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Joined: Fri Sep 29, 2017 7:04 am

Relation between k and activation energy

Postby Mishta Stanislaus 1H » Sun Mar 11, 2018 11:01 pm

What exactly is the relationship between k and activation energy?

Lily Sperling 1E
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Re: Relation between k and activation energy

Postby Lily Sperling 1E » Sun Mar 11, 2018 11:22 pm

You can observe the relationship through the Arrhenius Equation - basically, the formula implies that the rate constant increases exponentially as the activation energy decreases.

Christina Cen 2J
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Re: Relation between k and activation energy

Postby Christina Cen 2J » Sun Mar 11, 2018 11:44 pm

Reactions generally speed up when temperature increases and slow down when temperature decreases. This means that k increases with increasing temperature, which in turn increases the overall rate of the reaction.

diangelosoriano
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Re: Relation between k and activation energy

Postby diangelosoriano » Mon Mar 12, 2018 4:01 pm

If a catalyst were added, how would this also affect k or activation energy?

Johann Park 2B
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Re: Relation between k and activation energy

Postby Johann Park 2B » Mon Mar 12, 2018 4:36 pm

diangelosoriano wrote:If a catalyst were added, how would this also affect k or activation energy?


When you add a catalyst, the reaction is sped up - k is increased and Ea is lowered. The new pathway has a lower activation energy.

Nehal Banik
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Re: Relation between k and activation energy

Postby Nehal Banik » Mon Mar 12, 2018 4:41 pm

As activation energy decreases, it reduces the energy barrier required for the reaction to proceed therefore the rate constant increases, causes the overall rate of the reaction to increase. Also, if the activation energy is higher, the dependence of the rate constant on temperature increases, meaning at higher temperatures the rate constant is most likely going to be higher. These are a couple of the relationships that can be understood from the Arrhenius equation in the textbook.
Hope that helps!

Mai V 4L
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Re: Relation between k and activation energy

Postby Mai V 4L » Sun Mar 08, 2020 11:25 pm

Anyone have a video they think is a good reference for this topic?

Joshua Eidam 2A
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Re: Relation between k and activation energy

Postby Joshua Eidam 2A » Sat Mar 13, 2021 10:55 pm

diangelosoriano wrote:If a catalyst were added, how would this also affect k or activation energy?

Adding a catalyst is going to decrease the activation energy, Ea, which will ultimately lead to an increase in the rate constant k.

Joshua Eidam 2A
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Joined: Wed Sep 30, 2020 9:58 pm

Re: Relation between k and activation energy

Postby Joshua Eidam 2A » Sat Mar 13, 2021 10:58 pm

A clear way to look at the relationship between k and the activation energy, Ea, is through the Arrhenius equation, . This equation shows how a decrease in activation energy would ultimately lead to an increase in k and vice versa. Hope this helps!

005502505
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Joined: Wed Feb 17, 2021 12:17 am

Re: Relation between k and activation energy

Postby 005502505 » Wed Mar 09, 2022 9:04 pm

Using the equation k= Ae^-Ea/RT, you can determine that adding a catalyst will decrease the activation energy (Ea); with a decrease of Ea comes an increase in k, the rate constant.

Kathryn Heinemeier 3H
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Re: Relation between k and activation energy

Postby Kathryn Heinemeier 3H » Sun Mar 13, 2022 11:20 pm

When a catalyst is added, the activation energy will decrease while the rate constant, k will increase.


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