Enthalpy

Moderators: Chem_Mod, Chem_Admin

Rachna Goli 3E
Posts: 24
Joined: Fri Sep 25, 2015 3:00 am

Enthalpy

Postby Rachna Goli 3E » Thu Mar 03, 2016 2:14 pm

Why is it that transition state enthalpies tend to be positive?

Chem_Mod
Posts: 23858
Joined: Thu Aug 04, 2011 1:53 pm
Has upvoted: 1253 times

Re: Enthalpy

Postby Chem_Mod » Thu Mar 03, 2016 5:54 pm

The transition state enthalpy is very similar to the activation energy. Because enthalpy describes heat transferred and heat is a transfer of energy. According to certain collision theories, the transition state enthalpy is in fact the exact SAME thing as activation energy.

Maddie Turk Disc 2J
Posts: 90
Joined: Wed Sep 30, 2020 9:48 pm

Re: Enthalpy

Postby Maddie Turk Disc 2J » Sun Mar 07, 2021 4:40 pm

I believe it is just the same thing as activation energy!

edward_brodell_2I
Posts: 92
Joined: Wed Sep 30, 2020 9:59 pm

Re: Enthalpy

Postby edward_brodell_2I » Fri Mar 12, 2021 9:04 pm

As mentioned, I think it has to do with the potential energies of the reactants and products as they undergo reaction.

005502505
Posts: 49
Joined: Wed Feb 17, 2021 12:17 am

Re: Enthalpy

Postby 005502505 » Wed Mar 09, 2022 9:06 pm

From my notes: in a transition state, the standard Gibbs free energy of activation is always unfavorable and therefore always positive. Hope this helps!

705748759
Posts: 33
Joined: Mon Jan 09, 2023 2:44 am

Re: Enthalpy

Postby 705748759 » Sun Mar 19, 2023 11:08 pm

I believe it is always positive because it is the same as the activation energy


Return to “*Complex Reaction Coordinate Diagrams”

Who is online

Users browsing this forum: No registered users and 3 guests