Geometry

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Alan Chien 1J
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Geometry

Postby Alan Chien 1J » Wed Mar 09, 2016 1:54 pm

When I look at cyclopentane, I know it has an envelope conformation when it is puckered but I does it have a cis and trans like cyclohexane. If you fill in one hydrogen, the other carbons can't alternate axial up and down because there are only 5 carbons and that would not make sense. Does it have some kind of pattern when drawing the conformation?

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Re: Geometry

Postby Chem_Mod » Wed Mar 09, 2016 9:47 pm

Cyclopentane can have cis and trans. At each carbon of the cyclopentane, you can have substituents pointing either up or down. Cyclopentane is kind of in a "fixed" position, so it doesn't do chair flips like cyclohexane can, so something that's axial in cyclopentane remains axial, and something that's equatorial in cyclopentane remains equatorial.

Cis/Trans and axial/equatorial are two separate things.


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