Determining the equilibrium constant

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Spencer Cutrow 1A
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Joined: Fri Sep 25, 2015 3:00 am

Determining the equilibrium constant

Postby Spencer Cutrow 1A » Mon Mar 07, 2016 9:44 pm

If we are given a molecule with 4 confirmations, like butane, will we ever be asked to determine multiple equilibrium constants at once. If so, Is there anything we can tell by looking at the equilibrium constant between two confirmations which are not directly next two each other?

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Re: Determining the equilibrium constant

Postby Chem_Mod » Tue Mar 08, 2016 1:13 am

If they ask you to determine multiple equilibrium constants, then you're gonna have to determine multiple equilibrium constants (sorry, I have no idea what the final's gonna look like).

Check out page 111 in your course reader. Basically you're gonna solve for Keq using the equation deltaG = -RT*ln(Keq).
You know that R is the gas constant, and T will be provided to you. All that's left is to find deltaG.
deltaG is going to be a difference in energies. If your'e finding the Keq for gauche to eclipsed conformation, the you'll use their energy difference as deltaG. If you're finding the Keq for anti to gauche, then you'll do the same as before and get the difference in energy as your deltaG.


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