difference between empirical and molecular
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difference between empirical and molecular
How do you know if the empirical and molecular formula are equal?
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Re: difference between empirical and molecular
Once you have calculated the empirical formula of the specified compound, calculate the molar mass of the empirical formula. Then, compare this to the molar mass given in the question for the specified compound. If these two values are the same, then the empirical and molecular formulas are the same. If not, then you can divide the molar mass of the compound given by the molar mass of the empirical formula to get the factor by which the empirical formula needs to be multiplied by in order to get the molecular formula. Hope this helps!
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Re: difference between empirical and molecular
Usually in that case, in the question, there will be a molar mass listed for that molecular or compound. After getting your empirical formula, you find out the molar mass (add up all the molar masses for each element), and compare it to the molar mass in the question. If they match, then your empirical formula is also your molecular formula. If they don't, you need to figure out what integer you need to multiply by in order for those masses to match. (for ex, if you calculated 100g for the molar mass but the question gives you 200g, you need to multiply your stoichiometric coefficients by 2). I don't know if I explained this correctly but hope it helps.
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Re: difference between empirical and molecular
Hi! You would have to know what the molar masses are of the molecular formula and empirical formula. The empirical formula will normally have a smaller molar mass as it just represents the ratio of molecules. If the two formulas are equal to each other, then their molar masses will be the same.
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Re: difference between empirical and molecular
If the molar mass of the molecule is equal to the total mass of the empirical formula that you calculated, then they are the same. If it is different, then divide the given molar mass by your calculated empirical formula mass to find the scalar factor. Then adjust all the atom numbers of the empirical formula accordingly to determine the molecular formula.
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Re: difference between empirical and molecular
In order to determine if they are equal or different you would need the molar mass of the initial (usually empirical but not always) equation and then compare that to the molecular mass. The molecular mass must be given in the question.
Eq: Molecular mass / initial molar mass found
and if it does not equal 1, (for example - it equals 2) you would multiply the initial formula by that number (2) to get the molecular formula
Eq: Molecular mass / initial molar mass found
and if it does not equal 1, (for example - it equals 2) you would multiply the initial formula by that number (2) to get the molecular formula
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Re: difference between empirical and molecular
After calculating the empirical formula, you can use the periodic table to calculate its mass. If the directions are telling you to find the molecular formula, they should have given you a mass for that compound. If you divide the mass of the molecular formula by the mass of the empirical formula and the answer is 1, then the two formulas are the same. However, they are rarely the same. It usually will come out to a value greater than one which means that you have to multiply the subscripts of the empirical formula by whatever number you got. For example, if the empirical formula was C6H6O2 and the number you got after dividing the mass was 2, then the molecular formula would be C12H12O4.
Re: difference between empirical and molecular
Hi, it'll be equal if the empirical mass is equal to the molecular mass given.
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Re: difference between empirical and molecular
You would know that the empirical and molecular formulas are equal if they have the same molar mass. When you are solving a problem that asks something about both the molecular and empirical formula you should given the molar masses for both or should have enough information to solve for them.
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Re: difference between empirical and molecular
Assuming the question you're answering gives you the molar mass of the actual molecule, you should first find the molar mass of the empirical formula, and then divide the molar mass of the molecule by it. If the factor you get from this division is 1, they would be equal. If not, multiply each element in the empirical formula by the factor, and you should get the molecular formula.
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Re: difference between empirical and molecular
The empirical formula is the ratio of atoms while the molecular formula gives you the actual amount of atoms in a molecule, so they won't be equal.
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Re: difference between empirical and molecular
Empirical formula sets the varying ratios of molecules to make up a formula while the molecular formula specify the specific amount of each molecule.
Re: difference between empirical and molecular
L-Dopa, a drug used for the treatment of Parkinson’s disease, is 54.82% C, 5.62% H, 7.10% N, and 32.46% O, and has a molar mass of 197.19 g/mol.
This problem from Empirical and Molecular Formulas Post-Module Assessment makes it clear that it is possible to have an empirical formula equivalent to the molecular formula.
This problem from Empirical and Molecular Formulas Post-Module Assessment makes it clear that it is possible to have an empirical formula equivalent to the molecular formula.
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Re: difference between empirical and molecular
Since molecular equations are basically some sort of multiple of the empirical equation, find out what that multiple is (should be fairly easy given you have both equations) and then divide the molar mass of the molecular equation by that multiple and if it equals the molar mass of the empirical equation, you know they are equal.
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Re: difference between empirical and molecular
The question will usually state the final molar mass of the product, and ask you to calculate the molecular formula of that product. You will then take the empirical formula that you have calculated, and then find the molar mass of the empirical formula. Once that is done, compare the molar mass of the empirical formula to the molar mass of the product given in the problem. If the masses are extremely close of equal to one another, then the empirical formula would be equal to the molecular formula. If it is not equal, divide the molar mass of the product by the molar mass of the empirical formula to obtain the multiplying factor. Take that factor, and multiply it by all the subscripts in the empirical formula, and you should get the molecular formula.
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Re: difference between empirical and molecular
If the empirical formula mass is equal to the molecular formula mass, then empirical formula equals molecular formula.
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Re: difference between empirical and molecular
You'll be able to see once you calculate the empirical formula, then if there is no way to simplify it further for the molecular formula then you are left with them being the same. But I think it can also depend on the context there may be a range the problem asks for!
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