textbook F13

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Nan_Guan_1L
Posts: 84
Joined: Wed Sep 30, 2020 9:59 pm

textbook F13

Postby Nan_Guan_1L » Wed Oct 28, 2020 8:11 am

In an experiment, 4.14 g of phosphorus combined with chlorine to produce 27.8 g of a white solid compound. (a) What is the empirical formula of the compound? (b) Assuming that the empirical and molecular formulas of the compound are the same, what is its name?

I had trouble getting the right answer for a, which is PCl5.
Instead I got P2Cl5 by doing the following:
moles of P: 4.14/30.973=0.1333
moles of Cl: (27.8-4.14) / 35.5x2 = 0.333
0.333/0.1333=2.5 --> and that's how I got P2Cl5.
I figured the textbook did 35.5 for molar mass of chlorine instead of 35.5x2. I though chlorine is Cl2. can somebody tell me where I did wrong or is this an error in the textbook. thank you!!

Lindsey_Su_3A
Posts: 99
Joined: Wed Sep 30, 2020 10:03 pm
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Re: textbook F13

Postby Lindsey_Su_3A » Wed Oct 28, 2020 8:57 am

Chlorine is only diatomic (Cl2) when it is standing alone, like O2. So for the molar mass, you would just use 35.5.

Hope that helps!

Natalie Do 3F
Posts: 109
Joined: Wed Sep 30, 2020 10:03 pm

Re: textbook F13

Postby Natalie Do 3F » Tue Dec 15, 2020 4:58 pm

First you devide 4.14 g by the molar mass to get .134 moles. You then find the moles of Cl by subtracting 4.14 from 27.8 and dividing by the molar mass to get .667. Divide both by the smaller (.134) to get the ratio 5:1


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