definition

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George_Zhu
Posts: 29
Joined: Mon Jun 17, 2019 7:23 am

definition

Postby George_Zhu » Wed Jul 24, 2019 10:30 am

what is the definition of ligand and bidentate ligand ?

Brian Kwak 1D
Posts: 88
Joined: Fri Sep 28, 2018 12:17 am

Re: definition

Postby Brian Kwak 1D » Wed Jul 24, 2019 11:03 am

Ligands are ions or neutral molecules that bond to a central metal atom or ion. Ligands act as Lewis bases (electron pair donors), and the central atom acts as a Lewis acid (electron pair acceptor). Ligands have at least one donor atom with an electron pair used to form covalent bonds with the central atom.

Bidentate ligands have two donor atoms which allow them to bind to a central metal atom or ion at two points. Common examples of bidentate ligands are ethylenediamine (en), and the oxalate ion (ox).
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2AA0CAB7-6C09-412D-B3D7-366BB800DBE9.png
Example of a bidentate ligand. Ethylenedianime
2AA0CAB7-6C09-412D-B3D7-366BB800DBE9.png (3.65 KiB) Viewed 1348 times

Maddie Turk Disc 2J
Posts: 90
Joined: Wed Sep 30, 2020 9:48 pm

Re: definition

Postby Maddie Turk Disc 2J » Tue Dec 15, 2020 6:41 pm

ligands are just the things attatched to the central atom right?

Joanne Yuh 3I
Posts: 114
Joined: Wed Sep 30, 2020 9:42 pm

Re: definition

Postby Joanne Yuh 3I » Tue Dec 15, 2020 7:21 pm

Maddie Turk Disc 2C wrote:ligands are just the things attatched to the central atom right?


Yes, generally ligands are the Lewis bases that are attached to the central atom. They are e-pair donors of the molecule/ion.

205769933
Posts: 109
Joined: Fri Sep 24, 2021 5:49 am

Re: definition

Postby 205769933 » Fri Dec 03, 2021 8:41 pm

Brian Kwak 1D wrote:Ligands are ions or neutral molecules that bond to a central metal atom or ion. Ligands act as Lewis bases (electron pair donors), and the central atom acts as a Lewis acid (electron pair acceptor). Ligands have at least one donor atom with an electron pair used to form covalent bonds with the central atom.

Bidentate ligands have two donor atoms which allow them to bind to a central metal atom or ion at two points. Common examples of bidentate ligands are ethylenediamine (en), and the oxalate ion (ox).


Thank you for this definition! Helped so much.


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