hydrogen bonding

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Ashley Zhu 1A
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Joined: Fri Sep 28, 2018 12:16 am

hydrogen bonding

Postby Ashley Zhu 1A » Tue Nov 13, 2018 9:38 pm

During lecture, Dr. Lavelle said that the partial positive charge on a hydrogen interacts with the/a lone pair on an N, O, or F. I always thought the interaction was with an N, O, or F that had a partial negative charge. Is this incorrect or do both occur at the same time when a hydrogen bond forms? Does the lone pair contribute to the partial negative charge?

Kassidy Tran 1E
Posts: 77
Joined: Fri Sep 28, 2018 12:15 am

Re: hydrogen bonding

Postby Kassidy Tran 1E » Tue Nov 13, 2018 10:02 pm

For a hydrogen bond to form a hydrogen must have a partial positive charge from being bonded to a atom with higher electronegativity (like N, O, or F). The partially positive hydrogen is then attracted to a partially charged negative atom. For example in the case of water, since H is bonded to O which has high electronegativity, the O pulls the electrons towards itself, and is partially negative and H becomes partially positive. Between one water molecule and another, the partially positive H of one molecule can now make a hydrogen bond with the partially negative O of the other molecule.

Anusha 1H
Posts: 65
Joined: Fri Sep 28, 2018 12:15 am

Re: hydrogen bonding

Postby Anusha 1H » Tue Nov 13, 2018 11:15 pm

You're right about the partial negative charge, which is determined by the electronegativity of the atoms in the molecule.
I think the reason Lavelle made that distinction in class is because a partially negative atom with at least one lone pair has a high density of negative charge, so it is ideal for hydrogen bonding.


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