Hess's Law

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kiara chan
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Hess's Law

Postby kiara chan » Sun Jan 23, 2022 11:26 am

During friday's class, we went over three different methods on calculating enthalpy change. I know that the third method using the sums of product minus initial isn't as specific, but which of the other 2 methods would be most preferred?

Neelaj Das 3I
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Re: Hess's Law

Postby Neelaj Das 3I » Sun Jan 23, 2022 11:27 am

I don't think there is particularly any method that is "preferred". You should know each method and when to use it based on a given problem. Sometimes, you may be given the bond enthalpy information meaning you have to use the second method, etc. It's all situationally based on the problem and the information provided.

Caitlin_Tang_Dis3H
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Re: Hess's Law

Postby Caitlin_Tang_Dis3H » Sun Jan 23, 2022 12:08 pm

I agree with Neelaj. Based on what the professor went over in class, we can use Hess's Method when we have 2 reactions that we can add to get a net reaction and thus a net change in enthalpy. With method 2, we can use bond enthalpies to calculate the enthalpy change with one reaction given. And the third method, like Kiara stated, can be used when we have combustion involved.

Kathryn Heinemeier 3H
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Re: Hess's Law

Postby Kathryn Heinemeier 3H » Sun Jan 23, 2022 10:34 pm

I think it'll mostly just depend on what information we're given in the problem.

Lesley Kim 1K
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Re: Hess's Law

Postby Lesley Kim 1K » Mon Jan 24, 2022 4:44 pm

All the different methods can be used to solve questions about enthalpy changes. The method you choose is going to be the one you find the most convenient based on the information provided!

Kaira Shibata 1E
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Re: Hess's Law

Postby Kaira Shibata 1E » Mon Jan 24, 2022 5:03 pm

Neither is preferred, it really just depends on what information is given in the question. Whichever set is given, you do the corresponding calculations.

Veronica Larson- 1I
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Re: Hess's Law

Postby Veronica Larson- 1I » Mon Jan 24, 2022 5:13 pm

I think it just depends on what information we are given. For example, if you are given the bond enthalpies in the question, it would be the most convenient to use the second method, but that doesn't mean it will necessarily work for every question so you just have to decide based on what you're given. Hope that helps!

Arya Bhalla 1H
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Re: Hess's Law

Postby Arya Bhalla 1H » Tue Jan 25, 2022 4:52 pm

The method used depends on which information is given. Is you are given bond enthalpies, then you can use this information to draw out the compounds and figure out which bonds are broken and formed.

Kainath Kamil Dis 2K
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Joined: Fri Sep 24, 2021 5:37 am

Re: Hess's Law

Postby Kainath Kamil Dis 2K » Tue Jan 25, 2022 6:13 pm

It depends on what information you are given in the problem. like whether you've been given bond angle, etc.

joshua_quinn_1C
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Re: Hess's Law

Postby joshua_quinn_1C » Thu Jan 27, 2022 9:36 pm

The method you would use depends on the information given in the problem and what it is asking for. Hope this helps!

Allen Mayo 1E
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Joined: Tue Feb 16, 2021 12:17 am

Re: Hess's Law

Postby Allen Mayo 1E » Sat Jan 29, 2022 2:55 pm

I believe each method is useful based on what is the given for the problem. There is not a "preferred" method.

Om Patel
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Joined: Fri Sep 24, 2021 7:10 am

Re: Hess's Law

Postby Om Patel » Sat Jan 29, 2022 2:58 pm

it does not matter what method you choose

Hannah Thornton 1F
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Joined: Fri Sep 24, 2021 5:53 am

Re: Hess's Law

Postby Hannah Thornton 1F » Sat Jan 29, 2022 10:30 pm

No method is specifically preferred, it just depends on what information is given in the question.

805401611
Posts: 111
Joined: Sat Nov 28, 2020 12:18 am

Re: Hess's Law

Postby 805401611 » Sun Jan 30, 2022 11:27 pm

From my understanding, I believe the method used is based off the problem that is given to you, not so much that there is a preferred method. It's problem by problem

Kimberly_martinez2I
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Joined: Fri Sep 24, 2021 6:25 am

Re: Hess's Law

Postby Kimberly_martinez2I » Sun Jan 30, 2022 11:30 pm

As people have previously said, I don't think any method is preferred. Knowing all the methods would be more helpful because ultimately it depends on the information given in the question.

Cynthia_L_2C
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Joined: Fri Sep 24, 2021 7:25 am

Re: Hess's Law

Postby Cynthia_L_2C » Sun Jan 30, 2022 11:53 pm

There is no preferred method. For these, you just go based on the problem.

raynebunado
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Joined: Fri Sep 24, 2021 6:58 am

Re: Hess's Law

Postby raynebunado » Sun Jan 30, 2022 11:58 pm

I think you pick the method that works best with what you're given in the problem!

kayleec1004
Posts: 74
Joined: Fri Sep 24, 2021 6:57 am

Re: Hess's Law

Postby kayleec1004 » Mon Jan 31, 2022 12:00 am

There is no "preferred" method. It depends on the information given in the problem.

Reece Fong 2k
Posts: 105
Joined: Fri Sep 24, 2021 6:21 am

Re: Hess's Law

Postby Reece Fong 2k » Mon Jan 31, 2022 8:51 am

The best method is the method you can use with the information given to you.

Hannah_Pon_1F
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Re: Hess's Law

Postby Hannah_Pon_1F » Mon Jan 31, 2022 9:12 am

Like what everyone said choose the method according to the information you are given but also usually it's "easier" to add and subtract the reaction enthalpies compared to calculating all of the energies for bonds being broken and formed.

Alexander Moroz 1B
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Re: Hess's Law

Postby Alexander Moroz 1B » Mon Jan 31, 2022 10:21 am

The information given in a problem guides you in choosing the best method for determining emt happy or reactions. If the problem gives you several reactions and each of their heat of reactions then use Hess’s law, if you are given bond enthalpies, use bond enthalpies, etc.


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