reversible vs irreversible

isochoric/isometric:
isothermal:
isobaric:

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Belle Calforda3f
Posts: 67
Joined: Fri Sep 29, 2017 7:07 am

reversible vs irreversible

Postby Belle Calforda3f » Sun Jan 14, 2018 5:36 pm

What are the two equations that are used for reversible and irreversible reactions and how do you differentiate between the processes if not told in the problem?

Joyce Lee 1C
Posts: 52
Joined: Fri Sep 29, 2017 7:03 am
Been upvoted: 1 time

Re: reversible vs irreversible

Postby Joyce Lee 1C » Sun Jan 14, 2018 6:21 pm

The reversible expansion of an ideal gas has a pressure that keeps changing, so you have to use an integral to find the area under the curve. The equation that is used for reversible expansion is w=-nRTln(V2/V1)

The irreversible expansion is against a constant external pressure, so you don't need an integral (just find the area of a rectangle). The equation used for irreversible expansion is w=-P ΔV

Jonathan Tangonan 1E
Posts: 50
Joined: Sat Jul 22, 2017 3:01 am

Re: reversible vs irreversible

Postby Jonathan Tangonan 1E » Sun Jan 14, 2018 7:49 pm

I think what's also important to note is that a change that is done reversibly does more work than a change carried out irreversibly if you are asked to identify in that instance which is reversible and which is irreversible. This is provided that the initial and final states are the same.


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