So, I know how the enthalpy equation is derived to equal the heat added to a system. Though - why is it possible to say enthalpy = U+PV
I'm a little confused about what enthalpy is I guess and why its equation makes sense.
Also in H = delta U + PdeltaV
what is PdeltaV symbolizing, since delta U = q + PdeltaV ?
Enthalpy Equation
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Re: Enthalpy Equation
Hey, P∆V represents work done to the system. Since w=FxD and F=PxA D (distance) and A (area), we can get the equation w=P ∆V.
Hope it helps.
Hope it helps.
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- Posts: 30
- Joined: Fri Sep 29, 2017 7:05 am
Re: Enthalpy Equation
according to U=q+w, under constant P(delta H=qp),when there is an expansion, work is done by the system, therefore w=-P*delta V (P is constant so only V changes, and since work is done by the system, there is a negative sign in the front); and:
U=q+w
=delta H+w
=delta H+(-P*delta V)
=delta H- P*delta V
deltaH =U+P*delta V (put -P*delta V in the last equation to the left side of the equation)
Hope it helps!
U=q+w
=delta H+w
=delta H+(-P*delta V)
=delta H- P*delta V
deltaH =U+P*delta V (put -P*delta V in the last equation to the left side of the equation)
Hope it helps!
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