Thermodynamics Rules/Concepts

isochoric/isometric:
isothermal:
isobaric:

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MinjooPark_3I
Posts: 116
Joined: Wed Sep 30, 2020 9:33 pm

Thermodynamics Rules/Concepts

Postby MinjooPark_3I » Fri Mar 12, 2021 12:12 pm

Hi! I'm sure there are already posts about this but I wanted to ask if you all can list how certain conditions affect the internal energy, entropy, enthalpy, work, etc.

So I know that:
-if the initial and finals states are the same, dU and dS will be 0 because they are state functions
-w=0 in isobaric, isochoric conditions
-dU=0 in isothermal processes

I know there are probably many more but I can't think of them from the top of my head.
Can you all list some other ones? Thank you!!

Yasmina Zaarour 1G
Posts: 100
Joined: Wed Sep 30, 2020 9:51 pm
Been upvoted: 1 time

Re: Thermodynamics Rules/Concepts

Postby Yasmina Zaarour 1G » Fri Mar 12, 2021 12:37 pm

- If a reaction is reversible, then and
-If a reaction is irreversible, then so

Also would like to add that I think work doesn't equal zero in isobaric (constant pressure) conditions ! w=-PV so it is only equal to zero when it is in isochoric conditions like you added.

Lakshmi Davuluri 1E
Posts: 100
Joined: Wed Sep 30, 2020 9:50 pm

Re: Thermodynamics Rules/Concepts

Postby Lakshmi Davuluri 1E » Fri Mar 12, 2021 12:53 pm

Yasmina Zaarour 1G wrote:- If a reaction is reversible, then and
-If a reaction is irreversible, then so

Also would like to add that I think work doesn't equal zero in isobaric (constant pressure) conditions ! w=-PV so it is only equal to zero when it is in isochoric conditions like you added.


Yeah, I agree with you. I also think that work doesn't equal zero under isobaric conditions because of the equation w=-P*deltaV. Even though pressure is constant, there can still be a change in volume, which would result in a nonzero value for work.

MinjooPark_3I
Posts: 116
Joined: Wed Sep 30, 2020 9:33 pm

Re: Thermodynamics Rules/Concepts

Postby MinjooPark_3I » Sat Mar 13, 2021 8:25 am

thank you for correcting me!


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