Calculating final temp & enthalpy for an ideal monatomic gas


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Jia Hao Liu 3L
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Joined: Fri Sep 26, 2014 2:02 pm

Calculating final temp & enthalpy for an ideal monatomic gas

Postby Jia Hao Liu 3L » Wed Feb 11, 2015 11:43 am

Can someone guide me through this problem?

"Suppose that 1.00 kJ of heat is transferred to 2.00 mol argon. What will the final temperature be if the heat is transferred at a constant pressure? Calculate the enthalpy change for the process and describe the thermodynamic reaction. Assume an ideal, monatomic gas at STP (25 Celcius, 1 atm)."

Any help is appreciated. Thanks!

Jenna Kovsky 1I
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Joined: Fri Sep 26, 2014 2:02 pm

Re: Calculating final temp & enthalpy for an ideal monatomic

Postby Jenna Kovsky 1I » Wed Feb 11, 2015 12:48 pm

The first part (calculating the final temperature) is fairly straightforward. I used the equation q=n*C*deltaT. For the heat capacity (C), you were told to assume that it is an ideal, monatomic gas at constant pressure, so you would use 5/2 R as your heat capacity (this is given on the formula sheet). So you just plug in 5/2*8.314J/Kmol for C, 1.00kJ for q, 2.00mol for n, and 298K (because you're assuming STP) for T initial. Then you just solve for T final. Don't forget to convert q from kilojoules to joules (because the gas constant uses joules)

As for the part about calculating the enthalpy change, I'm still working on that personally, I'll post here again if I get it.
Hope that helped!

Jenna Kovsky 1I
Posts: 13
Joined: Fri Sep 26, 2014 2:02 pm

Re: Calculating final temp & enthalpy for an ideal monatomic

Postby Jenna Kovsky 1I » Wed Feb 11, 2015 12:54 pm

Actually, now that I think about it, doesn't q=deltaH at constant pressure?

Jia Hao Liu 3L
Posts: 4
Joined: Fri Sep 26, 2014 2:02 pm

Re: Calculating final temp & enthalpy for an ideal monatomic

Postby Jia Hao Liu 3L » Wed Feb 11, 2015 12:55 pm

Yeah, that's what i was thinking... So delta H = 1.00 kJ and the reaction is endothermic?

Jenna Kovsky 1I
Posts: 13
Joined: Fri Sep 26, 2014 2:02 pm

Re: Calculating final temp & enthalpy for an ideal monatomic

Postby Jenna Kovsky 1I » Wed Feb 11, 2015 1:36 pm

That seems right to me! Where did you get this problem, maybe you can look up the solution online or something?

Jia Hao Liu 3L
Posts: 4
Joined: Fri Sep 26, 2014 2:02 pm

Re: Calculating final temp & enthalpy for an ideal monatomic

Postby Jia Hao Liu 3L » Wed Feb 11, 2015 2:35 pm

It was on my quiz! Thanks for your help!

Jenna Kovsky 1I
Posts: 13
Joined: Fri Sep 26, 2014 2:02 pm

Re: Calculating final temp & enthalpy for an ideal monatomic

Postby Jenna Kovsky 1I » Wed Feb 11, 2015 3:52 pm

That seems right to me! Where did you get this problem, maybe you can look up the solution online or something?

Chem_Mod
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Re: Calculating final temp & enthalpy for an ideal monatomic

Postby Chem_Mod » Wed Feb 11, 2015 10:39 pm

Correct, is true always. Since this process is indeed constant pressure, then


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