Reversible and Isobaric
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Reversible and Isobaric
Can I assume that an isobaric expansion is irreversible since the equation for irreversible expansion is Next*deltaV ?
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Re: Reversible and Isobaric
I would only do the calculation for irreversible reactions if the problem says specifically.
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Re: Reversible and Isobaric
The irreversible equation is only used when pressure is constant. If pressure is changing, then you use the reversible equation.
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Re: Reversible and Isobaric
I believe that isobaric means constant pressure and in order for that equation to be used, the external pressure has to be held constant. I would be cautious using this though unless it specifically said that the process was irreversible or reversible.
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Re: Reversible and Isobaric
Isobaric means that deltaP = 0, but doesn't say if the process is reversible or irreversible. Therefore, the only assumption one can make is that U = detaH - pdeltaV (as there is only one P value to plug in, usually external pressure).
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