when to use each equation


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Kaethe Zappacosta 2L
Posts: 106
Joined: Fri Sep 24, 2021 7:29 am

when to use each equation

Postby Kaethe Zappacosta 2L » Fri Jan 28, 2022 2:23 pm

I am confused on when we use w=-pdeltaV versus w=-nRTln(Vf/Vi)?

Jeffrey Yang 3I
Posts: 50
Joined: Mon Jan 03, 2022 9:37 pm

Re: when to use each equation

Postby Jeffrey Yang 3I » Fri Jan 28, 2022 3:53 pm

These two equations relate to what values are constant in the scenario. If the pressure is constant, you can remove it from the integral to have w = -p*deltaV. If the temperature is constant, you can replace pressure with nRT, and pull this out from the integral because it is constant. When you integrate 1/V, you have the ln(Vf/Vi) term.

Harsimer Bal 3K
Posts: 106
Joined: Fri Sep 24, 2021 5:16 am
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Re: when to use each equation

Postby Harsimer Bal 3K » Fri Jan 28, 2022 6:38 pm

When work equals -PdeltaV, the external pressure of a system is constant during expansion in a system. This equation is used for an irreversible process as the expansion is a measurable amount of change that cannot be reversed rather than many infinitesimal changes to a variable. Work is equal to -nRTln(V2/V1) for the reversible, isothermal expansion of an ideal gas. The temperature remains constant and the pressure of the gas falls as it expands so the external pressure must be reduced to match the pressure of the gas with each step.

Maggie Clark
Posts: 100
Joined: Fri Sep 24, 2021 7:34 am

Re: when to use each equation

Postby Maggie Clark » Fri Jan 28, 2022 9:20 pm

I would see what is given in the problem, and plug that in


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