U = q +w or U = q-w??


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HaoYun_Liew_1I
Posts: 39
Joined: Fri Sep 29, 2023 10:16 am

U = q +w or U = q-w??

Postby HaoYun_Liew_1I » Fri Mar 15, 2024 5:21 pm

I see both formulas occasionally show up in different formulas, and it is the variable w that seems to be confusing since sometimes +w represents working being done by the system (expansion) vs +w being work done on the system (compression), and im not sure in which formula where +w is work is done by the system and vice versa?

Brian Bognuda 2I
Posts: 98
Joined: Fri Sep 29, 2023 11:00 am

Re: U = q +w or U = q-w??

Postby Brian Bognuda 2I » Fri Mar 15, 2024 5:24 pm

The correct equation is U = q + w. An easy way to remember this is when a reaction is isothermal, U = 0, which makes q = -w. Hope this helps.

Callista OConnor
Posts: 80
Joined: Mon Jan 09, 2023 2:01 am

Re: U = q +w or U = q-w??

Postby Callista OConnor » Sun Mar 17, 2024 9:56 pm

It is always q + w. Your confusion may be coming from the fact that sometimes, when delta U = 0, we set w = -q to get a work equation that utilizes the reversible heat equation (with a negative sign in front).

105561735
Posts: 82
Joined: Sat Oct 09, 2021 5:04 am

Re: U = q +w or U = q-w??

Postby 105561735 » Mon Mar 18, 2024 12:00 am

The way I remember it is that U=q+ w and delta u= -W


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