Irreversible vs Reversible


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Rosselyn_Machado_2B
Posts: 80
Joined: Fri Sep 29, 2023 12:25 pm

Irreversible vs Reversible

Postby Rosselyn_Machado_2B » Sat Mar 16, 2024 11:26 pm

Hi, how would you know it an reaction equation is reversible or irreversible? Are there key things to note to differentiate the two? Thank you!

Logan_reyes_3H
Posts: 84
Joined: Fri Sep 29, 2023 12:11 pm

Re: Irreversible vs Reversible

Postby Logan_reyes_3H » Sat Mar 16, 2024 11:27 pm

Irreversible chemical reactions can occur in only one direction. They usually specify in the problem whether the the reaction is reversible or not.

306278293
Posts: 85
Joined: Fri Sep 29, 2023 11:44 am

Re: Irreversible vs Reversible

Postby 306278293 » Sat Mar 16, 2024 11:36 pm

It is also notable that these reactions use different equations! For example, on the last midterm there was a question about finding work for an irreversible expansion, which is what entailed us to use w = - P ∆V rather than other work equations such as w=-nRT ln V2/V1.

Sarah Egan 3A
Posts: 42
Joined: Mon Jan 03, 2022 9:11 am

Re: Irreversible vs Reversible

Postby Sarah Egan 3A » Sat Mar 16, 2024 11:53 pm

Reversible reactions are expressed using equilibrium constants and rate laws for both forward and reverse reactions but irreversible reactions are just rate laws only for the forward reaction.

Grace Kim 1a
Posts: 44
Joined: Fri Sep 29, 2023 9:36 am

Re: Irreversible vs Reversible

Postby Grace Kim 1a » Sun Mar 17, 2024 12:19 am

If the problem says that there is slow expansion at a constant pressure, then it indicates a reversible expansion is occuring.

Holiday Parsons 2D
Posts: 123
Joined: Fri Sep 29, 2023 11:07 am

Re: Irreversible vs Reversible

Postby Holiday Parsons 2D » Sun Mar 17, 2024 12:47 pm

conceptually, reversible processes take place infinitesimally (hence why an integral is used to derive the reversible work equation, "w=-nRT ln V2/V1" because of the incremental changes involved). Irreversible processes occur when large changes take place and thus cannot be returned to their original state.

306060519
Posts: 109
Joined: Fri Sep 29, 2023 11:29 am

Re: Irreversible vs Reversible

Postby 306060519 » Sun Mar 17, 2024 8:23 pm

You can tell a system is reversible if it can be reserved back into its original state using mechanisms.


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