Irreversible vs Reversible
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Irreversible vs Reversible
Hi, how would you know it an reaction equation is reversible or irreversible? Are there key things to note to differentiate the two? Thank you!
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Re: Irreversible vs Reversible
Irreversible chemical reactions can occur in only one direction. They usually specify in the problem whether the the reaction is reversible or not.
Re: Irreversible vs Reversible
It is also notable that these reactions use different equations! For example, on the last midterm there was a question about finding work for an irreversible expansion, which is what entailed us to use w = - P ∆V rather than other work equations such as w=-nRT ln V2/V1.
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Re: Irreversible vs Reversible
Reversible reactions are expressed using equilibrium constants and rate laws for both forward and reverse reactions but irreversible reactions are just rate laws only for the forward reaction.
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Re: Irreversible vs Reversible
If the problem says that there is slow expansion at a constant pressure, then it indicates a reversible expansion is occuring.
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Re: Irreversible vs Reversible
conceptually, reversible processes take place infinitesimally (hence why an integral is used to derive the reversible work equation, "w=-nRT ln V2/V1" because of the incremental changes involved). Irreversible processes occur when large changes take place and thus cannot be returned to their original state.
Re: Irreversible vs Reversible
You can tell a system is reversible if it can be reserved back into its original state using mechanisms.
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