temperature of a reversible reaction
Moderators: Chem_Mod, Chem_Admin
-
- Posts: 77
- Joined: Wed Oct 03, 2018 12:16 am
temperature of a reversible reaction
It was mentioned today in lecture that the temperature of an reversible reaction both inside and outside the system has to be constant, why is this the case?
-
- Posts: 62
- Joined: Fri Sep 28, 2018 12:28 am
Re: temperature of a reversible reaction
The reaction is not isolated and takes place in a heat reservoir. This way, even if the reaction is exothermic, the overall temperature will remain the same at the beginning and the end of the reaction.
-
- Posts: 61
- Joined: Fri Sep 28, 2018 12:15 am
Re: temperature of a reversible reaction
The delta T is essentially 0 because of the heat resevoir. When we talk about isothermal reversible expansion, isothermal refers to a constant "same" temperature even though as stated above their is a slight change in temp that is quickly replaced by the surroundings.
-
- Posts: 41
- Joined: Fri Sep 28, 2018 12:21 am
Re: temperature of a reversible reaction
And from there, if deltaT is zero, it follows that deltaU = 0 and therefore q = -w.
Return to “Concepts & Calculations Using First Law of Thermodynamics”
Who is online
Users browsing this forum: No registered users and 3 guests