q and w = 0


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Samantha Chung 4I
Posts: 77
Joined: Wed Oct 03, 2018 12:16 am

q and w = 0

Postby Samantha Chung 4I » Mon Feb 11, 2019 5:23 pm

Is there a specific set of conditions under which we can assume q and w equals to zero? Or does it depend on the problem?

Meachelle_Lum_1I
Posts: 92
Joined: Fri Sep 28, 2018 12:24 am

Re: q and w = 0

Postby Meachelle_Lum_1I » Mon Feb 11, 2019 5:42 pm

q=0 if the problem is adiabatic.
w=0 if there is no volume change.
q=-w if deltaU=0, which occurs when the system is in isothermal conditions. This is because isothermal occurs at a constant temperature, and for ideal gases, U=3/2nRT. For solids and liquids, q=-w because U=q+w.
q and w will both be 0 for isolated conditions, in which no heat or work can be transferred.

Rimsha Hussaini 1A
Posts: 31
Joined: Fri Sep 28, 2018 12:20 am

Re: q and w = 0

Postby Rimsha Hussaini 1A » Mon Feb 11, 2019 9:23 pm

If no heat was exchanged in the system, q = 0 and deltaU = w.
If no work was being done in the system, w = 0 and deltaU = q.
For an ideal gas in an isothermal system, deltaU = 0 = q + w. In this situation, q = nRTln(V2/V1).

Charles Hood Disc 1C
Posts: 39
Joined: Fri Sep 28, 2018 12:19 am

Re: q and w = 0

Postby Charles Hood Disc 1C » Mon Feb 11, 2019 9:50 pm

If an ideal gas is "isothermal" then you can assume ΔU = 0.


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