Different ways to calculate change in U


Moderators: Chem_Mod, Chem_Admin

ashwathinair
Posts: 113
Joined: Sat Aug 17, 2019 12:17 am

Different ways to calculate change in U

Postby ashwathinair » Sun Feb 02, 2020 11:38 pm

How do you calculate the change in U for different situations: constant/changing pressure, temperature, volume etc?

Jared_Yuge
Posts: 100
Joined: Sat Aug 17, 2019 12:17 am

Re: Different ways to calculate change in U

Postby Jared_Yuge » Sun Feb 02, 2020 11:41 pm

In a closed system with no constants its just delta U = q +w

Jared_Yuge
Posts: 100
Joined: Sat Aug 17, 2019 12:17 am

Re: Different ways to calculate change in U

Postby Jared_Yuge » Sun Feb 02, 2020 11:43 pm

If delta V is 0 (constant volume) then its just deltaU = q

Jared_Yuge
Posts: 100
Joined: Sat Aug 17, 2019 12:17 am

Re: Different ways to calculate change in U

Postby Jared_Yuge » Sun Feb 02, 2020 11:43 pm

if delta P is 0 (under constant pressure) then delta U = delta H - P deltaV

Jared_Yuge
Posts: 100
Joined: Sat Aug 17, 2019 12:17 am

Re: Different ways to calculate change in U

Postby Jared_Yuge » Sun Feb 02, 2020 11:46 pm

This is assuming it is an open or closed system with a piston, where heat and compression/expansion change, but in an isolated system the delta U is just q + w =0 because the point of an isolated system is that the internal energy doesn't change


Return to “Concepts & Calculations Using First Law of Thermodynamics”

Who is online

Users browsing this forum: No registered users and 1 guest