What equation to use when finding work


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705340227
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Joined: Wed Sep 30, 2020 10:08 pm

What equation to use when finding work

Postby 705340227 » Sun Feb 07, 2021 11:53 am

When do I use w= -P * delta V versus w = -nRTln(Vfinal/Vinitial)?

gabbi_r2C
Posts: 108
Joined: Wed Sep 30, 2020 9:52 pm

Re: What equation to use when finding work

Postby gabbi_r2C » Sun Feb 07, 2021 11:57 am

We use the first equation (w=-PdeltaV) when pressure is constant; you can derive this from the integral equation Dr. Lavelle gave us in lecture. We use the second equation (w=-nRTln(Vf/Vi)) when pressure is not constant, as you cannot pull out P from the integral equation nor can you solve the expression without substituting something for pressure, and the above equation is that derived substitution.

SophiaNguyen_2L
Posts: 112
Joined: Wed Sep 30, 2020 9:59 pm

Re: What equation to use when finding work

Postby SophiaNguyen_2L » Sun Feb 07, 2021 12:00 pm

I believe you'd use W = - P x ∆V for irreversible expansions (pressure is constant). And on the other hand, you'd use W = -nRT ln (V2/V1) for reversible expansions (pressure is not constant).


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