Using internal or external conditions
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Using internal or external conditions
I sometimes get confused if I should use the pressure/volume/temperature of the system or the surroundings. Is there a rule of thumb that I should know or could help? Thank you!
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Re: Using internal or external conditions
I believe that most of the time, we will use the pressure/volume/temp of the system. For irreversible pathways, external pressure is often used (the pressure of the surroundings). For reversible pathways, we usually use the system's values.
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Re: Using internal or external conditions
You always want to use the system's conditions for reversible pathways.
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