delta U=0


Moderators: Chem_Mod, Chem_Admin

Carolina Gomez 2G
Posts: 100
Joined: Wed Sep 30, 2020 9:32 pm

delta U=0

Postby Carolina Gomez 2G » Thu Feb 18, 2021 1:32 pm

Why is delta U equal to 0 for isothermal expansions?

SelenaDahabreh1D
Posts: 161
Joined: Wed Sep 30, 2020 9:47 pm
Been upvoted: 3 times

Re: delta U=0

Postby SelenaDahabreh1D » Thu Feb 18, 2021 1:34 pm

Delta U = 0 for isothermal expansions because the temperature is constant in isothermal expansions. When the temperature is constant, no heat could be supplied or released from the process. Thus, delta U = 0. And remember for isothermal (constant temperature) expansions, q=-w, so both q and w would be 0 making delta U 0 as well.

Mikayla James 2A
Posts: 102
Joined: Wed Sep 30, 2020 9:31 pm
Been upvoted: 2 times

Re: delta U=0

Postby Mikayla James 2A » Thu Feb 18, 2021 1:58 pm

Hi! In lecture #13, Dr. Lavelle discusses how for isothermal, reversible reactions of ideal gases, any energy lost by the system during expansion (the work value) is replaced in the form of heat absorbed by the system (the q value). Thus, q=-w and by the equation ΔU = q+w , the net change in the internal energy is 0 and because energy that is lost during work is replaced through heat absorbed, the temperature of the system remains the same. Hope this helps!

Keon Amirazodi 3H
Posts: 107
Joined: Wed Sep 30, 2020 9:59 pm

Re: delta U=0

Postby Keon Amirazodi 3H » Sun Feb 21, 2021 2:46 pm

Delta U=0 in isothermal reactions because there is no change in temperature. Since U=q+w, in isothermal reactions, q=-w.

Grace_Remphrey_2J
Posts: 100
Joined: Wed Sep 30, 2020 9:54 pm

Re: delta U=0

Postby Grace_Remphrey_2J » Sun Feb 21, 2021 3:34 pm

Since the temperature is held constant, the change in energy is zero. The heat absorbed by the gas equals the work done by the ideal gas on its surroundings. Enthalpy change is also equal to zero because the change in energy zero and the pressure and volume is constant. Hope this helps!

Brandon Gruender 3F
Posts: 101
Joined: Wed Sep 30, 2020 10:03 pm

Re: delta U=0

Postby Brandon Gruender 3F » Sun Feb 21, 2021 3:52 pm

In Isothermal reactions the temperature is constant, so there is no heat transfer. In these reactions q=-w, so they cancel out and leave delta U equal to 0.

Edwin Liang 1I
Posts: 100
Joined: Wed Sep 30, 2020 9:34 pm

Re: delta U=0

Postby Edwin Liang 1I » Sun Feb 21, 2021 4:16 pm

Delta u = 0 because temperature is a constant meaning the change in energy will also be zero. In ideal gas law, enthalpy is a function of temperature, so in isothermal process involving only ideal gases, the change of enthalpy will also be zero.

DominicMalilay 1F
Posts: 114
Joined: Wed Sep 30, 2020 9:36 pm

Re: delta U=0

Postby DominicMalilay 1F » Sun Feb 21, 2021 7:12 pm

Since U=q+w, an isothermal rxn would mean no heat transfer and constant temp, making both values 0.

Evelyn Silva 3J
Posts: 104
Joined: Wed Sep 30, 2020 9:42 pm

Re: delta U=0

Postby Evelyn Silva 3J » Sun Feb 21, 2021 7:19 pm

This is because the temperature is constant and there is no heat being transferred. Since q=-w they cancel out and the internal energy is zero.

Vivian_Le_1L
Posts: 53
Joined: Thu Dec 17, 2020 12:19 am

Re: delta U=0

Postby Vivian_Le_1L » Sun Feb 21, 2021 9:00 pm

In an isothermal process, temperature is constant, so the heat absorbed by the gas equals the work done by the ideal gas on its surroundings. Thus, q=-w and by the equation ΔU = q+w , the net change in the internal energy is 0.

Justin Zhang_1A
Posts: 100
Joined: Wed Sep 30, 2020 9:48 pm

Re: delta U=0

Postby Justin Zhang_1A » Sun Feb 21, 2021 9:10 pm

Temperature doesn't change in isothermal processes, so there is no heat or energy being transferred, so delta U is 0.

Chinmayi Mutyala 3H
Posts: 105
Joined: Wed Sep 30, 2020 9:50 pm

Re: delta U=0

Postby Chinmayi Mutyala 3H » Sun Feb 28, 2021 11:34 pm

delta U is 0 for an isothermal reversible expansion since the amount of energy lost from work is replaced by heat. q= -w

David Y
Posts: 109
Joined: Wed Sep 30, 2020 9:49 pm

Re: delta U=0

Postby David Y » Fri Mar 12, 2021 10:43 am

No change in temperature means deltaU=0 because q=-w

Ava Nickman
Posts: 101
Joined: Wed Sep 30, 2020 9:54 pm

Re: delta U=0

Postby Ava Nickman » Fri Mar 12, 2021 10:57 am

temperature stays constant

Brian Acevedo 2E
Posts: 69
Joined: Wed Sep 30, 2020 9:44 pm

Re: delta U=0

Postby Brian Acevedo 2E » Sat Mar 13, 2021 1:13 pm

The change in internal energy (delta U) is 0 for isothermal systems because any heat added to or taken from the system translates directly into work done by (or on) the ideal gas involved. The equation delta U = q+w can be rearranged as q=-w when there is no change in internal energy, indicating that the aforementioned explanation is valid.

Gicelle Rubin 1E
Posts: 101
Joined: Fri Oct 02, 2020 12:16 am

Re: delta U=0

Postby Gicelle Rubin 1E » Sat Mar 13, 2021 11:17 pm

That's because there isn't any change in temperature :)

Ashley Wagner 2A
Posts: 66
Joined: Wed Sep 30, 2020 9:32 pm

Re: delta U=0

Postby Ashley Wagner 2A » Sat Mar 13, 2021 11:18 pm

Delta U is equal to 0 because the temperature of the system stays constant.

Diana Aguilar 3H
Posts: 120
Joined: Wed Sep 30, 2020 9:50 pm

Re: delta U=0

Postby Diana Aguilar 3H » Sun Mar 14, 2021 10:59 pm

Like many others have stated, Delta U is equal to 0 for isothermal expansions because the temperature stays constant.


Return to “Concepts & Calculations Using First Law of Thermodynamics”

Who is online

Users browsing this forum: No registered users and 2 guests