Reversible Vs Irreversible
Moderators: Chem_Mod, Chem_Admin
-
- Posts: 30
- Joined: Fri Sep 29, 2017 7:05 am
Reversible Vs Irreversible
Why is the temperature constant in reversible reactions whereas temperature changes along the path for irreversible reactions?
Re: Reversible Vs Irreversible
For reversible expansion, it is isothermal because the system does work and lose energy, and then the loss of energy is replaced by the heat flow into the system. So U, the internal energy, remains constant. For U = 3/2 nRT, T also stays constant.
-
- Posts: 51
- Joined: Thu Jul 13, 2017 3:00 am
-
- Posts: 42
- Joined: Fri Sep 29, 2017 7:06 am
Re: Reversible Vs Irreversible
I believe that being at thermodynamic equilibrium (constant heat) is part of the definition of a reversible reaction whereas it is not required for irreversible.
Return to “Concepts & Calculations Using Second Law of Thermodynamics”
Who is online
Users browsing this forum: No registered users and 6 guests