Reversible Vs Irreversible


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joycelee1A
Posts: 30
Joined: Fri Sep 29, 2017 7:05 am

Reversible Vs Irreversible

Postby joycelee1A » Fri Jan 26, 2018 12:53 pm

Why is the temperature constant in reversible reactions whereas temperature changes along the path for irreversible reactions?

Sue Xu 2K
Posts: 58
Joined: Fri Sep 29, 2017 7:06 am

Re: Reversible Vs Irreversible

Postby Sue Xu 2K » Fri Jan 26, 2018 1:13 pm

For reversible expansion, it is isothermal because the system does work and lose energy, and then the loss of energy is replaced by the heat flow into the system. So U, the internal energy, remains constant. For U = 3/2 nRT, T also stays constant.

Michael Cheng 1C
Posts: 51
Joined: Thu Jul 13, 2017 3:00 am

Re: Reversible Vs Irreversible

Postby Michael Cheng 1C » Sat Jan 27, 2018 10:05 pm

So then why is temperature not constant in irreversible reactions?

Kevin Tabibian 1A
Posts: 42
Joined: Fri Sep 29, 2017 7:06 am

Re: Reversible Vs Irreversible

Postby Kevin Tabibian 1A » Sat Jan 27, 2018 11:35 pm

I believe that being at thermodynamic equilibrium (constant heat) is part of the definition of a reversible reaction whereas it is not required for irreversible.


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