Spontaneous  [ENDORSED]


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Ju-Wei Wang 1I
Posts: 31
Joined: Fri Sep 29, 2017 7:05 am

Spontaneous

Postby Ju-Wei Wang 1I » Sat Jan 27, 2018 1:21 pm

In a problem, how are we supposed to determine whether a reaction/process is spontaneous or not? I know you can figure it out when given Gibbs free energy, but what other way can be used to figure this out?

Varsha Sivaganesh 1A
Posts: 51
Joined: Thu Jul 13, 2017 3:00 am

Re: Spontaneous

Postby Varsha Sivaganesh 1A » Sat Jan 27, 2018 1:33 pm

Well in class, Lavelle mentioned that in any spontaneous process, there is an increase in entropy. However, I'm not sure if that means ALL spontaneous processes have a positive

Susie Lee 2I
Posts: 20
Joined: Fri Sep 29, 2017 7:05 am

Re: Spontaneous

Postby Susie Lee 2I » Sat Jan 27, 2018 3:11 pm

Can someone briefly explain what it means to have a spontaneous process?

Diane Bui 2J
Posts: 61
Joined: Sat Jul 22, 2017 3:00 am

Re: Spontaneous

Postby Diane Bui 2J » Sat Jan 27, 2018 6:10 pm

A spontaneous process means that it has the tendency to occur naturally without an outside force acting on it.

Tiffany 1B
Posts: 32
Joined: Fri Sep 29, 2017 7:05 am

Re: Spontaneous

Postby Tiffany 1B » Sat Jan 27, 2018 6:19 pm

Yeah so with spontaneous processes the entropy does increase so I think you would probably be able to assume that a positive delta S means spontaneous. Although Gibbs free energy might be a more definite way...

Felicia Fong 2G
Posts: 31
Joined: Sat Jul 22, 2017 3:00 am

Re: Spontaneous

Postby Felicia Fong 2G » Sat Jan 27, 2018 8:20 pm

An example for a spontaneous process would be a ball falling down a hill. This occurs naturally. A non spontaneous process would be a ball rolling uphill, which wouldn't occur on its own.

Chem_Mod
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Re: Spontaneous  [ENDORSED]

Postby Chem_Mod » Mon Jan 29, 2018 2:04 pm

Spontaneity is dependent on the value of the Gibb's free energy for a process. Spontaneous processes will have a negative value. Just because a process is exothermic or increases entropy does not mean that it is spontaneous. For example, melting ice increases entropy, but ice will not melt below 0 C.


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